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材料导报  2024, Vol. 38 Issue (8): 23040216-6    https://doi.org/10.11896/cldb.23040216
  电化学能源材料与器件 |
二氧化碳电催化还原酸性体系研究进展
孙亚洲, 徐沙, 邹金含, 吴智华*, 谢顺吉*
厦门大学化学化工学院,固体表面物理化学国家重点实验室,能源材料化学协同创新中心,福建能源材料科学与技术创新实验室,福建 厦门 361005
Recent Developments in the Electrocatalytic Reduction of CO2 in Acidic Environments
SUN Yazhou, XU Sha, ZOU Jinhan, WU Zhihua*, XIE Shunji*
State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM), College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian, China
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摘要 利用可再生能源提供的电能电催化还原CO2制高值化学品和燃料,为全球气候变暖和能源危机提供了一种可行的解决方案,具有巨大的实际应用潜力。目前研究较多的碱性和中性反应体系中CO2易与氢氧根(OH-)反应生成碳酸盐或碳酸氢盐,造成CO2损失的同时会降低反应体系的能量转化效率和稳定性。研究开发酸性体系的电催化还原CO2反应(CO2RR),有望解决上述问题。本文针对CO2电催化还原的酸性体系展开讨论,系统整理了反应装置、催化剂、反应微环境对CO2RR性能的影响以及酸性体系中的微观反应机理,最后针对酸性体系中催化剂设计、反应机理研究、反应微环境调控、反应器设计优化等提出前瞻性建议。
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作者相关文章
孙亚洲
徐沙
邹金含
吴智华
谢顺吉
关键词:  二氧化碳  电催化  还原  酸性电解体系    
Abstract: Electrocatalytic conversion of CO2 into high-value chemicals and fuels by renewable energy provides a viable approach to the global climate change and energy crisis, and its development has great potential for practical production. At present, most of the basic and neutral reaction systems studied, CO2 is liable to interact with hydroxide (OH-) to form carbonate or bicarbonate, resulting in CO2 loss, lowering the energy conversion efficiency and stability of the reaction system. The above problems will be solved by the research and development of electrocatalytic CO2 reduction reaction (CO2RR) in acid. This review has shed light on the effects of reaction device, catalyst, reaction microenvironment on the performance of CO2RR and the microscopic reaction mechanism systematically in acidic CO2RR. Finally, foresight tactics are put forward for catalyst design, reaction mechanism research, reaction microenvironment regulation, and reactor design and optimization in acidic CO2RR.
Key words:  carbon dioxide    electrocatalysis    reduction    acidic electrolytes
出版日期:  2024-04-25      发布日期:  2024-04-28
ZTFLH:  O646  
基金资助: 国家自然科学基金(22022201);福建能源材料科学与技术创新实验室科技项目(RD2020020201)
通讯作者:  *吴智华,2012年福州大学本科毕业,2015年厦门大学硕士毕业,2015年至今任厦门大学能源材料化学协同创新中心和嘉庚创新实验室实验师,参与国家重大研究计划培育项目1项、国家自然科学基金面上项目1项,主持省级项目1项,在Biotechnology Letter、Molecules等学术刊物上发表论文5篇。wuzh@xmu.edu.cn
谢顺吉,厦门大学教授,博士研究生导师。2008年湖南大学本科毕业,2014年厦门大学博士毕业,2014—2018年厦门大学能源材料化学协同创新中心iChEM博士后和研究员,2018年入职厦门大学,2020年被聘为厦门大学化学化工学院教授、博士研究生导师。研究聚焦发展电催化和光催化新方法,将二氧化碳、甲烷、甲醇等碳一分子和可再生生物质分子选择性地催化转化为高值化学品,并研究催化反应机制及其调控的表界面化学。在Nature Catal.、Nature Commun.、Energy Environ.Sci.、Chem.Soc.Rev.、Chem、Angew.Chem.Int.Ed.、ACS Catal.等国际学术刊物上发表论文30余篇。shunji_xie@xmu.edu.cn   
作者简介:  孙亚洲,2021年6月于郑州大学获得工学学士学位。现为厦门大学化学化工学院硕士研究生,在谢顺吉教授的指导下进行研究。目前主要研究领域为CO2电催化还原制CO及乙烯等。
引用本文:    
孙亚洲, 徐沙, 邹金含, 吴智华, 谢顺吉. 二氧化碳电催化还原酸性体系研究进展[J]. 材料导报, 2024, 38(8): 23040216-6.
SUN Yazhou, XU Sha, ZOU Jinhan, WU Zhihua, XIE Shunji. Recent Developments in the Electrocatalytic Reduction of CO2 in Acidic Environments. Materials Reports, 2024, 38(8): 23040216-6.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.23040216  或          https://www.mater-rep.com/CN/Y2024/V38/I8/23040216
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