金属卤化物钙钛矿纳米晶体/聚合物复合材料的研究进展

doi:10.11896/cldb.23040056

材料导报

2024, Vol. 38

Issue (15): 23040056-10 https://doi.org/10.11896/cldb.23040056

高分子与聚合物基复合材料

金属卤化物钙钛矿纳米晶体/聚合物复合材料的研究进展

孙元杰¹, 李志刚^1,2, 王艺¹, 田波¹, 李金凤¹, 张楠^1,2, 赵浚峰², 张建伟¹, 李拓¹, 赵弘韬^1,2,*

1 黑龙江省原子能研究院,哈尔滨 150081
2 哈尔滨工程大学核科学与技术学院,哈尔滨 150006

Research Progress of Metal Halide Perovskite Nanocrystalline/Polymer Composites

SUN Yuanjie¹, LI Zhigang^1,2, WANG Yi¹, TIAN Bo¹, LI Jinfeng¹, ZHANG Nan^1,2, ZHAO Junfeng², ZHANG Jianwei¹, LI Tuo¹, ZHAO Hongtao^1,2,*

1 Heilongjiang Institute of Atomic Energy, Harbin 150081, China
2 School of Nuclear Science and Technology, Harbin Engineering University, Harbin 150006, China

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摘要金属卤化物钙钛矿纳米晶体因其独特的光电特性,在光伏和光电等领域展现了巨大的应用前景,受到广泛的研究关注。但钙钛矿纳米晶体本身的离子晶体性质使其在水、热等环境下不稳定,从而限制了其实际应用。金属卤化物钙钛矿纳米晶体可以与聚合物结合形成纳米复合材料,具有许多优越的特性。聚合物基体可以赋予复合材料稳定性、可拉伸性和溶液加工性,而纳米晶体可保持其尺寸、形状和组成相关的光电特性。因此,这些纳米复合材料在下一代显示器、照明、传感、生物医学技术和能量转换等领域具有巨大的潜力。本文总结了金属卤化物钙钛矿纳米晶/聚合物纳米复合材料的最新研究进展。首先,讨论了制备金属卤化物钙钛矿纳米晶体/聚合物复合材料的各种合成策略。其次,介绍了金属卤化物钙钛矿纳米晶体/聚合物复合材料在发光二极管、激光和闪烁体等领域的应用。最后,提出了该领域未来的研究方向和挑战。

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	孙元杰
	李志刚
	王艺
	田波
	李金凤
	张楠
	赵浚峰
	张建伟
	李拓
	赵弘韬

关键词: 金属卤化物钙钛矿纳米晶体聚合物复合材料

Abstract: Metal halide perovskite nanocrystals have attracted extensive research attention due to their unique photoelectric properties, showing great application prospects in photovoltaic and optoelectronic fields. However, due to the ionic crystal properties of perovskite nanocrystals, they are unstable in water, heat and other environments, which limits their practical application. Metal halide perovskite nanocrystals can be combined with polymers to form nanocomposites with many superior properties. Polymer matrix can endow composites with stability, stretchability and solution processability, while nanocrystals can maintain their size, shape and composition-related photoelectric properties. Therefore, these nanocomposites have great potential in the fields of next-generation displays, lighting, sensing, biomedical technology and energy conversion. This paper summarizes the latest research progress of metal halide perovskite nanocrystals/polymer nanocomposites. Firstly, various synthesis strategies for preparing perovskite nanocrystals/polymer composites are discussed. Secondly, the applications of metal halide perovskite nanocrystals/polymer composites in light-emitting diodes, lasers and scintillators are discussed. Finally, the future research directions and challenges in this field are proposed.

Key words: metal halide perovskite nanocrystalline polymer composites

出版日期: 2024-08-10 发布日期: 2024-08-29

ZTFLH:	O632
	TB381

基金资助: 黑龙江省自然科学基金(LH2022A024);黑龙江省科学院自然科学基金(YZ2022YZN01);黑龙江省属科研院所科研业务费(CZKYF2022-1-C032);黑龙江应用技术研发计划(GA20C011);黑龙江大学功能无机材料化学教育部重点实验室开放课题

通讯作者: * 赵弘韬,博士,黑龙江省原子能研究院研究员、博士研究生导师。2010年博士毕业于哈尔滨工业大学。目前主要从事核技术应用及辐射防护研究。发表论文40余篇,包括Journal of Materials Chemistry A、 Journal of Chemical Physics、 Process Safety and Environmental Protection等。zhaohongtao2019@163.com

作者简介: 孙元杰,2021年6月于济宁学院获得理学学士学位。现为黑龙江省科学院硕士研究生,在赵弘韬研究员的指导下开展柔性钙钛矿辐射探测材料的应用研究。

引用本文:

孙元杰, 李志刚, 王艺, 田波, 李金凤, 张楠, 赵浚峰, 张建伟, 李拓, 赵弘韬. 金属卤化物钙钛矿纳米晶体/聚合物复合材料的研究进展[J]. 材料导报, 2024, 38(15): 23040056-10.
SUN Yuanjie, LI Zhigang, WANG Yi, TIAN Bo, LI Jinfeng, ZHANG Nan, ZHAO Junfeng, ZHANG Jianwei, LI Tuo, ZHAO Hongtao. Research Progress of Metal Halide Perovskite Nanocrystalline/Polymer Composites. Materials Reports, 2024, 38(15): 23040056-10.

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http://www.mater-rep.com/CN/10.11896/cldb.23040056 或 http://www.mater-rep.com/CN/Y2024/V38/I15/23040056

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