Please wait a minute...
《材料导报》期刊社  2017, Vol. 31 Issue (3): 1-6    https://doi.org/10.11896/j.issn.1005-023X.2017.03.001
  材料综述 |
形状记忆聚氨酯材料的研究进展*
崔航, 王锋, 胡剑青, 涂伟萍
华南理工大学化学与化工学院, 广州 510640;
Research Progress of Shape Memory Polyurethane Materials
CUI Hang, WANG Feng, HU Jianqing, TU Weiping
School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640;
下载:  全 文 ( PDF ) ( 1353KB ) 
输出:  BibTeX | EndNote (RIS)      
摘要 形状记忆聚氨酯是一种可以响应外界刺激,并通过特定的热力学过程回复到初始形态的新型智能高分子材料。基于不同的应用,提供形状展开功能、形状固定及回复功能、形状回复率及回复力可控等性能。形状记忆聚氨酯可以通过热、电、光、磁等方式直接或者间接地激发材料的形状记忆性能,在智能纺织、航空航天、生物医用等领域具有广阔的应用前景。首先介绍了形状记忆聚氨酯的结构、记忆机理和分类;然后讨论了影响其形状记忆性能的因素,主要包括硬段种类和含量的影响、软段的种类和相对分子质量的影响、交联剂的影响、掺杂填料的影响等。在此基础上总结了形状记忆聚氨酯在不同领域的应用进展,最后展望了形状记忆聚氨酯网络结构化设计思路和未来的发展方向。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
崔航
王锋
胡剑青
涂伟萍
关键词:  聚合物  聚氨酯  形状记忆    
Abstract: Shape memory polyurethane(SMPU) is a novel class of intelligent polymer materials that can recover the permanent shape in responsive to external stimuli.Base on different applications, shape memory polyurethane can provide a deployable property,shape fix and recovery property and controllable shape recovery velocity and shape recovery force.Many triggers such as heat,electronic,light,magntic can be used to activate the shape memory properties by direct or remote way. Shape memory polyurethanes show significant technological applications ranging from biomedical devices to aerospace technology.The structure, shape memory mechanism and classification of SMPUs are introduced,and factors which influence the shape memory properties are discussed.The applications of SMPUs in different fields based on above content are summarized.Finally,the future development of SMPUs with the network structure are prospected.
Key words:  polymers    polyurethane    shape memory
               出版日期:  2017-02-10      发布日期:  2018-05-02
ZTFLH:  TQ323.8  
基金资助: *广东省自然科学基金(2015A030313207);广东省公益研究与能力建设项目(2015A010105004;2015A010105023);广东省绿色化学产品技术重点实验室开放基金(GC201601)
作者简介:  崔航:男,1991年生,硕士研究生,从事有机功能高分子材料研究 E-mail:ceclackcui@mail.scut.edu.cn 涂伟萍:通讯作者,教授,博士研究生导师,主要从事有机高分子材料及其复合材料研究 E-mail:ceytu@scut.edu.cn
引用本文:    
崔航, 王锋, 胡剑青, 涂伟萍. 形状记忆聚氨酯材料的研究进展*[J]. 《材料导报》期刊社, 2017, 31(3): 1-6.
CUI Hang, WANG Feng, HU Jianqing, TU Weiping. Research Progress of Shape Memory Polyurethane Materials. Materials Reports, 2017, 31(3): 1-6.
链接本文:  
http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2017.03.001  或          http://www.mater-rep.com/CN/Y2017/V31/I3/1
1 Lendlein A, Kelch S.Shape-memory polymers[J]. Angewandte Che-mie-International Edition,2002,41(12):2034.
2 Zhang Q W,Wei H Q,Liu Y J,et al.Triple-shape memory effects of bismaleimide based thermosetting polymer networks prepared via heterogeneous crosslinking structures[J].RSC Adv,2016,6(13):10233.
3 Luo H S,Li Z W,Yi G B,et al.Electro-responsive silver nanowire-shape memory polymer composites[J]. Mater Lett,2014,134:172.
