Abstract: The curves of displacement and stress vs. time and temperature were acquired by a displacement-tested system and force-tested system, respectively. The interactions of content, displacement, stress and microstructure evolution during the solidification of Mg-Cu alloys were stu-died. The findings showed that the addition of Cu into pure Mg melt results in its expansion behaviors changing from liquid expansion behavior only to the coexistence of liquid expansion behavior and mushy zone expansion behavior during solidification process. Additionally, the displacement of mushy zone expansion (Δl) decreases first and then increases with the increase in Cu content. The dependence of Δl on Cu content is the combined effects of the formation of CuMg2 divorced eutectic, (ɑ-Mg + CuMg2) eutectic phase and the heating effect of crystallization latent heat on residual liquid phase. The minimum value of Δl is 7.5×10-3 mm, which is present in the solidification process of Mg-2.5Cu alloy. The mean solidification shrinkage rate (shr) increases significantly first and then decreases with the increase in Cu content, and the maximum value of shr (3.3×10-4 mm·s-1) is present in the solidification process of Mg-0.8Cu alloy. The formation of expansion stress is influenced more by the mushy zone expansion during the solidification process.
蒙毅, 杨越, 孙健, 曹雷刚. Cu含量对Mg-Cu合金凝固行为的影响[J]. 材料导报, 2025, 39(11): 22100123-9.
MENG Yi, YANG Yue, SUN Jian, CAO Leigang. Effect of Cu Content on the Solidification Behaviors of Mg-Cu Alloys. Materials Reports, 2025, 39(11): 22100123-9.
1 Wang X J, Xu D K, Wu R Z, et al. Journal of Materials Science & Technology, 2018, 34, 245. 2 Zhang X, Wang Y, Liu D R, et al. Journal of Crystal Growth, 2020, 543, 1. 3 Hassan S F, Gupta M. Materials Research Bulletin, 2002, 37, 377. 4 Chen S Q, Dong X P, Ma R, et al. Materials Science and Engineering A, 2012, 551, 87. 5 Kawamura Y, Kasahara T, Izumi S, et al. Scripta Materialia, 2006, 55 (5), 453. 6 Cermak J, Kral L, Roupcova P. International Journal of Hydrogen Energy, 2021. 46, 14494. 7 Kursun C, Gogebakan M. Journal of Alloys & Compounds, 2014, 619, 138. 8 Sun Z, Zou L Y, Cheng X M, et al. Materials, 2021, 14(15), 4246. 9 Yan X D, Wan P, Tan L L, et al. Materials Science & Engineering B, 2018, 229, 105. 10 Ren L, Xu L, Feng J W, et al. Journal of Materials Science:Materials in Medicine, 2012, 23(5), 1235. 11 Witte F, Kaese V, Haferkamp H, et al. Biomaterials, 2005, 26(17), 3557. 12 Wang S, Yang C G, Ren L, et al. Materials Letters, 2014, 129(32), 88. 13 Li Y, Liu L N, Wan P, et al. Biomaterials, 2016, 106, 250. 14 Chen J X, Peng W, Zhu L, et al. Materials Technology, 2018, 33(2), 145. 15 Pan F S, Yang M B, Chen X H. Journal of Materials Science & Technology, 2016, 32(12), 1211. 16 Wang Z, Huang Y D, Srinivasan A, et al. Materials & Design, 2013, 47, 90. 17 Song J F, Pan F S, Jiang B, et al. Journal of Magnesium and Alloys, 2016, 4(3), 151. 18 Cao G, Kou S. Materials Science and Engineering A, 2006, 417, 230. 19 Rappaz M, Drezet J, Gremaud M. Metallurgical and Materials Transactions A, 1999, 30(2), 448. 20 Wang Z, Huang Y D, Srinivasan A, et al. Journal of Materials Science, 2014, 49, 353. 21 Wang Y S, Yu J Z, Wang Q D, et al. Materials Reports, 2003, 17(11), 72 (in Chinese). 王业双, 俞继志, 王渠东, 等. 材料导报, 2003, 17(11), 72. 22 Eskin D G, Suyitno, Katgerman L. Progress in Materials Science, 2004, 49(5), 629. 23 Clyne T W, Davies G J. British Foundryman, 1981, 74, 65. 24 Wei Z Q, Liu Z, Wang Z, et al. The Chinese Journal of Nonferrous Metals, 2018, 28(2), 233 (in Chinese). 魏子淇, 刘正, 王志, 等. 中国有色金属学报, 2018, 28(2), 233. 25 Vinodh G, Jafari N H, Li D J, et al. Metallurgical and Materials Transactions A, 2020, 51, 1897. 26 Zhou L, Huang Y D, Mao P L, et al. International Journal of Cast Metals Research, 2011, 24, 170. 27 Song J F, Wang Z, Huang Y D, et al. Metallurgical and Materials Tran-sactions A, 2015, 46, 6003. 28 Wang Y S, Wang Q D, Wu G H, et al. Materials Letters, 2002, 57, 929. 29 Cao G, Kou S. Metallurgical and Materials Transactions A, 2006, 37, 3647. 30 Song J F, Wang Z, Huang Y D, et al. Journal of Materials Science, 2016, 51, 2687. 31 Li P J, Tang B, Kandalova E G. Materials Letters, 2005, 59, 671. 32 Li S S, Tang B, Jin Xi Y, et al. Journal of Materials Science, 2012, 47, 2000. 33 Meng Y, Sun J, Cao L G, et al. Acta Metallurgica Sinica-English Letters, 2018, 32(5), 559. 34 Meng Y, Yang Y, Cao L G, et al. International Journal of Metalcasting, 2022, 17, 703. 35 Okamoto H. Journal of Phase Equilibria and Diffusion, 2015, 36(2), 183. 36 Mezbahul-Islam M, Mostafa A O, Medraj M. Journal of Materials, 2014, 2014, 1. 37 LiY, Li H X, Katgermanb L, et al. Progress in Materials Science, 2021, 117, 1. 38 Stangeland A, Mo A, Nielsen Ø, et al. Metallurgical and Materials Transactions A, 2004, 35, 2903. 39 Chen Z, Wang B, Li S J, et al. ChemElectroChem, 2016, 3, 165.