溶胶-凝胶-燃烧法中双功能络合剂对掺铝氧化锌性能影响的研究

doi:10.11896/cldb.23100131

材料导报

2025, Vol. 39

Issue (1): 23100131-7 https://doi.org/10.11896/cldb.23100131

无机非金属及其复合材料

溶胶-凝胶-燃烧法中双功能络合剂对掺铝氧化锌性能影响的研究

孔德茹¹, 刘靖^2,*, 杨晓林¹, 孙冬兰¹, 张进康¹

1 天津科技大学理学院, 天津 300457
2 天津科技大学化工与材料学院, 天津 300457

Effect of Bi-functional Complexing Agent on Properties of Aluminum Doped Zinc Oxide in Sol-Gel-Combustion Method

KONG Deru¹, LIU Jing^2,*, YANG Xiaolin¹, SUN Donglan¹, ZHANG Jinkang¹

1 Faculty of Science, Tianjin University of Science and Technology, Tianjin 300457, China
2 School of Chemical Engineering and Materials, Tianjin University of Science and Technology, Tianjin 300457, China

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摘要本工作通过溶胶-凝胶-燃烧法在不同的双功能络合剂——乙醇胺(MEA)、柠檬酸(CA)或乙酰丙酮(ACAC)辅助下制备了(002)取向的掺铝氧化锌(AZO)粉末。对所制备粉末的物相结构、形貌和光学性能进行表征,进一步利用所制备的AZO粉末对亚甲基蓝溶液(MB)进行光催化降解研究。结果表明:采用不同的络合剂时,所有样品均为沿(002)方向择优取向的AZO粉末;其中以ACAC作络合剂时制备的AZO粉末呈粒径27.8 nm左右的球形结构,禁带宽度为3.129 eV,光致发光强度优于其他两种粉末,降解MB溶液的效率可达98%。

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	孔德茹
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	张进康

关键词: AZO粉末溶胶-燃烧-煅烧法络合剂光催化

Abstract: In this work, (002) oriented aluminum-doped zinc oxide (AZO) powder had been prepared with different bi-functional complexing agents—ethanolamine (MEA), citric acid (CA), or acetylacetone (ACAC) via the sol-gel-combustion method. X-ray powder diffraction (XRD), scanning electron microscope (SEM), UV-Vis spectroscope (UV-Vis) and photoluminescence spectroscope (PL) were applied to characterize the phase structure, morphology, and optical properties of the AZO prepared. Furthermore, these AZO powders were evaluated in the photocatalytic degradation of methylene blue solution (MB). The results showed that when different complexing agents were used, all powder products had the same pure phase structures of AZO with preferred orientation along the (002) direction;the AZO powder prepared with ACAC as the complexing agent demonstrated spherical particles with a particle of 27.8 nm, a bandgap width of 3.129 eV, and it's photoluminescence intensity was superior to the other two powders. It's efficiency of MB degradation solution could reach 98%.

Key words: AZO powder sol-gel-combustion method complexing agent photocatalysis

出版日期: 2025-01-10 发布日期: 2025-01-10

ZTFLH:

TQ132.41

基金资助: 国家自然科学基金(21373150)

通讯作者: *刘靖,天津科技大学化工与材料学院副教授。主要从事锂离子电池电解液中功能性有机添加剂的合成及应用研究,生物质聚合物合成及应用研究,纳米/微米结构的导电聚吡咯、聚苯胺及其复合物的相关科研工作。jingliu@tust.edu.cn

作者简介: 孔德茹,天津科技大学硕士研究生,在孙冬兰教授和刘靖副教授的指导下进行研究。目前主要研究方向为AZO透明导电薄膜及光催化AZO纳米粉末。

引用本文:

孔德茹, 刘靖, 杨晓林, 孙冬兰, 张进康. 溶胶-凝胶-燃烧法中双功能络合剂对掺铝氧化锌性能影响的研究[J]. 材料导报, 2025, 39(1): 23100131-7.
KONG Deru, LIU Jing, YANG Xiaolin, SUN Donglan, ZHANG Jinkang. Effect of Bi-functional Complexing Agent on Properties of Aluminum Doped Zinc Oxide in Sol-Gel-Combustion Method. Materials Reports, 2025, 39(1): 23100131-7.

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https://www.mater-rep.com/CN/10.11896/cldb.23100131 或 https://www.mater-rep.com/CN/Y2025/V39/I1/23100131

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