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材料导报  2025, Vol. 39 Issue (14): 24060008-11    https://doi.org/10.11896/cldb.24060008
  金属与金属基复合材料 |
高温太阳光谱选择性吸收涂层的研究进展
豆裕, 范同祥*
上海交通大学材料科学与工程学院、金属基复合材料国家重点实验室,上海 200240
Research Progress of High-temperature Solar Selectively Absorptive Coatings
DOU Yu, FAN Tongxiang*
State Key Laboratory of Metal Matrix Composites, School of Materials Science and Engineering, Shanghai Jiao Tong University, shanghai 200240, China
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摘要 光热转换是当前世界范围内最普及和最常见的太阳能利用方式,而同时具有高太阳能吸收率和低红外发射率的太阳光谱选择性吸收涂层可以显著提高光热转换效率。与中低温(0＜T＜400 ℃)应用的太阳光谱选择性吸收涂层相比,高温(T≥400 ℃)太阳光谱选择性吸收涂层表现了巨大的发展潜力和应用前景。然而太阳光谱选择性吸收涂层在高温下的老化和失效问题制约了其在高温领域的应用。因此,迫切需要开发具有出色光谱选择性和高温热稳定性的选择性吸收涂层。本文从太阳光谱选择性吸收涂层的设计机理出发,总结了具有高温热稳定性的吸收涂层的类型和最新研究进展,主要包括双金属陶瓷、过渡金属化合物和高熵合金氮化物多层结构三大类,并分类讨论了其主要的失效机制和热稳定性增强策略。在此基础上探讨了各种耐高温吸收涂层的制备工艺,并综述了加速老化试验与寿命预测。最后指出并展望了高温太阳光谱选择性吸收涂层面临的问题及研究方向。
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豆裕
范同祥
关键词:  高温太阳光谱选择性吸收涂层  光热转换  热稳定性  加速老化试验  寿命预测    
Abstract: Photothermal conversion is currently the most popular and common way of solar energy utilizing worldwide, and solar selectively absorptive coating with high solar absorption and low infrared emissivity can significantly improve the efficiency. Compared with absorptive coatings used in medium and low temperatures (0＜T＜400 ℃), high temperature (T≥400 ℃) solar selectively absorptive coatings show great potential for development and applicative prospects. However, the aging and failure of them at high-temperatures limit their applications. Therefore, there is an urgent need to develop solar selectively absorptive coatings with excellent spectral selectivity and high-temperature thermal stability. In this paper, the design mechanism of solar selectively absorptive coating is outlined. And the types and latest developments of absorptive coatings with high-temperature thermal stability are summarized, mainly including bimetallic ceramics, transition metal compounds, and high-entropy alloy nitride multilayer structures. The main failure mechanisms and thermal stability enhancement strategies are classified and discussed. At the same time, the preparation processes of various high-temperature absorptive coatings are discussed, and accelerated aging tests and life predictive methods are summarized. Finally the problems and research directions faced by high-temperature solar selectively absorptive coatings are pointed out and discussed.
Key words:  high-temperature solar selectively absorptive coating    photothermal conversion    thermal stability    accelerated aging test    life prediction
出版日期:  2025-07-25      发布日期:  2025-07-29
ZTFLH:  TK51  
  TB34  
基金资助: 上海市科委项目(21511103400)
通讯作者:  * 范同祥,博士,上海交通大学材料学院教授、博士研究生导师。目前主要从事特种功能金属基复合材料和生物启迪功能材料方面的研究。txfan@sjtu.edu.cn   
作者简介:  豆裕,上海交通大学材料科学与工程学院硕士研究生,在范同祥教授的指导下进行研究。目前主要研究领域为基于仿生微纳米结构的太阳光谱选择性吸收涂层。
引用本文:    
豆裕, 范同祥. 高温太阳光谱选择性吸收涂层的研究进展[J]. 材料导报, 2025, 39(14): 24060008-11.
DOU Yu, FAN Tongxiang. Research Progress of High-temperature Solar Selectively Absorptive Coatings. Materials Reports, 2025, 39(14): 24060008-11.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.24060008  或          https://www.mater-rep.com/CN/Y2025/V39/I14/24060008
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