六方氮化硼负载纳米氧化铝复合填料的制备及改性环氧涂层的防腐性能研究

doi:10.11896/cldb.22110089

材料导报

2024, Vol. 38

Issue (20): 22110089-6 https://doi.org/10.11896/cldb.22110089

高分子与聚合物基复合材料

六方氮化硼负载纳米氧化铝复合填料的制备及改性环氧涂层的防腐性能研究

颜蜀雋¹, 谭雅莉^2,*, 庞忠荣¹, 万鹏颖^2,3, 齐福刚^2,3

1 国家能源集团宁夏煤业有限责任公司,银川 750001
2 邦泽科技有限公司,湖南湘潭 411105
3 湘潭大学材料科学与工程学院,湖南湘潭 411105

Preparation of Hexagonal Boron Nitride Loaded Nano-alumina Composite Fillers and the Utility in Modifying Epoxy Corrosion Inhibition Coatings

YAN Shujun¹, TAN Yali^2,*, PANG Zhongrong¹, WAN Pengying^2,3, QI Fugang^2,3

1 National Energy Group Ningxia Coal Industry Co., Ltd., Yinchuan 750001, China
2 Hunan Bangzer Technology Co., Ltd., Xiangtan 411100, Hunan, China
3 School of Materials Science and Engineering, Xiangtan University, Xiangtan 411105, Hunan, China

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摘要将γ-氨基丙基三乙氧基硅烷(KH550)改性的Al₂O₃纳米颗粒负载在覆盖有聚多巴胺(PDA)的六方氮化硼(h-BN)片层表面,合成了一种新型的PDA-BN@f-Al₂O₃复合材料,然后将其作为填料分散在环氧树脂中制备复合环氧涂层。结果表明,PDA-BN@f-Al₂O₃复合材料在环氧树脂中具有良好的分散性,并且表现出主动缓蚀的效果。添加质量分数为1%的PDA-BN@f-Al₂O₃复合材料的环氧涂层表现出良好的阻隔性能以及长效防腐的效果,其低频区的阻抗模量(|Z|_{0.01 Hz})比纯环氧涂层高三个数量级,同时复合涂层的柔韧性也得到提升。

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	齐福刚

关键词: 六方氮化硼纳米氧化铝复合材料环氧树脂耐腐蚀性能

Abstract: A novel PDA-BN@f-Al₂O₃ nanohybrid was synthesized by depositing Al₂O₃ nanoparticles modified with γ-aminopropyl triethoxysilane (KH550) on the surface of hexagonal boron nitride (h-BN) sheets covered by polydopamine (PDA). Then the PDA-BN@f-Al₂O₃ hybrids was dispersed in epoxy resin to prepare composite coating samples. Various characterizations revealed that PDA-BN@f-Al₂O₃ hybrids showed good dispersibility in the epoxy resin, and had a corrosion inhibitive performance. The epoxy coating added with 1wt% PDA-BN@f-Al₂O₃ hybrids exhibited satisfactory performances of medium blocking and long-term corrosion resistance, as it achieved an impedance modulus in low frequency region (|Z|_{0.01 Hz}) three-order-magnitude higher than that of the pure epoxy coating and an improvement in flexibility.

Key words: h-BN nano-Al₂O₃ composite epoxy resin corrosion resistance

出版日期: 2024-10-25 发布日期: 2024-11-05

ZTFLH:

TQ638

基金资助: 宁夏回族自治区宁东基地科技创新发展专项(2019NDKJLX0008); 湖南省高新技术产业科技创新引领计划项目(2022GK4038)

通讯作者: * 谭雅莉,湖南邦泽科技有限公司工程师。2020年本科毕业于湖南工业大学印刷工程专业,2023年硕士毕业于湘潭大学材料科学与工程专业。目前主要从事高分子合成、重防腐多功能涂料等相关方向的研究。发表SCI论文2篇,中文期刊论文2篇。yalily_tan@outlook.com

作者简介: 颜蜀雋,国家能源集团宁夏煤业有限责任公司煤炭化学工业技术研究院高级工程师。主要从事催化转化及过程强化领域创新工作,参与国家、省部级科研项目10项,授权专利9项。

引用本文:

颜蜀雋, 谭雅莉, 庞忠荣, 万鹏颖, 齐福刚. 六方氮化硼负载纳米氧化铝复合填料的制备及改性环氧涂层的防腐性能研究[J]. 材料导报, 2024, 38(20): 22110089-6.
YAN Shujun, TAN Yali, PANG Zhongrong, WAN Pengying, QI Fugang. Preparation of Hexagonal Boron Nitride Loaded Nano-alumina Composite Fillers and the Utility in Modifying Epoxy Corrosion Inhibition Coatings. Materials Reports, 2024, 38(20): 22110089-6.

链接本文:

http://www.mater-rep.com/CN/10.11896/cldb.22110089 或 http://www.mater-rep.com/CN/Y2024/V38/I20/22110089

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