V-Ti-Fe三元合金显微组织、氢传输行为及耐蚀性能研究

doi:10.11896/cldb.22110007

材料导报

2024, Vol. 38

Issue (8): 22110007-7 https://doi.org/10.11896/cldb.22110007

金属与金属基复合材料

V-Ti-Fe三元合金显微组织、氢传输行为及耐蚀性能研究

马东帅¹, 闫二虎^1,2,*, 白金旺¹, 王豪¹, 张硕¹, 王艺豪¹, 李唐卫¹, 郭智洁¹, 周子锐¹, 邹勇进¹, 孙立贤^1,*

1 桂林电子科技大学广西信息材料重点实验室,广西桂林 541004
2 中南大学粉末冶金国家重点实验室,长沙 410083

Study on Microstructure, Hydrogen Transportation Behavior and Corrosion Resistance of V-Ti-Fe Alloy

MA Dongshuai¹, YAN Erhu^1,2,*, BAI Jinwang¹, WANG Hao¹, ZHANG Shuo¹, WANG Yihao¹, LI Tangwei¹, GUO Zhijie¹, ZHOU Zirui¹, ZOU Yongjin¹, SUN Lixian^1,*

1 Guangxi Key Laboratory of Information Materials, Guilin University of Electronic Technology, Guilin 541004, Guangxi, China
2 State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China

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摘要 Nb-Ti-Fe双相合金已被证实具有优异的渗氢性能,有望成为替代传统Pd膜的渗氢材料。V和Nb同属于5B族,具有类似的物理化学性质,但是,V-Ti-Fe双相合金组织转变规律和渗氢性能至今无人研究。基于此,本工作对V-Ti-Fe三元合金的显微组织和渗氢行为开展了详细研究,并探索了热处理和电化学腐蚀对改善渗氢性能的可能性。研究结果表明:V-Ti-Fe三元合金体系中存在一个包共晶凝固反应,即L+TiFe₂→Bcc-(V,Ti)+TiFe (1 626 K)。液相面投影图中存在三个相区,分别为TiFe相区、TiFe₂相区和Bcc-(V,Ti)相区。其中,TiFe相区合金室温组织由初生TiFe相和{Bcc-(V,Ti)+TiFe}共晶结构组成,TiFe₂相区合金室温组织由初生TiFe相、TiFe₂相和Bcc-(V,Ti)相构成,Bcc-(V,Ti)相区合金室温组织由初生Bcc-(V,Ti)相和TiFe相组成,渗氢性能测试证实了该系合金抗氢脆性能较弱。具体来说,上述三区域内部铸态合金在渗氢实验前均发生了不同程度的破碎,仅V_2.5Ti_62.5Fe₃₅合金能够渗氢,不过,该合金在渗氢后期发生断裂。最后,本工作采用电化学腐蚀和真空热处理两种方法改善该合金体系的渗氢性能,其中,V_2.5Ti_62.5Fe₃₅合金具有较高的耐腐蚀性能,经热处理后该合金的渗氢性能明显提升,其在623 K下的氢渗透性能为1.03×10^-9 mol H₂ m^-1·s^-1·Pa^-0.5。

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	马东帅
	闫二虎
	白金旺
	王豪
	张硕
	王艺豪
	李唐卫
	郭智洁
	周子锐
	邹勇进
	孙立贤

关键词: V-Ti-Fe合金显微组织热处理耐腐蚀性能渗氢性能

Abstract: Nb-Ti-Fe duplex alloys have been proven to have excellent hydrogen permeability, which are also expected to become a hydrogen permeable material to replace traditional Pd films. V and Nb belong to the same 5B group, with similar physical and chemical properties. However, the microstructure and hydrogen permeability changes of V-Ti-Fe have not been studied so far. Based on this, studying in detailed the microstructure and hydrogen transportation behavior of V-Ti-Fe ternary alloys, and the possibility of heat treatment and electrochemical corrosion for improving hydrogen permeability are explored. The results show that there is a quasiperitectic solidification reaction in the V-Ti-Fe ternary alloy system, determined as L+TiFe₂→V+TiFe (1 626 K). There are three phase regions in the liquid phase projection surface, containing of the TiFe phase region, the TiFe₂ phase region and the Bcc-(V, Ti) phase region. Among them, the room temperature structure of the TiFe phase alloy is composed of the primary TiFe phase and the {Bcc-(V, Ti)+TiFe} eutectic structure, the room temperature structure of the TiFe₂ phase alloy is composed of the primary TiFe phase, TiFe₂ phase and Bcc-(V, Ti) phase, and the room temperature structure of the Bcc-(V, Ti) phase alloy is composed of the primary Bcc-(V, Ti) phase and TiFe phase. Hydrogen permeability test confirmed that the alloy system has weak hydrogen embrittlement resistance. Specifically, the internal cast alloy in the above three regions has undergone different degrees of crushing during the hydrogen permeation experiment, and only the V_2.5Ti_62.5Fe₃₅ alloy can permeate hydrogen, but the alloy breaks during the hydrogen permeation process. Finally, the hydrogen permeability of the alloy system is improved by two methods, electrochemical corrosion and vacuum heat treatment. Of these alloys, V_2.5Ti_62.5Fe₃₅ alloy not only has high corrosion resistance, but also possesses excellent hydrogen permeability after heat treatment, and its hydrogen permeability is 1.03×10^-9 mol H₂ m^-1·s^-1·Pa^-0.5 at 623 K.

