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材料导报  2025, Vol. 39 Issue (24): 24120008-9    https://doi.org/10.11896/cldb.24120008
  高分子与聚合物基复合材料 |
ZSM-22在烷烃加氢异构反应中应用的研究进展
王智莹1,2, 伞晓广1,*, 苗昱露1,2, 董磊2
1 沈阳化工大学化学工程学院,沈阳 110142
2 中国科学院大学大连化学物理研究所,辽宁 大连 116023
Research Progress on Applying ZSM-22 to Alkane Hydroisomerization
WANG Zhiying1,2, SAN Xiaoguang1,*, MIAO Yulu1,2, DONG Lei2
1 College of Chemical Engineering, Shenyang University of Chemical Technology, Shenyang 110142, China
2 Dalian Institute of Chemical Physics (DICP), Chinese Academy of Sciences, Dalian 116023, Liaoning, China
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摘要 以分子筛为载体负载贵金属的双功能催化剂一直是烷烃加氢异构反应的主要研究对象。ZSM-22作为一种单维孔道的分子筛载体,具有更符合异构反应机理的择形选择性,但特殊的晶体形貌导致分子扩散严重受限。本文简述了烷烃加氢异构反应的扩散路径及异构机理,总结了近年来在理想型ZSM-22载体制备方面的探索与研究;从纳米晶体的合成、金属掺杂以及简单的分子筛后处理等方面阐述了载体理化性质的改变对催化剂性能的影响,总结了分子筛载体的调变规律以及在制备过程中受到的限制;深入阐述了分子筛性能调变与烷烃加氢异构反应结果之间的构效关系;同时,展望了催化剂载体后处理提质增效的研究方向。
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王智莹
伞晓广
苗昱露
董磊
关键词:  烷烃  加氢异构  ZSM-22分子筛  后处理  反应机理    
Abstract: The bifunctional catalysts with zeolites as supports have long been the main research topic in the hydroisomerization of alkanes. ZSM-22, as a type of single dimensional zeolite, has demonstrated excellent shape selectivity in the isomerization reaction. However, the crystal morphology-induced diffusion limitation of ZSM-22 is an unavoidable obstacle to its application. This review briefly describes the diffusion and hydroisomerization mechanism of alkanes, and outlines the efforts in exploring and hypothesizing the preparation of ideal ZSM-22 made by global researchers in recent years. It focuses on the methods of adjusting, doping, and postprocessing of zeolites to elaborate their influence on the catalytic performance, and summarizes the optimization law of the zeolite support as well as its limitations in the preparation process. The structure-activity relationship between the modified molecular sieve properties and the catalytic performance is discussed in detail. The paper ends with a discussion about the future trends of the research on postprocessing ZSM-22 for enhancing its quality and efficiency.
Key words:  alkane    hydroisomerization    ZSM-22 molecular sieve    postprocessing    reaction mechanism
出版日期:  2025-12-25      发布日期:  2025-12-17
ZTFLH:  TQ032  
  TE65  
通讯作者:  *伞晓广,博士,沈阳化工大学化学工程学院教授,博士研究生导师。目前主要从事功能纳米材料的设计、开发及其在碳一化工、工业催化以及气敏传感器应用等领域的研究工作。sanxiaoguang@syuct.edu.cn   
作者简介:  王智莹,沈阳化工大学化学工程学院硕士研究生,在校内导师伞晓广教授和联合培养单位导师的指导下开展庚烷临氢异构催化剂的相关研究。
引用本文:    
王智莹, 伞晓广, 苗昱露, 董磊. ZSM-22在烷烃加氢异构反应中应用的研究进展[J]. 材料导报, 2025, 39(24): 24120008-9.
WANG Zhiying, SAN Xiaoguang, MIAO Yulu, DONG Lei. Research Progress on Applying ZSM-22 to Alkane Hydroisomerization. Materials Reports, 2025, 39(24): 24120008-9.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.24120008  或          https://www.mater-rep.com/CN/Y2025/V39/I24/24120008
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