镧系金属-有机框架材料作为荧光探针的研究进展

doi:10.11896/cldb.20060292

材料导报

2022, Vol. 36

Issue (16): 20060292-8 https://doi.org/10.11896/cldb.20060292

金属与金属基复合材料

镧系金属-有机框架材料作为荧光探针的研究进展

初红涛^*, 尹杰, 林清, 隋秉蓉, 谭金铭, 苏立强, 马文辉

齐齐哈尔大学化学与化学工程学院,黑龙江齐齐哈尔 161006

Research Progress of Lanthanide Metal-Organic Framework Materials as Fluorescent Probes

CHU Hongtao^*, YIN Jie, LIN Qing, SUI Bingrong, TAN Jinming, SU Liqiang, MA Wenhui

College of Chemistry and Chemical Engineering, Qiqihaer University, Qiqihaer 161006, Heilongjiang, China

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摘要金属-有机框架(Metal-organic frameworks, MOFs)材料是由配位键将金属离子与有机配体连接而形成的结构有序的网状配合物,在离子交换、气体分离及存贮、催化、荧光传感及药物输送等领域具有重要的应用价值。
利用具有荧光发射特性的MOFs与客体分子作用后荧光强度的变化,可实现对目标组分的定量检测,而仅依靠单一配体发光的MOFs,定量方法易受外界条件的干扰,会影响结果准确性。金属离子和有机配体的性质决定了MOFs的荧光特性,是该领域学者们研究的重点。镧系元素的三价离子(Ln³⁺)具有未被完全充满的4f电子层结构,其荧光性能独特,易与氧、氮原子配位,且可与有机配体配位形成具有特殊拓扑结构的高配位配合物。Ln³⁺与有机配体形成的镧系金属-有机框架(Ln-MOFs)材料除了具有结构有序、比表面积大的特点外,同时结合了有机配体和镧系元素二者的荧光特性,作为比率型荧光探针被广泛应用。选择不同的有机配体及镧系元素,可开发出对不同组分产生响应的Ln-MOFs。
本文对近年来Ln-MOFs在阴、阳离子以及小分子的荧光检测及温度传感方面的研究进展进行了综述,并对其检测结果、检测机理及影响因素等进行了分析,然后对Ln-MOFs材料作为荧光探针的设计理念进行了总结,最后对Ln-MOFs研究中存在的问题进行了分析,并对其未来发展进行了展望。

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	初红涛
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	苏立强
	马文辉

关键词: 镧系金属-有机框架材料荧光探针三价镧系离子发光功能应用

Abstract: Metal-organic frameworks (MOFs) are ordered network complexes formed by the connection of metal ions with organic ligands coordination bonds, demonstrating high application potential in ion exchange, gas separation and storage, catalysis, fluorescence sensing, and drug delivery.
The quantitative detection of target components can be achieved by using changes in fluorescence intensity after the interaction between MOFs with fluorescence emission properties and guest molecules. For MOFs with a single ligand luminescence, the quantitative method is vulnerable to external interference, and the accuracy of the results is affected. The properties of metal ions and organic ligands determine the fluorescence properties of MOFs, which is the focus of research in this field. The trivalent lanthanide ion (Ln³⁺) has a 4f electron layer, which is incompletely filled, and exhibits unique fluorescence properties. Besides, it is prone to coordination with oxygen and nitrogen atoms. It can form high-coordination complexes with a particular topological structure by coordinating with organic ligands. Lanthanide metal-organic frameworks (Ln-MOFs) formed by Ln³⁺ and organic ligands are widely used as ratio fluorescent probes because of their ordered structure and high specific surface area, as well as the combined fluorescence properties of organic ligands and lanthanides. Ln-MOFs that respond to different components can be deve-loped by selecting different organic ligands and lanthanides.
This paper offers a retrospection of the research efforts with respect to the progress of Ln-MOFs in fluorescence detection and temperature sensing of anions, cations and small molecules. This paper also provides analysis of the detection results, detection mechanism and influencing factors. Moreover, we summarize the design concept of Ln-MOFs as fluorescent probes. Finally, we pay attention to the problems existing in the research on Ln-MOFs and focus on the prospect of its future development.

Key words: Ln-MOF fluorescent probe trivalent lanthanide ion (Ln³⁺) luminous function application

出版日期: 2022-08-25 发布日期: 2022-08-29

ZTFLH:

O657

基金资助: 黑龙江省自然科学基金优秀青年项目(YQ2019H034);黑龙江省教育厅项目(135109201)

通讯作者: ^*lange1979@163.com

作者简介: 初红涛,工学博士,齐齐哈尔大学教授、硕士研究生导师。2005年3月毕业于齐齐哈尔大学分析化学专业,获得硕士学位;2014年11月毕业于哈尔滨工业大学化学工程与技术专业,获博士学位。2005年入职齐齐哈尔大学工作至今,主要从事新型荧光探针的设计及应用、色谱分析技术应用等研究,发表学术论文50余篇。

引用本文:

初红涛, 尹杰, 林清, 隋秉蓉, 谭金铭, 苏立强, 马文辉. 镧系金属-有机框架材料作为荧光探针的研究进展[J]. 材料导报, 2022, 36(16): 20060292-8.
CHU Hongtao, YIN Jie, LIN Qing, SUI Bingrong, TAN Jinming, SU Liqiang, MA Wenhui. Research Progress of Lanthanide Metal-Organic Framework Materials as Fluorescent Probes. Materials Reports, 2022, 36(16): 20060292-8.

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http://www.mater-rep.com/CN/10.11896/cldb.20060292 或 http://www.mater-rep.com/CN/Y2022/V36/I16/20060292

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