4 Fiorito F,Sauchelli M,Arroyo D,et al,Shape morphing solar sha-dings: A review[J].Renewable Sustainable Energy Rev,2016,55:863.
5 Rodriguez E D,et al.Linear/network poly(epsilon-caprolactone) ble-nds exhibiting shape memory assisted self-healing (SMASH)[J].ACS Appl Mater Interfaces,2011,3(2):152.
6 Meng Q H,Hu J H,Zhu Y,et al.Biological evaluations of a smart shape memory fabric[J].Textile Res J,2009,79(16):1522.
7 Dailing E A,Nair D P,Setterberg W K,et al.Combined, independent small molecule release and shape memory via nanogel-coated thiourethane polymer networks[J].Polym Chem,2016,7(4):816.
8 Liu Y Y,Zhao J,Zhao L Y,et al.High performance shape memory epoxy/carbon nanotube nanocomposites[J]. ACS Appl Mater Interfaces,2016,8(1):311.
9 Shao L N,Dai J,Zhang Z X,et al.Thermal and electroactive shape memory behaviors of poly(L-lactide)/thermoplastic polyurethane blend induced by carbon nanotubes[J].RSC Adv,2015,5(123):101455.
10 Chen H M,Li Y,Liu Y,et al.Highly pH-sensitive polyurethane exhibiting shape memory and drug release[J]. Polym Chem,2014,5(17):5168.
11 Behl M, Lendlein A.Shape-memory polymers[J].Mater Today,2007,10(4):20.
12 Mather P T, Luo X F, Rousseau I A.Shape memory polymer research[J].Annual Rev Mater Res,2009,39:445.
13 Behl M, Razzaq M Y, Lendlein A.Multifunctional shape-memory polymers[J].Adv Mater,2010,22(31):3388.
14 Hu J L, Chen S J.A review of actively moving polymers in textile applications[J].J Mater Chem,2010,20(17):3346.
15 Hu J L,Zhu Y,Huang H H, et al.Recent advances in shape-memory polymers: Structure, mechanism, functionality, modeling and applications[J].Prog Polym Sci,2012,37(12):1720.
16 Yang J H,Chun B C,Chung Y C,et al.Comparison of thermal/mechanical properties and shape memory effect of polyurethane block-copolymers with planar or bent shape of hard segment[J].Polymer,2003,44(11):3251.
17 Li Shucai,Jia Xunmin,Li Shuai.Effect of hard segment structure on polyurethane shape memory effect with hydrophilic group in the chain[J].China Plastics Industry,2009,37(12):44(in Chinese).
李树才,贾旭敏,李帅.硬段结构对分子链含亲水团的聚氨酯形状记忆性能的影响[J].塑料工业,2009,37(12):44.
18 Zhu Y,Hu J L,Yeung K W,et al.Shape memory effect of PU ionomers with ionic groups on hard-segments[J]. Chinese J Polym Sci,2006,24(2):173.
19 Gu L,Cui B,W Q Y,et al.Bio-based polyurethanes with shape me-mory behavior at body temperature: Effect of different chain exten-ders[J].RSC Adv,2016,6(22):17888.
20 Chen Shaojun,Su Jingcang,Zhao Wenbin,et al.Studies on selecting of the soft-segment composition of shape memory polyurethane based liquidated-MDI[J].Polym Mater Sci Eng,2005,21(5):166(in Chinese).
陈少军,粟劲苍,赵文斌,等.液化MDI形状记忆聚氨酯软段组成的选择[J].高分子材料科学与工程,2005,21(5):166.
21 Yan Bing,Deng Jianru.Structure and properties of shape memory polyurethane[J].Plastics,2003,32(5):61(in Chinese).
严冰,邓剑如.形状记忆聚氨酯的结构与性能研究[J].塑料,2003,32(5):61.
22 Kim B K,Lee S Y,Laa J S,et al.Polyurethane ionomers having shape memory effects[J].Polymer,1998,39(13):2803.
23 Ma Lifang,Li Jie,Luo Yunjun.Comparision of shape memory properties of cross-linking and linear water-based polyurethane[J].Chem Ind Eng Prog,2006,25(1):78(in Chinese).
