Abstract: High quality, low-cost, green synthesis and high efficiency transfer techniques are significantly important with the development for promoting the application of graphene and the whole graphene related industries. At present, chemical vapor deposition based on catalytic growth on metal surface has become a main method in synthesis of high quality and large area graphene. Film transfer techniques as a bridge connect synthesis and its application is playing an important role in the process of realizing industrialization application of graphene. Nowadays, graphene film transfer techniques are various direct and indirect transfer methods mainly used kinds of polymers as substrates or supporting materials. We introduced graphene transfer methods in single polymer transfer method, polymer of composite structure transfer method and other graphene film transfer methods. Also we made analysis and summary according to the character of each transfer method. The requirements and advantages of each class are described and compared. At the end, the future of graphene transfer technique is briefly introduced.
张自元, 门传玲, 曹军, 李振鹏, 赵明杰. 借助聚合物实现石墨烯转移的技术进展*[J]. 《材料导报》期刊社, 2017, 31(3): 130-135.
ZHANG Ziyuan, MEN Chuanling, CAO Jun, LI Zhenpeng, ZHAO Mingjie. Technological Advances in Realizing Graphene Transfer with the Help of Polymers. Materials Reports, 2017, 31(3): 130-135.
1 Novoselov K S, Geim A K, et al. Electric field effect in atomically thin carbon films[J].Science,2004,306(5696):666. 2 Koppens F H L, Mueller T, Avouris P, et al. Photodetectors based on graphene, other two-dimensional materials and hybrid systems[J]. Nature Nanotechnology,2014,9(10):780. 3 Butler S Z, Hollen S M, Cao L, et al. Progress, challenges, and opportunities in two-dimensional materials beyond graphene[J]. ACS Nano,2013,7(4):2898. 4 Nair R R, Blake P, Grigorenko A N, et al. Fine structure constant defines visual transparency of graphene[J]. Science,2008,320(5881):1308. 5 Lee C, Wei X, Kysar J W, et al. Measurement of the elastic properties and intrinsic strength of monolayer graphene[J]. Science,2008,321(5887):385. 6 Morozov S V, Novoselov K S, Katsnelson M I, et al. Giant intrinsic carrier mobilities in graphene and its bilayer[J]. Phys Rev Lett,2008,100(1):016602. 7 Bolotin K I, Sikes K J, Jiang Z, et al. Ultrahigh electron mobility in suspended graphene[J]. Solid State Commun,2008,146(9):351. 8 Du X, Skachko I, Barker A, et al. Approaching ballistic transport in suspended graphene[J]. Nature Nanotechnol,2008,3(8):491. 9 Novoselov K S, Fal V I, Colombo L, et al. A roadmap for graphene[J]. Nature,2012,490(7419):192. 10 Ren W, Cheng H M. The global growth of graphene[J]. Nature Nanotechnol,2014,9(10):726. 11 Zurutuza A, Marinelli C. Challenges and opportunities in graphene commercialization[J]. Nature Nanotechnology,2014,9(10):730. 12 Du Yan,Ji Tiezheng,Zhang Jiaoqiang,et al.Preparation and characterization of graphene nanosheets/high density polyethylene conductive composites[J]. J Aeronautical Mater,2013,33(1):68(in Chinese). 杜彦, 季铁正, 张教强, 等. 石墨烯/高密度聚乙烯导电复合材料的制备与表征[J]. 航空材料学报,2013,33(1):68. 13 Rao C N R, Sood A K, Subrahmanyam K S, et al. Graphene: The new two-dimensional nanomaterial[J]. Angew Chem Int Ed,2009,48(42):7752. 14 Qian Y, Lu S, Gao F. Preparation of MnO2/graphene composite as electrode material for supercapacitors[J]. J Mater Sci,2011,46(10):3517. 15 Yang X, Niu G, Cao X, et al. The preparation of functionalized graphene oxide for targeted intracellular delivery of siRNA[J]. J Mater Chem,2012,22(14):6649. 16 Kim I H, Jeong Y G. Polylactide/exfoliated graphite nanocomposites with enhanced thermal stability, mechanical modulus, and electrical conductivity[J]. J Polym Sci Part B: Polym Phys,2010,48(8):850. 17 Yu Q, Lian J, Siriponglert S, et al. Graphene segregated on Ni surfaces and transferred to insulators[J]. Appl Phys Lett,2008,93(11):113103. 