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材料导报  2024, Vol. 38 Issue (20): 23050199-7    https://doi.org/10.11896/cldb.23050199
  高分子与聚合物基复合材料 |
加成型液体硅橡胶的研究及应用进展
刘佳杰, 后振中*, 杨庆浩*, 赵秋丽
西安科技大学材料科学与工程学院,西安 710054
Research Progress of Additive Liquid Silicone Rubber
LIU Jiajie, HOU Zhenzhong*, YANG Qinghao*, ZHAO Qiuli
School of Materials Science and Engineering, Xi’an University of Science and Technology, Xi’an 710054, China
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摘要 加成型液体硅橡胶(ALSR)是硅氢加成反应在硅橡胶固化交联领域中的一个重要应用。因为是加成交联,ALSR在固化过程中不产生副产物,收缩率极小,能深层固化且对接触的材料无腐蚀,所以加工成型时无气泡、砂眼,尺寸稳定,具有优良的耐热冲击性能,在诸多领域有着重要应用价值。本文首先简述了ALSR的基本组成与固化机理,然后以性能为切入点综述了近年来ALSR在机械、导热、粘结和阻燃等性能方面的研究进展,以及在电子电气、医疗、3D打印、光学和汽车领域的应用,最后提出高性能、多功能、复合化和先进加工是未来ALSR的发展方向。
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刘佳杰
后振中
杨庆浩
赵秋丽
关键词:  加成型液体硅橡胶  固化机理  性能  应用    
Abstract: Addition liquid silicone rubber (ALSR) is an important application of hydrosilylation addition reaction in the field of silicone rubber curing and crosslinking. As it is crosslinked by addition, ALSR does not produce by-products during the curing process, has very small shrinkage, can be deeply solidified, and has no corrosion to the materials in contact. Therefore, there are no bubbles and sand holes during processing and molding, with stable size, excellent heat shock resistance, and has important application value in many fields. This article first outlines the basic composition and curing mechanism of ALSR, and then reviews the research progress in mechanical, thermal, adhesive, and flame retardant properties of ALSR in recent years, as well as its applications in the fields of electronic and electrical, medical, 3D printing, optical, and automotive. Finally, it proposes that high-performance, multifunctional, composite, and advanced processing are the future development directions of ALSR.
Key words:  addition type liquid silicone rubber    curing mechanism    properties    application
出版日期:  2024-10-25      发布日期:  2024-11-05
ZTFLH:  TQ333.93  
基金资助: 陕西省重点研发计划(2023-YBGY-448);榆林市科技计划项目(CXY-2022-160)
通讯作者:  * 后振中,西安科技大学材料科学与工程学院讲师。2010年在同济大学获得材料学工学博士学位。主要研究方向为导电聚合物基新能源材料和功能性软材料。在国内外学术期刊上发表论文30余篇,其中被SCI、EI、ISTP收录20余篇,ESI高被引热点论文1篇;获得发明专利授权3项。hzzhong1981@163.com
杨庆浩,西安科技大学材料科学与工程学院副教授、硕士研究生导师。2001—2002在日本大阪大学应用化学专业进行特别研究,2008年在西安交通大学取得材料科学与工程专业博士学位。目前主要研究方向为功能高分子材料。发表期刊论文30余篇,其中被SCI、EI、ISTP收录10余篇;获批发明专利3项、实用新型专利2项、软件著作权1项,参与编写著作2部。yangxjtu@hotmail.com   
作者简介:  刘佳杰,2021年7月于西安科技大学获得工学学士学位。现为西安科技大学材料科学与工程学院硕士研究生,在杨庆浩副教授和后振中讲师的指导下进行研究。目前主要从事功能材料研究。
引用本文:    
刘佳杰, 后振中, 杨庆浩, 赵秋丽. 加成型液体硅橡胶的研究及应用进展[J]. 材料导报, 2024, 38(20): 23050199-7.
LIU Jiajie, HOU Zhenzhong, YANG Qinghao, ZHAO Qiuli. Research Progress of Additive Liquid Silicone Rubber. Materials Reports, 2024, 38(20): 23050199-7.
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http://www.mater-rep.com/CN/10.11896/cldb.23050199  或          http://www.mater-rep.com/CN/Y2024/V38/I20/23050199
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