水性丙烯酸交通标线涂料研究现状与发展趋势

doi:10.11896/cldb.22120007

材料导报

2024, Vol. 38

Issue (21): 22120007-12 https://doi.org/10.11896/cldb.22120007

高分子与聚合物基复合材料

水性丙烯酸交通标线涂料研究现状与发展趋势

郑直¹, 郭乃胜^1,*, 金鑫^1,2, 房辰泽¹, 尤占平³, 谭忆秋⁴

1 大连海事大学交通运输工程学院,辽宁大连 116026
2 沈阳建筑大学交通与测绘工程学院,沈阳 110168
3 密歇根理工大学土木与环境工程系,密歇根霍顿 MI49931
4 哈尔滨工业大学交通科学与工程学院,哈尔滨 150090

Research Advances and Development Trends of Acrylic Acid-based Waterborne Traffic Marking Paints

ZHENG Zhi¹, GUO Naisheng^1,*, JIN Xin^1,2, FANG Chenze¹, YOU Zhanping³, TAN Yiqiu⁴

1 College of Transportation Engineering, Dalian Maritime University, Dalian 116026, Liaoning, China
2 School of Transportation and Geomatics Engineering, Shenyang Jianzhu University, Shenyang 110168, China
3 Department of Civil and Environmental Engineering, Michigan Technological University, Houghton MI49931, Michigan, USA
4 School of Transportation Science and Engineering, Harbin Institute of Technology, Harbin 150090, China

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摘要交通标线作为重要的交通安全设施,在控制道路交通、提高道路行车安全系数方面发挥着极其重要的作用。但传统的溶剂型与热熔型交通标线涂料存在成本高、逆反射性能差、老化现象严重等缺陷,并且在使用过程中会对环境造成较大的污染。因此,亟须寻求一种能有效弥补上述缺陷的新型交通标线涂料。水性丙烯酸交通标线涂料凭借着优良的耐久性能与环保性能以及高效的施工性,被视为全寿命周期评价中综合性能最佳的交通标线涂料,是未来交通标线涂料的主要发展方向之一。
近年来,学者们通过对水性丙烯酸交通标线涂料进行物理改性、化学改性以及配合比优化,使其使用性能得到了显著的改善,并取得了丰硕的成果。同时纳米材料与稀土类发光材料的快速发展也为水性丙烯酸交通标线涂料提供了无限的可能。但目前水性丙烯酸交通标线涂料在我国的使用率仍然相对较低,其综合性能也有待进一步提升。并且当前研究主要停留在宏观尺度域,未对水性丙烯酸交通标线涂料的细微观特性进行充分研究,也未能建立起宏观性能与细微观结构属性之间的联系。与此同时,现有的水性丙烯酸交通标线涂料评价方法无法满足其在全寿命周期内的功能性与耐久性需求,尚缺乏一套全面、系统的水性丙烯酸交通标线涂料评价体系。尽管部分学者对水性丙烯酸交通标线涂料服役期内的性能演化规律进行了研究,但多针对逆反射性能,性能预测模型仍不够全面。此外,鲜见针对水性丙烯酸交通标线涂料与路面的黏结界面性能及内在机理的研究。
本文综述了近年来水性丙烯酸交通标线涂料的重要研究进展。从概述水性丙烯酸乳液的化学结构与特性出发,之后从改性方法、配合比优化、性能研究等方面重点介绍了水性丙烯酸交通标线涂料的发展现状。文章最后提出了研究中存在的问题并展望了未来发展趋势。

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关键词: 道路工程水性丙烯酸交通标线涂料水性丙烯酸树脂配合比设计微观特性耐久性逆反射性

