聚酰亚胺材料的抗原子氧防护技术研究进展

doi:10.11896/cldb.23080220

材料导报

2024, Vol. 38

Issue (23): 23080220-10 https://doi.org/10.11896/cldb.23080220

高分子与聚合物基复合材料

聚酰亚胺材料的抗原子氧防护技术研究进展

袁璐¹, 许旻^1,*, 李毅¹, 王虎¹, 高恒蛟¹, 高文生^2,*, 李中华¹, 何延春¹

1 中国空间技术研究院兰州空间技术物理研究所,真空技术与物理重点实验室,兰州 730000
2 兰州大学化学化工学院,兰州 730000

Advanced Progress of Atomic Oxygen Resistant Techniques on Polyimide Materials

YUAN Lu¹, XU Min^1,*, LI Yi¹, WANG Hu¹, GAO Hengjiao¹, GAO Wensheng^2,*, LI Zhonghua¹, HE Yanchun¹

1 Science and Technology on Vacuum Technology and Physics Laboratory, Lanzhou Institute of Physics, China Academy of Space Technology, Lanzhou 730000, China
2 College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China

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摘要低地球轨道环境中的原子氧具有高通量和强氧化性,会快速侵蚀航天器表面的聚酰亚胺材料,造成材料严重失效。针对聚酰亚胺材料抵抗原子氧侵蚀能力不足的问题,国内外研究人员积极探索,已提出多种抗原子氧防护技术,这些技术方案可分为包覆法、基体调控和外加涂层防护三个方面。此外,本文还整理了计算模拟探究抗原子氧防护效果的主要策略,指出计算与实验相结合有助于提高材料模型的准确性以及对抵抗原子氧侵蚀效果的预测能力。本文结合航天工程的实际应用,合理分析这三类防护措施的优势与不足,系统总结出不同聚酰亚胺基复合材料的抗原子氧防护性能。最后,对聚酰亚胺材料抗原子氧防护技术的研究工作进行总结,并展望了未来发展趋势。

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	袁璐
	许旻
	李毅
	王虎
	高恒蛟
	高文生
	李中华
	何延春

关键词: 原子氧低地球轨道防护涂层聚合物材料侵蚀率

Abstract: Atomic oxygen (AO) in low earth orbit environment has high flux and strong oxidizing properties. It can erode rapidly the polyimide on the surface of the spacecraft, causes serious material failure. Researchers have explored many positive solutions to the problem of weak AO resis-tance of polyimide, and there are three main types of these technical approaches, i.e. cladding blanket, matrix modification and coating protection. Besides, the main strategies for numerical simulation technique of AO resistant effect were also summarized. It showed that combination of simulation and experiment could improve the model accuracy and the predictive ability of AO resistant effect. In this work, the advantages and disadvantages of these solutions were analyzed according to the aerospace engineering, and then we systematically summarized resistance abilities of different polyimide materials. Overall, we summed up the AO resistant techniques of polyimide materials clearly and prospected their future development tendency.

Key words: atomic oxygen low earth orbit protective coating polymer erosion yield

出版日期: 2024-12-10 发布日期: 2024-12-10

ZTFLH:

V45

基金资助: 国家重点研发计划(2022YFB3806300);国家自然科学基金(U1937601;12305289);国防基础科研项目(JCKY2020203B019);甘肃省自然科学基金(23JRRA1363)

通讯作者: * 许旻,1994年毕业于哈尔滨工业大学电气工程专业本科,2006年兰州大学凝聚态物理专业博士毕业。研究员,现就职兰州空间技术物理研究所,长期从事表面工程、先进材料和装备技术研究工作。现为中国空间技术研究院物理电子学博士研究生导师、产品首席专家,航天科技集团公司表面工程工艺首席专家。长期科研工作中,研制的多种产品在航天型号中成功应用,承担过多项国家重大基础科研和工程类项目的研究工作,在科研工作中发表论文30余篇,包含Composites Part B、ACS Applied Polymer Material、Diamond and Related Material、Composite Interfaces等。授权专利25项,获多项国防和省科技进步奖。xmsurface@126.com
高文生,兰州大学化学化工学院博士,从事博士后研究(合作导师:李灿院士)。2013年中国海洋大学材料化学专业本科毕业,2018年兰州大学材料物理与化学博士毕业,2018—2019年兰州空间物理技术研究所从事空间站原子氧防护工作。2019年至今,兰州大学物理化学专业从事博士后研究工作。目前主要从事聚合物纳米复合材料的结构设计及应用开发等方面的研究工作。以第一作者及通信作者身份在Advanced Materials、Composites Part A、Composites Part B等专业领域期刊发表论文10余篇,申请国家发明专利3项。gaowsh13@lzu.edu.cn

作者简介: 袁璐,2018年6月、2022年6月分别于南京理工大学和上海大学获得工学学士学位和硕士学位。现为中国空间技术研究院兰州空间技术物理研究所博士研究生,在许旻研究员的指导下进行研究。目前主要研究领域为原子氧防护与涂层材料方向。

引用本文:

袁璐, 许旻, 李毅, 王虎, 高恒蛟, 高文生, 李中华, 何延春. 聚酰亚胺材料的抗原子氧防护技术研究进展[J]. 材料导报, 2024, 38(23): 23080220-10.
YUAN Lu, XU Min, LI Yi, WANG Hu, GAO Hengjiao, GAO Wensheng, LI Zhonghua, HE Yanchun. Advanced Progress of Atomic Oxygen Resistant Techniques on Polyimide Materials. Materials Reports, 2024, 38(23): 23080220-10.

链接本文:

http://www.mater-rep.com/CN/10.11896/cldb.23080220 或 http://www.mater-rep.com/CN/Y2024/V38/I23/23080220

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