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材料导报  2026, Vol. 40 Issue (10): 25050072-9    https://doi.org/10.11896/cldb.25050072
  无机非金属及其复合材料 |
高熵钙钛矿氧化物陶瓷的制备与应用研究进展
张爱迪1, 郭洪飞1,2,*, 赵敏1, 石玉敏1, 左震1
1 内蒙古工业大学材料科学与工程学院,呼和浩特 010051
2 内蒙古科学技术研究院先进材料与能源研究所,呼和浩特 010020
Research Progress on Preparation and Application of High-entropy Perovskite Oxide Ceramics
ZHANG Aidi1, GUO Hongfei1,2,*, ZHAO Min1, SHI Yumin1, ZUO Zhen1
1 School of Materials Science and Engineering, Inner Mongolia University of Technology, Hohhot 010051, China
2 Institute of Advanced Materials and Energy, Inner Mongolia Institute of Science and Technology, Hohhot 010020, China
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摘要 高熵钙钛矿氧化物陶瓷作为一种新型功能材料,凭借其高熵效应所赋予的优异介电性能、卓越的储能性能以及显著的催化活性,受到了国内外学者的广泛关注。本文首先概述了高熵钙钛矿氧化物陶瓷材料,介绍了其晶体结构基础与设计方法;接着探讨了多种制备方法,包括传统的固相反应法、溶胶-凝胶法,以及先进的闪烧法和放电等离子烧结技术等。此外,还系统介绍了高熵钙钛矿氧化物陶瓷的卓越性能,涵盖电学、磁学、热学以及介电与储能等方面,这些性能使其在电磁波吸收材料、固体氧化物燃料电池、介电与储能材料等诸多领域展现出广阔的应用前景。最后展望了高熵钙钛矿氧化物陶瓷未来的研究方向,包括新体系的开发、理论计算的深入以及应用领域的拓展等方面。
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张爱迪
郭洪飞
赵敏
石玉敏
左震
关键词:  高熵陶瓷  高熵效应  钙钛矿结构  制备方法    
Abstract: As a new type of functional material, high-entropy perovskite oxide ceramics have attracted extensive attention from scholars at home and abroad due to their excellent dielectric properties, excellent energy storage performance and significant catalytic activity arising from the high-entropy effect. In this paper, we first summarize the high-entropy perovskite oxide ceramic materials and introduce their crystal structure basis and design methods. Then, a variety of preparation methods were discussed, including the traditional solid-phase reaction method, the sol-gel method, as well as the advanced flash firing method and discharge plasma sintering technology. In addition, the excellent properties of high-entropy perovskite oxide ceramics are systematically introduced, covering electricity, magnetism, thermal, dielectric and energy storage, etc., which make them show broad application prospects in many fields such as electromagnetic wave absorbing materials, solid oxide fuel cells, dielectric and energy storage materials, etc. Finally, the future research directions of high-entropy perovskite oxide ceramics were discussed, including the development of new systems, in-depth theoretical calculations, and the expansion of application fields.
Key words:  high-entropy ceramics    high-entropy effect    perovskite structure    preparation method
发布日期:  2026-06-03
ZTFLH:  TQ174.1  
基金资助: 国家自然科学基金(52465061);内蒙古自治区科技创新重大示范工程“揭榜挂帅”项目(2024JBGS0035);内蒙古自治区自然科学基金重点项目(2024ZD26)
通讯作者:  *郭洪飞,教授,博士研究生导师。主要从事智能制造、材料加工、军民融合研究工作。ghf-2005@163.com   
作者简介:  张爱迪,2024年6月于吉林建筑大学获得工学学士学位。目前主要研究领域为高熵陶瓷、铬酸镧陶瓷连接方向。
引用本文:    
张爱迪, 郭洪飞, 赵敏, 石玉敏, 左震. 高熵钙钛矿氧化物陶瓷的制备与应用研究进展[J]. 材料导报, 2026, 40(10): 25050072-9.
ZHANG Aidi, GUO Hongfei, ZHAO Min, SHI Yumin, ZUO Zhen. Research Progress on Preparation and Application of High-entropy Perovskite Oxide Ceramics. Materials Reports, 2026, 40(10): 25050072-9.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.25050072  或          https://www.mater-rep.com/CN/Y2026/V40/I10/25050072
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