Key words: V-Ti-Fe alloy microstructure heat treatment corrosion resistance hydrogen permeability performance

出版日期: 2024-04-25 发布日期: 2024-04-28

ZTFLH:

TG139

基金资助: 国家自然科学基金(52161034;51761009;U20A20237);广西自然科学基金(2020GXNSFAA159163;2021GXNSFBA075057);广西八桂学者青年拔尖人才基金;桂林电子科技大学研究生教育创新计划项目(2023YCX155);广西信息材料重点实验室基金项目(211012-Z)

通讯作者: *闫二虎,桂林电子科技大学教授、博士研究生导师。2009年7月本科毕业于河北科技大学,2011年7月和2014年7月在哈尔滨工业大学分别取得工学硕士学位和工学博士学位,毕业后在桂林电子科技大学工作。2018年11月至2019年11月获广西高校优秀教师出国留学深造项目资助赴加拿大国家科学研究院信息-能源材料研究所进行为期一年的访学研究工作。主要从事合金定向凝固理论和新型能源材料方面的研究,主要包含相图热力学计算、多相合金凝固行为和新型渗氢/储氢性能的研究。近五年来在Journal of Membrane Science、Journal of Alloys and Compounds、International Journal of Hydrogen Energy、Journal of Crystal Growth、International Journal of Materials Research、《金属学报》等刊物上发表SCI文章80余篇,申请专利10余项。yeh@guet.edu.cn
孙立贤,桂林电子科技大学教授、博士研究生导师,俄罗斯自然科学院外籍院士,中科院优秀百人计划,广西优秀八桂学者,英国皇家化学会会士。1994年获湖南大学理学博士学位(师从俞汝勤院士);1995.2—1995.4任日本产业技术综合研究所客座研究员 (STA),1995.5—1996.10获洪堡基金(AvH)资助在德国耶拿大学无机分析化学研究所进行合作研究;1996.10—2002.9任日本工业技术院特别研究员(AIST)/产业技术研究员(NEDO)。在Energy & Environmental Science、Journal of Materials Chemistry A、Biosensors & Bioelectronics、Crystal Growth & Design、Journal of Physical Chemistry C、Dalton Transactions、International Journal of Hydrogen Energy等国内外重要学术刊物发表论文330余篇(其中SCI、EI收录300余篇)。sunlx@guet.edu.cn

作者简介: 马东帅,2020年6月毕业于河北科技大学;获得工学学士学位,现为桂林电子科技大学材料科学与工程学院硕士研究生,在闫二虎教授的指导下进行研究,目前主要研究领域为新型渗氢合金材料。

引用本文:

马东帅, 闫二虎, 白金旺, 王豪, 张硕, 王艺豪, 李唐卫, 郭智洁, 周子锐, 邹勇进, 孙立贤. V-Ti-Fe三元合金显微组织、氢传输行为及耐蚀性能研究[J]. 材料导报, 2024, 38(8): 22110007-7.
MA Dongshuai, YAN Erhu, BAI Jinwang, WANG Hao, ZHANG Shuo, WANG Yihao, LI Tangwei, GUO Zhijie, ZHOU Zirui, ZOU Yongjin, SUN Lixian. Study on Microstructure, Hydrogen Transportation Behavior and Corrosion Resistance of V-Ti-Fe Alloy. Materials Reports, 2024, 38(8): 22110007-7.

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https://www.mater-rep.com/CN/10.11896/cldb.22110007 或 https://www.mater-rep.com/CN/Y2024/V38/I8/22110007

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