18 Kim K S, Zhao Y, Jang H, et al. Large-scale pattern growth of graphene films for stretchable transparent electrodes[J]. Nature,2009,457(7230):706. 19 Li X, Cai W, An J, et al. Large-area synthesis of high-quality and uniform graphene films on copper foils[J]. Science,2009,324(5932):1312. 20 Reina A, Jia X, Ho J, et al. Large area, few-layer graphene films on arbitrary substrates by chemical vapor deposition[J]. Nano Lett,2008,9(1):30. 21 Bae S, Kim H, Lee Y, et al. Roll-to-roll production of 30-inch graphene films for transparent electrodes[J]. Nature Nanotechnol,2010,5(8):574. 22 Chandrashekar B N, Deng B, Smitha A S, et al. Roll-to-roll green transfer of CVD graphene onto plastic for a transparent and flexible triboelectric nanogenerator[J]. Adv Mater,2015,27(35):5210. 23 Wang Y, Tong S W, Xu X F, et al. Interface engineering of layer-by-layer stacked graphene anodes for high-performance organic solar cells[J]. Adv Mater,2011,23(13):1514. 24 Li X, Zhu Y, Cai W, et al. Transfer of large-area graphene films for high-performance transparent conductive electrodes[J]. Nano Lett,2009,9(12):4359. 25 Liang X, Sperling B A, Calizo I, et al. Toward clean and crackless transfer of graphene[J]. ACS Nano,2011,5(11):9144. 26 Caldwell J D, Anderson T J, Culbertson J C, et al. Technique for the dry transfer of epitaxial graphene onto arbitrary substrates[J]. ACS Nano,2010,4(2):1108. 27 Song J, Kam F Y, Png R Q, et al. A general method for transfering graphene onto soft surfaces[J]. Nature Nanotechnol,2013,8(5):356. 28 Lee Y, Bae S, Jang H, et al. Wafer-scale synthesis and transfer of graphene films[J]. Nano Lett,2010,10(2):490. 29 Shan Z, Li Q, Zhao Z,et al.One-step transfer and doping of large area graphene by ultraviolet curing adhesive[J]. Carbon,2015,84:9. 30 Kim K K, Reina A, Shi Y, et al. Enhancing the conductivity of transparent graphene films via doping[J]. Nanotechnology,2010,21(28):285205. 31 Deng B, Hsu P C, Chen G, et al. Roll-to-roll encapsulation of metal nanowires between graphene and plastic substrate for high-perfor-mance flexible transparent electrodes[J]. Nano Lett,2015,15(6):4206. 32 Man H, Yunlong G, Bin W, et al. Progress in transfer techniques of graphene synthesized by chemical vapor deposition[J].Chemistry,2012,75(11):974(in Chinese). 黄曼,郭云龙,武斌,等.化学气相沉积法合成石墨烯的转移技术研究进展[J].化学通报,2012,75(11):974. 33 Lock E H, Baraket M, Laskoski M, et al. High-quality uniform dry transfer of graphene to polymers[J]. Nano Lett,2011,12(1):102. 34 Park J, Hann S, Lu Y. Synthesis of graphene pattern using laser-induced chemical vapor deposition[C]//SPIE LASE. International Society for Optics and Photonics,2014:896813. 35 Marta B, Leordean C, Istvan T, et al. Efficient etching-free transfer of high quality, large-area CVD grown graphene onto polyvinyl alcohol films[J]. Appl Surf Sci,2016,363:613. 36 Cai Wei, Wang Cong, Fang Xiaohong, et al. Progress in transfer technologies and related supporting materials for grapheme film synthesized by chemical vapor deposition[J]. Mater Mechanical Eng,2015,39(11):7(in Chinese). 蔡伟, 王聪, 方小红,等.化学气相沉积生长石墨烯薄膜转移方法及转移用支撑材料的研究进展[J].机械工程材料,2015,39(11):7. 37 Fang W, Hsu A L, Song Y, et al. Asymmetric growth of bilayer graphene on copper enclosures using low-pressure chemical vapor deposition[J]. ACS Nano,2014,8(6):6491. 38 Jeong H J, Kim H Y, Jeong S Y, et al. Improved transfer of chemical-vapor-deposited graphene through modification of intermolecular interactions and solubility of poly (methylmethacrylate) layers[J]. Carbon,2014,66:612. 39 Martins L G P, Song Y, Zeng T, et al. Direct transfer of graphene onto flexible substrates[J]. Proceedings National Academy Sciences,2013,110(44):17762. 40 Verma V P, Das S, Lahiri I, et al. Large-area graphene on polymer film for flexible and transparent anode in field emission device[J]. Appl Phys Lett,2010,96(20):203108. 