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材料导报  2025, Vol. 39 Issue (14): 24040018-9    https://doi.org/10.11896/cldb.24040018
  高分子与聚合物基复合材料 |
适于复合材料预浸料工艺的邻苯二甲腈树脂体系研究进展
徐祚炜, 唐俊, 廖维, 吴楠, 邢素丽, 杨金水, 尹昌平*
国防科技大学空天科学学院,长沙 410073
Research Progress on the Phthalonitrile Resin Suitable for Composite Prepreg Processing
XU Zuowei, TANG Jun, LIAO Wei, WU Nan, XING Suli, YANG Jinshui, YIN Changping*
College of Aerospace Science and Engineering, National University of Defence Technology, Changsha 410073, China
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摘要 邻苯二甲腈树脂,是一类以邻苯二甲腈结构封端的热固性树脂,因其固化后形成的独特芳杂环体型网络结构而表现出卓越的热稳定性、耐化学腐蚀性、阻燃性能以及低介电常数等特性,在航空航天、船舶制造以及电子封装等诸多领域展现出巨大的应用潜力。然而,苛刻的成型工艺条件成为制约邻苯二甲腈树脂及其复合材料进一步发展和应用的主要障碍,因此迫切需要改善邻苯二甲腈树脂的工艺性能。本文综述了适用于预浸料工艺的邻苯二甲腈树脂研究现状,深入探讨了分子结构设计、共混改性、添加填料以及预聚等各种改性方法对邻苯二甲腈预浸料性能的影响。同时,本文还对各种改性方法进行了比较分析,并对邻苯二甲腈预浸料未来的发展趋势进行了展望。
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徐祚炜
唐俊
廖维
吴楠
邢素丽
杨金水
尹昌平
关键词:  邻苯二甲腈  复合材料  预浸料  湿法工艺    
Abstract: Phthalonitrile resin, as a class of thermosetting resins capped with the phthalonitrile group, exhibits excellent thermal stability, chemical resis-tance, flame retardancy, and low dielectric constant due to the unique arylheterocyclic network structure formed after curing. Such optimal properties endow it with great potential for applications in many fields, such as aerospace, shipbuilding, and electronic packaging. However, the crucial conditions of the manufacturing process have become the major obstacle to the further development and application of phthalonitrile resin and its composites. Therefore, the improvement of the processing technology of phthalonitrile resin is highly demanded. This summary reviews the current research progress of phthalonitrile-based prepreg, and the influence of various modification methods, such as molecular structure design, blending, addition of fillers and pre-polymerization, on the properties of the prepregs is discussed in depth. At the same time, the future prospects of phthalonitrile prepregs have been put forward.
Key words:  phthalonitrile    composite material    prepreg    wet process
出版日期:  2025-07-25      发布日期:  2025-07-29
ZTFLH:  TB323  
基金资助: 国防科技大学自主创新科学基金(22-ZZCX-076:23-22CX-22GC-01-10)
通讯作者:  * 尹昌平,博士,国防科技大学空天科学学院教授、博士研究生导师。主要从事结构功能一体化树脂基复合材料的研究工作。ychangping@163.com   
作者简介:  徐祚炜,国防科技大学空天科学学院硕士研究生,在尹昌平教授的指导下进行研究。目前主要研究领域为耐高温树脂基复合材料。
引用本文:    
徐祚炜, 唐俊, 廖维, 吴楠, 邢素丽, 杨金水, 尹昌平. 适于复合材料预浸料工艺的邻苯二甲腈树脂体系研究进展[J]. 材料导报, 2025, 39(14): 24040018-9.
XU Zuowei, TANG Jun, LIAO Wei, WU Nan, XING Suli, YANG Jinshui, YIN Changping. Research Progress on the Phthalonitrile Resin Suitable for Composite Prepreg Processing. Materials Reports, 2025, 39(14): 24040018-9.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.24040018  或          https://www.mater-rep.com/CN/Y2025/V39/I14/24040018
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