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材料导报  2021, Vol. 35 Issue (2): 2046-2051    https://doi.org/10.11896/cldb.20020063
  无机非金属及其复合材料 |
降低高强混凝土黏度的减水剂制备与机理研究
钱珊珊1,2, 姚燕1,3, 王子明1, 崔素萍1, 刘晓1, 郑春扬2
1 北京工业大学,材料与制造学部,北京 100124;
2 江苏奥莱特新材料股份有限公司,江苏省(奥莱特)混凝土高分子助剂工程技术研究中心,南京 211505;
3 中国建筑材料科学研究总院,绿色建筑材料国家重点实验室,北京 100124
Preparation and Mechanism of Superplasticizer for Reducing the Viscosity of High Strength Concrete
QIAN Shanshan1,2, YAO Yan1,3, WANG Ziming1, CUI Suping1, LIU Xiao1, ZHENG Chunyang2
1 Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing 100124, China;
2 Jiangsu Province Engineering Research Center (ARIT) of Concrete Polymer Additives, Jiangsu China Railway ARIT New Materials Co., Ltd, Nanjing 211505, China;
3 The State Key Laboratory of Green Building Materials, China Building Materials Academy, Beijing 100124, China
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摘要 根据分子结构设计原理,以马来酸酐与异戊烯醇聚氧乙烯聚氧丙烯醚大单体为主要反应原料,以甲基烯丙基磺酸钠为链转移剂,合成一款减水剂。采用凝胶渗透色谱、红外光谱、核磁氢谱等测试手段获得了合成产物的分子量及分子量分布等结构参数信息,同时比较了该减水剂与普通减水剂在表面张力、对水泥颗粒吸附行为、Zeta电位、水泥净浆流动性、水泥净浆流变性能及新拌混凝土应用性能方面的差异。性能评价结果表明,该减水剂具有良好的降黏效果,本工作还分析了其降黏作用机理。
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钱珊珊
姚燕
王子明
崔素萍
刘晓
郑春扬
关键词:  高强混凝土  减水剂  降黏    
Abstract: Asuperplasticizer was synthesized by maleic anhydride and isoprenyl-PE-PPG according to molecular structure design principle. The molecular structure of superplasticizer was determined by Fourier transform infrared spectroscopy, 1H nuclear magnetic resonance and gel permeation chromatography, respectively. The surface tension, adsorption behavior, zeta potential, the flow behaviour of superplasticized cement paste, rheological behavior of cement pastes, and application performance in concrete have been measured. Results of evaluation on performance have showed that superplasticizer has good viscosity-reducing effect and the mechanism of superplasticizer has been analyzed.
Key words:  high strength concrete    superplasticizer    viscosity-reducing
               出版日期:  2021-01-25      发布日期:  2021-01-28
ZTFLH:  TU528  
基金资助: 国家自然科学基金(51578025;E020501)
通讯作者:  yaoyan@cbmamail.com.cn   
作者简介:  钱珊珊,北京工业大学博士在读,硕士毕业于东南大学,江苏奥莱特新材料股份有限公司研发总监,入选2019年南京市中青年拔尖人才,2018年南京江北新区中青年科技创新优秀人才,获得2017年南京市五一劳动奖章。以第一发明人申请中国专利35件,美国专利3件,已授权中国专利28件,美国专利1件,发表学术论文30余篇,主要从事高性能混凝土、混凝土外加剂、混凝土耐久性及相关材料的研究与开发工作。
姚燕,教授级高级工程师,中国建筑材料科学研究院院长。1982年毕业于上海同济大学建筑材料工程系。兼任中国建筑材料工业协会副会长、中国硅酸盐学会副理事长等。主要从事高性能混凝土、混凝土外加剂、混凝土耐久性及相关材料的研究与开发工作。获得国家和部级科技进步奖10项,发表论文40余篇。
引用本文:    
钱珊珊, 姚燕, 王子明, 崔素萍, 刘晓, 郑春扬. 降低高强混凝土黏度的减水剂制备与机理研究[J]. 材料导报, 2021, 35(2): 2046-2051.
QIAN Shanshan, YAO Yan, WANG Ziming, CUI Suping, LIU Xiao, ZHENG Chunyang. Preparation and Mechanism of Superplasticizer for Reducing the Viscosity of High Strength Concrete. Materials Reports, 2021, 35(2): 2046-2051.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.20020063  或          http://www.mater-rep.com/CN/Y2021/V35/I2/2046
1 Li C Z, Fei N Q, Wang D M, et al. Journal of the Chinese Ceramic Society, 2005, 33(1),87(in Chinese).
李崇智, 冯乃谦, 王栋民, 等. 硅酸盐学报, 2005, 33(1),87.
2 Wu Z W. Journal of the Chinese Ceramic Society, 1979(3),82(in Chinese).
吴中伟. 硅酸盐学报, 1979(3),82.
3 Kong X M, Shi Z H, Wang D M. Journal of Building Materials, 2014, 17(6),939(in Chinese).
孔祥明, 史志花, 王栋民. 建筑材料学报, 2014, 17(6),939.
4 Wang K L, Song F F, Liu L. Materials Reports B:Research Papers, 2014, 28(9),117(in Chinese).
王可良, 宋芳芳, 刘玲. 材料导报:研究篇, 2014, 28(9),117.
5 Wang Z M, Zhang R Y, Wang Z H. Materials Reports, 2005(9),52(in Chinese).
王子明, 张瑞艳, 王志宏.材料导报, 2005(9),52.
6 Huang D N, Xie R S. Journal of the Chinese Ceramic Society 1984(3),107(in Chinese).
黄大能, 谢尧生. 硅酸盐学报, 1984(3),107.
7 Zhao Q X, Sun W, Miu C W, et al. Journal of the Chinese Ceramic Society, 2009(10),170
8 Chen L, Jiang Y Q, Hu F L, et al. Materials Reports B: Research Papers, 2013, 27(4),13(in Chinese).
陈龙, 蒋亚清, 胡飞龙, 等. 材料导报:研究篇, 2013, 27(4),130.
9 Wang Z M, Lu Z C, Lu F, et al. Journal of the Chinese Ceramic Society, 2012(11),40(in Chinese).
王子明, 卢子臣, 路芳,等. 硅酸盐学报, 2012(11),40.
10 Fan S W. China Concrete and Cement Products, 1991(1),135(in Chinese).
范沈抚.混凝土与水泥制品, 1991(1),135.
11 Li S, Wen Z Y. Journal of the Chinese Ceramic Society, 2009, 37(4),616.
12 Zhang M, Zhang Q H, Duan B, et al. Bulletin of the Chinese Ceramic Society, 2015(3),284(in Chinese).
张明, 张栓红, 段彬, 等.硅酸盐通报, 2015(3),284.
13 Kissa E. Dispersions characterization, testing and measurement, CRC Press, USA, 1999.
14 Elzbieta Janowska-Renkas. Construction and Building Materials, 2013, 38,1204.
15 Qian S S, Yao Y, Wang Z M, et al. Construction and Building Mate-rials, 2018, 169,452.
16 Kailey I, Blackwell C, Behles J. Industrial and Engineering Chemistry Research, 2013, 52(50),17913.
17 Parmar A, Bharatiya B, Patel K, et al. Journal of Surfactants and Detergents, 2013, 16(1),105.
18 Sakai E, Kawakami A, Daimon M. Macromolecular Symposia, 2001, 175(1),367.
19 Jardine L A, Koyata H, Folliard K J, et al. Patent application, US6670415, 2003.
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