Abstract: As an essential part of traffic safety facility, traffic markings play a crucial role in controlling road traffic and improving traffic safety. However, the conventional solvent-based and hot-melt marking paints have deficiencies such as high cost, poor retro-reflectivity, inferior aging resistance, and large environmental pollution. Hence there is an urgent need to seek new marking paint products that can overcome the aforementioned deficiencies. Acrylic acid-based waterborne traffic marking paints have been found highly durable and environmental friendly, and capable of facilitating rapid construction, are considered as the best marking paint candidate with respect to overall performance in the whole life-cycle assessment, and as one of the major development directions in the future.
In recent years, intensive and fruitful research efforts have been made in improving the working performances of acrylic acid-based waterborne traffic marking paints from the perspectives of physical modification, chemical modification and mixing proportion optimization. And the rapid development of nano-materials and rare-earth luminescent materials also provides infinite possibilities for acrylic acid-based waterborne paints. However, acrylic acid-based paints haven't yet found wide applications in traffic engineering, and also needs further improvement in comprehensive performance. Moreover, current research has been concentrated in the macroscopic scale domain. The microscopic properties of acrylic acid-based waterborne paints have not been thoroughly studied, and the understanding of the relationship between macroscopic properties and microscopic structural properties remains unclear. The existing performance evaluation methods of acrylic acid-based waterborne paints cannot fully reflect the whole-life-cycle functionality and durability requirements of the traffic marking paints. This urges the establishment of a comprehensive and systematic evaluation system for acrylic acid-based waterborne traffic marking paints. Furthermore, some researchers, though have studied the performance evolution of the acrylic acid-based coatings during their service life, mostly focused on retro-reflective performance and left the performance prediction model immature. In addition, there can be found few works studying the performances and underlying mechanisms of the paint-pavement adhesion interfaces.
After depicting necessary basic knowledge about chemical structure and properties of water-based acrylic acid emulsions, this review summarizes systematically the main present research progress of acrylic acid-based waterborne traffic marking paints from the perspectives of modification methods, mixing proportion optimization, and performance evaluation methods. It ends with a discussion on currently existing problems and the future development trend.

Key words: road engineering acrylic acid-based waterborne traffic marking paint water-based acrylic resin mixing proportion design microscopic property durabily retro-reflectivity

出版日期: 2024-11-10 发布日期: 2024-11-11

ZTFLH:

U414

基金资助: 国家自然科学基金(51308084);中央高校基本科研业务费专项资金(3132017029);大连海事大学“双一流”建设专项(BSCXXM021);辽宁公路科技创新重点科研项目(201701);大连市科技创新基金项目(2020JJ26SN062);辽宁省教育厅基金项目(LJKMZ20220922)

通讯作者: *郭乃胜,大连海事大学交通运输工程学院教授、博士研究生导师。2007年3月份毕业于大连海事大学,获得工学博士学位。2009—2012年在哈尔滨工业大学进行博士后研究工作。2013—2014年美国密歇根理工大学访问学者。目前主要从事沥青与沥青混合料等方面的研究工作。发表论文80余篇,其中SCI、EI检索50余篇,包括Construction and Building Materials、International Journal of Pavement Engineering、Journal of Materials in Civil Engineering、Transportation B等。naishengguo@dlmu.edu.cn

作者简介: 郑直,2022年6月毕业于沈阳建筑大学,获得工学硕士学位。现为大连海事大学交通运输工程学院博士研究生,在郭乃胜教授的指导下进行研究。目前主要研究领域为新型环保型道路工程材料。

引用本文:

郑直, 郭乃胜, 金鑫, 房辰泽, 尤占平, 谭忆秋. 水性丙烯酸交通标线涂料研究现状与发展趋势[J]. 材料导报, 2024, 38(21): 22120007-12.
ZHENG Zhi, GUO Naisheng, JIN Xin, FANG Chenze, YOU Zhanping, TAN Yiqiu. Research Advances and Development Trends of Acrylic Acid-based Waterborne Traffic Marking Paints. Materials Reports, 2024, 38(21): 22120007-12.

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http://www.mater-rep.com/CN/10.11896/cldb.22120007 或 http://www.mater-rep.com/CN/Y2024/V38/I21/22120007

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