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材料导报  2024, Vol. 38 Issue (19): 23050176-5    https://doi.org/10.11896/cldb.23050176
  高分子与聚合物基复合材料 |
PDMS包封CPCM制备三明治结构织物及热性能分析
张维1,2,*, 张义博1, 张琪1, 姚继明1,2, 郝尚1
1 河北科技大学纺织服装学院,石家庄 050018
2 河北省纺织服装技术创新中心,石家庄 050018
Fabrication of Sandwich Structured Fabric with PDMS Encapsulated CPCM and Its Thermal Performance Analysis
ZHANG Wei1,2,*, ZHANG Yibo1, ZHANG Qi1, YAO Jiming1,2, HAO Shang1
1 College of Textile and Garment, Hebei University of Science and Technology, Shijiazhuang 050018, China
2 Hebei Technology Innovation Center for Textile and Garment, Shijiazhuang 050018, China
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摘要 为解决正十八烷在使用过程中的相泄露问题,以细菌纤维素膜为支撑载体、聚二甲基硅氧烷为包封材料,通过真空浸渍和热固处理制备形稳性复合相变材料。正十八烷浸渍率高达84.9%,潜热能为212.70 J/g,可经受100次热循环测试。经180°弯折后回弹角为156.4°,回弹角相较于包封前提高了131.7%。以复合相变材料为中间层、涤棉混纺织物为外层,经由聚二甲基硅氧烷粘合和固化处理,制得三明治结构织物。吸热饱和后,三明治织物表面温度比普通织物延时降温310 s,在日照模型和人体热管理测试中其覆盖的空间内部温度比普通织物覆盖处降低0.9 ℃,显示出优异的储热和隔热性能。
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张维
张义博
张琪
姚继明
郝尚
关键词:  细菌纤维素膜  正十八烷  柔性复合相变材料  三明治结构织物  高潜热    
Abstract: In order to solve the problem of phase leakage in the use of octadecane, the composite phase change material (CPCM) with shape stability was prepared by vacuum impregnation and thermosetting treatment with bacterial cellulose membrane as support carrier and polydimethylsiloxane (PDMS) as encapsulation material. The impregnation rate of octadecane was as high as 84.9% with the latent heat energy of 212.70 J/g, and it could withstand 100 thermal cycle tests. After 180 bending, the recovery angle was 156.4°, which was 131.7% higher than that before encapsulation. Sandwich structured fabric (ss-F) was produced with CPCM as the inner layer and polyester-cotton blended fabric as the outer layer through PDMS bonding and curing process. After the saturation of heat absorption, the surface temperature of ss-F was 310 s cooler than that of ordinary fabric with delay. In the sunshine model and human thermal management test, the internal temperature of the space covered by it is 0.9 ℃ lower than that covered by ordinary fabric, which showed excellent thermal storage and insulation performance.
Key words:  bacterial cellulose membrane    octadecane    flexible composite phase change material    sandwich structured fabric    high latent heat
出版日期:  2024-10-10      发布日期:  2024-10-23
ZTFLH:  TB34  
  TS195.597  
基金资助: 河北省自然科学基金(B2022208014);河北省省属高校基本科研业务费专项资金(2021YWF17)
通讯作者:  *张维,通信作者,2014年10月于天津工业大学获得工学博士学位。现任河北科技大学纺织服装学院副教授、硕士研究生导师。目前主要研究领域为印染废水电化学高效处理技术与资源回用、医疗防护与卫生健康用纺织品的开发、纺织品绿色前处理及染色加工技术等。weizhang2999@163.com   
引用本文:    
张维, 张义博, 张琪, 姚继明, 郝尚. PDMS包封CPCM制备三明治结构织物及热性能分析[J]. 材料导报, 2024, 38(19): 23050176-5.
ZHANG Wei, ZHANG Yibo, ZHANG Qi, YAO Jiming, HAO Shang. Fabrication of Sandwich Structured Fabric with PDMS Encapsulated CPCM and Its Thermal Performance Analysis. Materials Reports, 2024, 38(19): 23050176-5.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.23050176  或          http://www.mater-rep.com/CN/Y2024/V38/I19/23050176
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