Research and Progress of Low-expansion β-eucryptite Composites
XUE Yaohui1, JIANG Junbiao1, ZHANG Hui1, WEN Changxiu2, SU Zongfeng1, CUI Xiaoxia2, GUO Haitao2
1 Xi’an Modern Control Technology Research Institute, Xi’an 710065, China; 2 Xi’an Institute of Optics and Precision Mechanics, Chinese Academy of Sciences (CAS), Xi’an 710119, China
Abstract: Thermal expansion coefficient is one of the important parameters of materials. In nature, most materials exhibit high thermal expansion coefficient which would lead to the phenomenon of thermal-expansion and cold-contraction. Therefore, these materials usually have poor thermal shock resistance and cannot be used in the environment with great temperature changes. The signal distortion usually occurs because of the destruction of aerospace components and the deformation of electronic device resulted from the uneven temperature distribution. It is exciting that there are a few materials with negative thermal expansion coefficient, and their volume decreases with the increase of temperature. Based on the additivity of the expansion coefficient, the compounds with low coefficient of thermal expansion can be obtained by introducing the material with low or negative coefficient of thermal expansion into the high ones, which can remarkably improve their thermal shock resistance. Negative thermal expansion materials include isotropic negative thermal expansion materials and anisotropic negative thermal expansion mate-rials. Isotropic negative thermal expansion materials are mainly ZrV2-xPxO7 and ZrW2O8 series. Anisotropic negative thermal expansion materials mainly include β-eucryptite, perovskite series, A2M3O12series, M(CN)2 (M=Zn, Cd) series, oxides, zeolite series and metal organic frameworks (MOFs), etc. The β-eucryptite is usually used to adjust the thermal expansion coefficient of composite materials owing to its negative thermal expansion coefficient (α=-6.1×10-6 K-1), low density (2.67 g/cm3), good thermal shock resistance, dielectric properties and infrared radiation. Composite materials with negative thermal expansion or near zero thermal expansion can be fabricated by compounding with other materials, which can greatly improve the thermal shock resistance and dimensional stability of the materials, and thus prolong the life of the materials. Therefore, β-eucryptite has been used to manufacture low expansion ceramics, glass-ceramics, metal matrix composites applied as fillers for electrical equipment, electronic components, device sealants, aircraft high precision components, humidity sensor sensitive materials and lithium ion battery so-lid electrolytes. At the same time, due to the anisotropic thermal expansion property of β-eucryptite, the composites will have more residual stress and lower mechanical strength. In order to solve this problem, fibers or whiskers with high mechanical strength can be introduced to form three-phase composites with low expansion and high mechanical strength, which is beneficial to expand the application of materials in inertial missiles, optic fiber gyro and other aerospace applications. In this paper, the research status and progress of the low expansion two-phase or three-phase composites of metals, glass and ceramics are reviewed. The preparation method, thermal properties and application fields of these low expansion coefficient composites are summarized. The future development trends and application prospects of the composites are also discussed.