41 Wang D Y, Huang I, Ho P H, et al. Clean-lifting transfer of large-area residual-free graphene films[J]. Adv Mater,2013,25(32):4521. 42 Cherian C T, Giustiniano F, Martin-Fernandez I, et al. ‘Bubble-free’ electrochemical delamination of CVD graphene films[J]. Small,2015,11(2):189. 43 Suk J W, Kitt A, Magnuson C W, et al. Transfer of CVD-grown monolayer graphene onto arbitrary substrates[J]. ACS Nano,2011,5(9):6916. 44 Lin Y C, Lu C C, Yeh C H, et al. Graphene annealing: How clean can it be?[J]. Nano Lett,2011,12(1):414. 45 Suk J W, Lee W H, Lee J, et al. Enhancement of the electrical properties of graphene grown by chemical vapor deposition via controlling the effects of polymer residue[J]. Nano Lett,2013,13(4):1462. 46 Her M, Beams R, Novotny L. Graphene transfer with reduced residue[J]. Phys Lett A,2013,377(21):1455. 47 Barin G B, Song Y, de Fátima Gimenez I, et al. Optimized graphene transfer: Influence of polymethylmethacrylate (PMMA) layer concentration and baking time on graphene final performance[J]. Carbon,2015,84:82. 48 Cha S, Cha M, Lee S, et al. Low-temperature, dry transfer-printing of a patterned graphene monolayer[J]. Sci Rep,2015,5:17877. 49 Chen X D, Liu Z B, Zheng C Y, et al. High-quality and efficient transfer of large-area graphene films onto different substrates[J]. Carbon,2013,56:271. 50 Kang J, Shin D, Bae S, et al. Graphene transfer: Key for applications[J]. Nanoscale,2012,4(18):5527. 51 Fechine G J M, Martin-Fernandez I, Yiapanis G, et al. Direct dry transfer of chemical vapor deposition graphene to polymeric substrates[J]. Carbon,2015,83:224. 52 Cai C, Jia F, Li A, et al. Crackless transfer of large-area graphene films for superior-performance transparent electrodes[J]. Carbon,2016,98:457. 53 Hiranyawasit W, Punpattanakul K, Pimpin A, et al. A novel me-thod for transferring graphene onto PDMS[J]. Appl Surf Sci,2015,358:70. 54 Zhu Y, Murali S, Cai W, et al. Graphene and graphene oxide: Synthesis, properties, and applications[J]. Adv Mater,2010,22(35):3906. 55 Kang J,Hwang S,Kim J H,et al.Efficient transfer of large-area graphene films onto rigid substrates by hot pressing [J].ACS Nano,2012,6(6):5360. 56 Chen Mu, Yan Yue, Zhang Xiaofeng, et al. Advances in large-area graohene film transfer techniques[J]. J Aeronautical Mater,2015,35(2):1(in Chinese). 陈牧,颜悦,张晓锋,等.大面积石墨烯薄膜转移技术研究进展[J].航空材料学报,2015,35(2):1. 57 Yamada T, Ishihara M, Kim J, et al. A roll-to-roll microwave plasma chemical vapor deposition process for the production of 294 mm width graphene films at low temperature[J]. Carbon,2012,50(7):2615. 58 Yamada T, Ishihara M, Hasegawa M. Large area coating of graphene at low temperature using a roll-to-roll microwave plasma chemical vapor deposition[J]. Thin Solid Films,2013,532:89. 59 Ryu J, Kim Y, Won D, et al. Fast synthesis of high-performance graphene films by hydrogen-free rapid thermal chemical vapor deposition[J]. ACS Nano,2014,8(1):950. 60 Hong B H,Ahn J,Kim H K,et al.Roll-to-roll doping method of graphene film, and doped graphene film: US 8926854[P].2015-01-06. 61 Kobayashi T, Bando M, Kimura N, et al. Production of a 100-m-long high-quality graphene transparent conductive film by roll-to-roll chemical vapor deposition and transfer process[J]. Appl Phys Lett,2013,102(2):023112. 62 Wood J D, Doidge G P, Carrion E A, et al. Annealing free, clean graphene transfer using alternative polymer scaffolds[J]. Nanotechnology,2015,26(5):055302. 63 Lupina G, Kitzmann J, Costina I, et al. Residual metallic contamination of transferred chemical vapor deposited graphene[J]. ACS Nano,2015,9(5):4776. 64 Anagnostopoulos G, Androulidakis C, Koukaras E N, et al. Stress transfer mechanisms at the submicron level for raphene/polymer systems[J]. ACS Appl Mater Interfaces,2015,7(7):4216.
渝公网安备50019002502923号 版权所有：《材料导报》编辑部
2017, Vol. 31 
