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材料导报  2024, Vol. 38 Issue (16): 23040152-5    https://doi.org/10.11896/cldb.23040152
  无机非金属及其复合材料 |
镍铁双氢氧化物的响应曲面法优化生长和电催化析氧性能研究
刘向阳1, 王议2, 夏爽1, 刘中清1,*
1 四川大学化学工程学院,成都 610065
2 四川轻化工大学化学工程学院,四川 自贡 643000
Optimization of Growth and Electrocatalytic Oxygen Evolution of Nickel-Iron Dihydroxide by Response Surface Method
LIU Xiangyang1, WANG Yi2, XIA Shuang1, LIU Zhongqing1,*
1 College of Chemical Engineering, Sichuan University, Chengdu 610065, China
2 College of Chemical Engineering, Sichuan University of Science & Technology, Zigong 643000, Sichuan, China
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摘要 采用腐蚀工程制备了层状镍铁双氢氧化物电催化剂,利用X光衍射、场发射扫描电镜、高分辨透射电镜和光电子能谱等对样品物理化学特性进行了表征,采用线性伏安特性曲线、塔菲尔曲线、电化学阻抗谱、循环伏安特性以及恒电流下电势-时间曲线对样品电催化析氧特性进行了详细分析。在单因子实验的基础上,以50 mA·cm-2对应析氧过电位为响应因子,用响应曲面法对影响催化剂性能的主要因素进行了优化,建立了泡沫镍铁腐蚀后析氧过电位的多项式模型,得出的优化制备条件为腐蚀温度80 ℃、时间9 h、NiSO4浓度9 mmol·L-1。在该条件下制备的样品在10 mA·cm-2下的过电位为200 mV,Tafel斜率为52.5 mV·dec-1;50 mA·cm-2电流密度下经过48 h连续测试,其OER催化活性仍能保持在95％,比起商用RuO2电极显示出优良的电催化活性。
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刘向阳
王议
夏爽
刘中清
关键词:  镍铁双氢氧化物  腐蚀工程  响应曲面法  电催化  析氧反应    
Abstract: The layered nickel-iron dihydroxide electrocatalysts were prepared by corrosion engineering. The physicochemical properties of the samples were characterized by X-ray diffraction, field emission scanning electron microscopy, high resolution transmission electron microscopy and photoelectron spectroscopy. Linear voltammetry characteristic curve, Tafel curve, electrochemical impedance spectrum, cyclic voltammetry cha-racteristic and constant-current potential-time curve were used to analyze the electrocatalytic oxygen evolution characteristics of samples in detail. On the basis of single factor experiment, with 50 mA·cm-2 corresponding to the oxygen evolution potential for response factor, by using the response surface method on the main factors affecting the catalyst performance is optimized, established the oxygen evolution after the foam nickel iron corrosion potential of the polynomial model. And the corrosion temperature of 80 ℃, time of 9 h, NiSO4 concentration of 9 mmol·L-1 are the optimization of the preparation conditions. The sample prepared under this condition has an overpotential of 200 mV at 10 mA·cm-2 and a Tafel slope of 52.5 mV·dec-1. After 48 h continuous testing at 50 mA·cm-2 current density, the OER catalytic activity remaines at 95%, showing better electrocatalytic activity than the commercial RuO2 electrode.
Key words:  nickel-iron dihydroxide    corrosion engineering    response surface method    electrocatalysis    oxygen evolution reaction
出版日期:  2024-08-25      发布日期:  2024-09-10
ZTFLH:  TB321  
通讯作者:  *刘中清,四川大学化学工程学院教授、博士研究生导师。2000年硕士毕业于中南大学,获得有色金属冶金硕士学位。2007年毕业于北京科技大学,获得材料学博士学位,毕业后到四川大学工作至今。目前主要研究方向为纳米材料的制备、性能及在催化合成、催化降解、水分解及太阳能电池等方面的应用。liuzqhgxy@scu.edu.cn   
作者简介:  刘向阳,2019年6月于北部湾大学获得工学学士学位。现为四川大学化学工程学院硕士研究生,在刘中清教授的指导下进行研究。目前主要研究领域为设计碱性电解水制氢中析氧反应催化剂。
引用本文:    
刘向阳, 王议, 夏爽, 刘中清. 镍铁双氢氧化物的响应曲面法优化生长和电催化析氧性能研究[J]. 材料导报, 2024, 38(16): 23040152-5.
LIU Xiangyang, WANG Yi, XIA Shuang, LIU Zhongqing. Optimization of Growth and Electrocatalytic Oxygen Evolution of Nickel-Iron Dihydroxide by Response Surface Method. Materials Reports, 2024, 38(16): 23040152-5.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.23040152  或          http://www.mater-rep.com/CN/Y2024/V38/I16/23040152
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