1 Wang J, Wang Y. Heat Treatment Technology and Equipment, 2009, 30(3), 39(in Chinese). 王姬, 王铀. 热处理技术与装备, 2009, 30(3), 39. 2 Sleight A W. Annual Review of Materials Research, 1998, 28(1), 29. 3 Mary T A, Evans J S O, Vogt T, et al. Science, 1996, 272(5258), 90. 4 Wang W Z, Wan Y C. Liao Ning Building Materials, 2006(1), 28(in Chinese). 王伟忠, 万玉春. 辽宁建材, 2006(1), 28. 5 Lichtenstein A I, Jones R O, Xu H, et al. Physical Review B, 1998, 58(10), 6219. 6 Liu X S. Rapid synthesis, properties improvement and functionalization of tailored thermal expansion materials. Master’s Thesis, Zhengzhou University, China, 2014(in Chinese). 刘献省. 可控热膨胀材料快速制备、性能改善及功能化研究. 硕士学位论文, 郑州大学, 2014. 7 Evans J S O, Mary T A, Sleight A W. Journal of Solid State Chemistry, 1997, 133(2), 580. 8 Goodwin A L, Kepert C J. Physical Review B, 2005, 71(R), 140301. 9 Artioli G, Dapiaggi M, Fornasini P, et al. Journal of Physics and Che-mistry of Solids, 2006, 67(9), 1918. 10 Lightfoot P, Woodcock D A, Maple M J, et al. Journal of Chemistry Materials, 2001, 11, 212. 11 Dubbeldam D, Walton K S, Ellis D E, et al. Angewandte Chemie International Edition, 2007, 119(24), 4580. 12 Pelletant A, Reveron H, Chêvalier J, et al. Materials Letters, 2012, 66(1), 68. 13 Diao Z C, Lin W L. China Tungsten Industry, 2010, 25(2), 38(in Chinese). 刁志聪, 林伟林. 中国钨业, 2010, 25(2), 38. 14 Yuan H L,Yuan B H, Li F,et al. Acta Physica Sinica, 2012, 61(22), 357(in Chinese). 袁焕丽,袁保合,李芳,等. 物理学报, 2012, 61(22), 357. 15 Korthuis V, Khosrovani N, Sleight A W. Chemistry Matterials , 1995, 7(2), 412. 16 Shen R, Wang C, Wang T M. Materials Review, 2001, 15(8), 35(in Chinese). 沈容, 王聪, 王天民. 材料导报, 2001, 15(8), 35. 17 Kryukova1 O N, Knyazeva A G, Pogrebenkov V M, et al. Journal of Materials Science, 2017, 52(19), 11314. 18 Hu P H, Chen J, Sun C, et al. Journal of the American Ceramic Society, 2011, 94(10), 3600. 19 Ju X W, Wu R M, Ma S B, et al. New Chemical Materials, 2015, 43(12), 15(in Chinese). 居相文, 吴日民, 马双彪, 等. 化工新型材料, 2015, 43(12), 15. 20 Chen X N, Zhu J J, Yang J. Acta Mteriae Compositae Sinica, 2012, 29(3), 145(in Chinese). 程晓农, 朱君君, 杨娟. 复合材料学报, 2012, 29(3), 145. 21 Mary T A, Sleight A W. Journal of Materials Research, 1999, 14(3), 912. 22 Du Z Y, Liang E J, Ding P, et al. The Journal of Light Scattering, 2008, 20(2), 145(in Chinese). 杜志勇, 梁二军, 丁佩, 等. 光散射学报, 2008, 20(2), 145. 23 Yan X H, Li B Y, Riedel R, et al. Journal of the Chinese Ceramic Society, 2009, 37(5), 653(in Chinese). 严学华, 李炳云, Riedel Ralf, 等. 硅酸盐学报, 2009, 37(5), 653. 24 Attfield M P, Sleight A W. Chemistry Materials, 1998, 10(7), 2013. 25 Yun D Q, Gu C Q, Wang X F. Acta Materiae Compositae Sinica, 2005, 22(5), 25(in Chinese). 云大钦, 谷臣清, 王晓芳. 复合材料学报, 2005, 22(5), 25. 26 Du J, Gao Y F, Luo H J. Solar Energy Materials & Solar Cells, 2011, 95(7), 1604. 27 Heaney P J, Prewitt C T, Gibbs G V. In: Silica: physical behavior, geochemistry, and materials applications, Washington, USA, 1994. 