Preparation of Pd Catalysts with Histidine Coordination Complex and Their Catalytic Performances on 2-Amylanthraquinone Hydrogenation
YAN Hua1,2, YANG Xiaoye1, ZHOU Junhong1, YUAN Zhongshan1, LI Defu1, WANG Shudong1,*
1 Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China 2 University of Chinese Academy of Sciences, Beijing 100049, China
Abstract: In order to improve the catalytic activity and selectivity of the catalyst for anthraquinone hydrogenation, a series of Pd-his/SiO2-T (his represents histidine, and T is the calcination temperature) catalysts were prepared by impregnation method, with the coordination complex of Pd-(NO3)2 and histidine as the precursor. The catalysts were prepared with SiO2 as the support through impregnation method under different calcination temperatures, and applied in anthraquinone hydrogenation reaction. For comparison, a Pd/SiO2-500 catalyst free of histidine was prepared with the optimal calcination temperature, and other conditions were kept the same. The SiO2 support and all the catalysts were investigated by various characterization techniques in detail. It was found that, with the calcination temperature rising, the Pd dispersion of catalysts decreased during 300—400 ℃, however from 400 ℃ to 600 ℃, the Pd dispersion nearly kept the same. The content of residual carbon species shrank, while the ratio of Pd0 component and its electron cloud density increased. The evaluation of anthraquinone hydrogenation showed that the highest hydrogenation efficiency of the catalysts reached 12.8 g/L, which was 2.13 times as the Pd/SiO2-500, and has a superior selectivity of 99.67%.
严华, 杨晓野, 周俊宏, 袁中山, 李德伏, 王树东. 基于组氨酸配合物的钯催化剂的制备及2-戊基蒽醌加氢性能[J]. 材料导报, 2024, 38(12): 23030130-6.
YAN Hua, YANG Xiaoye, ZHOU Junhong, YUAN Zhongshan, LI Defu, WANG Shudong. Preparation of Pd Catalysts with Histidine Coordination Complex and Their Catalytic Performances on 2-Amylanthraquinone Hydrogenation. Materials Reports, 2024, 38(12): 23030130-6.
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2024, Vol. 38 