28 Pan Zhao. Crystal structure, thermal expansion and related electrical properties in lead/bismuth-based perovskite-type oxides. Master’s Thesis, University of Science and Technology Beijing, China, 2007(in Chinese). 潘昭. Pb/Bi基钙钛矿氧化物的晶体结构、热膨胀及相关电学性能. 硕士学位论文, 北京科技大学, 2017. 29 Yang Y M, Li L C, Feng N. Chinese Journal of Inorganic Chemistry, 2007, 23(3), 382. 30 Tyagi A K, Achary S N, Mathews M D. Journal of Alloys and Compounds, 2002, 339(1), 207. 31 Zhao Y J, Wu Y B, Wang X J, et al. Semiconductor Materials, 2019, 44(1), 43(in Chinese). 赵英杰,伍泳斌,王晓娟, 等. 半导体技术, 2019, 44(1), 43. 32 Liu L N, Li P W, Wang Y. Piezoelectrics & Acoustooptics, 2018,40(6),888(in Chinese). 刘丽娜, 李朋伟, 王颖. 压电与声光, 2018, 40(6), 888. 33 Guan S Y, Yong K, Hu Z M, et al. Journal of Wuhan Institute of Technology, 2018, 40(5), 494(in Chinese). 关淑雅,雍堃,胡正茂, 等. 武汉工程大学学报, 2018, 40(5), 494. 34 Zhao Q, Guo L, Yang X, et al. Journal of Synthetic Crystals, 2018, 47(9), 1811(in Chinese). 赵强,郭莉,杨晓, 等. 人工晶体学报, 2018, 47(9), 1811. 35 He X Y, Li C X. Journal of Synthetic Crystals, 2017,46(8),1575(in Chinese). 何晓宇,李春霞. 人工晶体学报, 2017, 46(8), 1575. 36 Tschaufeser P, Parker S C. Journal of Physics Chemistry, 1995, 99(26), 10609. 37 Fridlyander I N, Klyagina N S, Tykachinskii I D, et al. Metal Science & Heat Treatment, 1974, 16(6), 495. 38 García-Moreno O, Borrell A, Bittmann B, et al. Journal of the European Ceramic Society, 2011, 31(9), 1641. 39 Wang L D, Fei W D, Hu M, et al. Materials Letters, 2002, 53(1), 20. 40 Wang L D, Fei W D, Yao C K. Materials Science & Engineering A, 2002, 336(1), 110. 41 Hu J, Fei W D, Li C, et al. Journal of Materials Science Letters, 1994, 13(24), 1797. 42 Fei W D, Wang L D. Materials Chemistry & Physics, 2004, 85(2-3), 450. 43 Xue Z W, Liu Z, Wang L D, et al. Metal Science Journal, 2010, 26(12), 1521. 44 Cao P. Synthesis, phase composition and property research of BaO-Al2O3-SiO2 glass-ceramics. Master’s Thesis, Tianjin University, China, 2013(in Chinese). 曹培. BaO-Al2O3-SiO2系微晶玻璃的制备、物相及性能研究. 硕士学位论文, 天津大学,2013. 45 Beall G H. Glass Science and Technology, 2000, 73(1), 3. 46 Kang L J. Research on glass-ceramics with negative coefficient of thermal expansion used as fiber bragg grating substrate. Master’s Thesis, Gradua-te University of Chinese Academy of Sciences (Xi'an Institute of Optics and Precision Mechanics), China, 2005(in Chinese). 康利军. 光纤布拉格光栅用负膨胀微晶玻璃基板的研究. 硕士学位论文, 中国科学院研究生院(西安光学精密机械研究所), 2005. 47 Li Y M, Ma G H, Wang Z M, et al. Glass & Enamel, 1998, 26(4), 13(in Chinese). 李月明, 马光华, 汪再明, 等. 玻璃与搪瓷, 1998, 26(4), 13. 48 Tong L, Jiang W H, Liang J, et al. China Ceramics, 2016, 52(11), 6(in Chinese). 童磊, 江伟辉, 梁健, 等. 中国陶瓷, 2016, 52(11), 6. 49 Liu X P, Pang X B, Wan L, et al. Transactions of Materials and Heat Treatment,2016,37(6), 10(in Chinese). 刘小磐, 庞先兵, 万隆, 等. 材料热处理学报, 2016, 37(6), 10. 50 Kryukova O N, Knyazeva A G, Pogrebenkov V M, et al. Journal of Materials Science, 2017, 52(19), 1. 51 Liu Y P. Investigation on low-melting point bismuthate sealing glass. Master’s Thesis, China Jiliang University, China, 2013(in Chinese). 刘远平. 低熔点铋酸盐封接玻璃的研究. 硕士学位论文, 中国计量学院, 2013. 52 Wang M Q, Fan X P, Zhang Y Y, et al. Bulletin of the Chinese Ceramic Society,1992, 11(1), 4(in Chinese). 王民权, 樊先平, 张园园,等. 硅酸盐通报,1992, 11(1), 4. 53 Chen F. Study of low-melting glass of Na2O-Al2O3-B2O3 system.Master’s Thesis, Shaanxi University of Science & Technology, China, 2006(in Chinese). 陈福. Na2O-Al2O3-B2O3系统低熔点玻璃的研究. 硕士学位论文,陕西科技大学,2006. 54 Guo H W. Study on preparation and property of R2O-P2O5-ZnO system lead-free low-melting sealing glass. Master’s Thesis, Shaanxi University of Science & Technology, China, 2006(in Chinese). 郭宏伟. R2O-P2O5-ZnO系统无铅低熔封接玻璃的制备及性能研究. 硕士学位论文, 陕西科技大学, 2006. 55 Yao X G, Ren H S, Jiang S H, et al. Journal of Inorganic Materials, 2018,33(4),385(in Chinese). 姚晓刚, 任海深, 姜少虎, 等. 无机材料学报,2018,33(4),385. 56 Liu J. Journal of the Chinese Ceramic Society, 1997, 25(1), 47(in Chinese). 刘健. 硅酸盐学报, 1997, 25(1), 47. 57 Zhu S Z, Liu Y C, Yu X D, Journal of Beijing Institute of Technology,2000, 20(2), 257(in Chinese). 朱时珍, 刘以成, 于晓东. 北京理工大学学报, 2000, 20(2), 257. 58 Fedorova A, Michelsen L, Scheffler M. Journal of the European Ceramic Society, 2018, 38(2), 719. 59 García-Moreno O, Fernández A. Journal of the European Ceramic Society, 2010, 30(15), 3219. 60 Ramirez I J. Journal of the Ceramic Society of Japan, 2006, 114(1336),1111. 61 Wang B,Xu S C,Xu Z Y,et al.Materials Protection,2013,46(s1),27(in Chinese). 王波, 徐少春, 徐照芸,等.材料保护, 2013, 46(s1),27. 62 Chen N, Wang H, Huo J, et al. Journal of the European Ceramic Society, 2017,37(15),4431. 63 Schneider H, Schreuer J, Hildmann B. Journal of the European Ceramic Society, 2008, 28(2), 329. 64 Travitzky N A. Journal of Materials Science Letters, 1998, 17(19), 1609. 65 Bsat S, Huang X. International Journal of Applied Ceramic Technology, 2016, 13(6), 1074. 66 Aramide F O, Alaneme K K, Olubambi P A, et al. International Journal of Materials and Chemistry,2015,5(6), 127. 67 Li C, Bian C, Han Y, et al. Journal of the European Ceramic Society, 2016, 36(3), 761. 68 Xu G, Zhao H, Cui H, et al. Journal of the Ceramic Society of Japan,2015, 123(1435), 156. 69 Kanimozhi K, Prabunathan P, Selvaraj V, et al. Polymer Composites, 2013, 35(9), 1663. 70 Zhang H, Zhang Y, Wang B, et al. Chemical Engineering Journal, 2015, 268, 109. 71 Garcia-Moreno O, Fernandez A, Torrecillas R. International Journal of Materials Research, 2013, 103(4), 416. 72 Han S X. Hebei Ceramics, 1985(2),13(in Chinese). 韩淑贤. 河北陶瓷, 1985(2), 13. 73 Zhang W, Han Y L, Wu J X, et al. Bulletin of the Chinese Ceramic Socie-ty, 2008, 27(2), 242(in Chinese). 张巍,韩亚苓,吴嘉希,等.硅酸盐通报, 2008, 27(2), 242. 74 Pelletant A, Reveron H, Chevalier J, et al. Journal of the European Ceramic Society, 2013, 33(3), 531. 75 Huang Y M, Shang J, Zhang Y P, et al. China Ceramics, 2015, 51(7), 64(in Chinese). 黄元茂, 商静, 张艳鹏, 等. 中国陶瓷, 2015, 51(7), 64. 76 Choi W K, Kang T S, Kim N I, et al. Journal of Ceramic Processing Research, 2015, 16(3), 324. 77 Fedorova A, Hourlier D, Scheffler M. Ceramics International, 2017, 43(5), 4483.
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2020, Vol. 34 