马俪芳,李杰,罗运军.交联型与线性水性聚氨酯的形状记忆性能比较[J].化工进展,2006,25(1):78.
24 Ji Jianzhong,Xia Zhean,Weng Shengguang,et al.Silylated PCL-based polyurethane with shape memory effect[J].J East China University of Science and Technology:Natural Science Edition,2010,36(5):674(in Chinese).
嵇建忠,夏浙安,翁盛光,等.具有形状记忆效应的硅烷化聚己内酯型聚氨酯[J].华东理工大学学报:自然科学版,2010,36(5):674.
25 Xu Longbin,Cen Hao,Fu Yaqin.Effect of silica content on the pro-perties of shape memory polyurathane hybrids[J].J Zhejiang Science Technology University,2010,27(6):869(in Chinese).
徐龙彬,岑浩,傅雅琴.二氧化硅含量对形状记忆聚氨酯杂化材料性能的影响[J].浙江理工大学学报,2010,27(6):869.
26 Gunes I S,Cao F,Jana S C,et al.Evaluation of nanoparticulate fillers for development of shape memory polyurethne nanocomposites[J].Polymer,2008,49(3):2223.
27 Sattar R, Kausar A, Siddiq M.Thermal, mechanical and electrical studies of novel shape memory polyurethane/polyaniline blends[J].Chinese J Polym Sci,2015,33(9):1313.
28 Wang W S,Ping P,Chen X S,et al.Polylactide-based polyurethane and its shape-memory behavior[J]. Eur Polym J,2006,42(6):1240.
29 Sun L,Huang W M,Lu H B,et al.Heating-responsive shape-memory effect in thermoplastic polyurethanes with low melt-flow index[J].Macromolecular Chem Phys,2014,215(24):2430.
30 Mahapatra S S, Yadav S K,Yoo H J,et al.Tailored and strong electro-responsive shape memory actuation in carbon nanotube-reinforced hyperbranched polyurethane composites[J].Sensors Actuators B-Chem,2014,193:384.
31 Lendlein A,Jing H Y,Junger O,et al.Light-induced shape-memory polymers[J].Nature,2005,434(7035):879.
32 Beblo R V, Weiland L M.Light activated shape memory polymer characterization[J].J Appl Mechan-Trans ASME,2009,76(1):11008.
33 Jiang H Y, Kelch S, Lendlein A.Polymers move in response to light[J].Adv Mater,2006,18(11):1471.
34 Wu L B, Jin C L, Sun X Y.Synthesis,properties, and light-induced shape memory effect of multiblock polyesterurethanes containing biodegradable segments and pendant cinnamamide groups[J].Biomacromolecules,2011,12(1):235.
35 Park J H, Kim B K.Infrared light actuated shape memory effects in crystalline polyurethane/graphene chemical hybrids[J].Smart Mater Structures,2014,23(2):5038.
36 Razzaq M Y, Anhalt M, Frormann L,et al.Thermal,electrical and magnetic studies of magnetite filled polyurethane shape memory polymers[J].Mater Sci Eng A-Structural Materials Properties Microstructure and Processing,2007,444(1-2):227.
37 Gu S Y,Jin S P,Gao X F,et al.Polylactide-based polyurethane shape memory nanocomposites (Fe3O4/PLAUs) with fast magnetic responsiveness[J].Smart Mater Structures,2016,25(5):5036.
38 Yang B, Huang W ,Li C,et al.On the enects of moisture in a polyurethane shape memory polymer[J].Smart Mater Structures,2004,13(1):191.
39 Huang W M,Yang B,An L,et al.Water-driven programmable polyurethane shape memory polymer: Demonstration and mechanism[J].Appl Phys Lett,2005,86(11):4105.
40 Lu H W, Liu S H,Wang S L,et al.Silver nanocrystals by hyperbranched polyurethane-assisted photochemical reduction of Ag+[J].Mater Chem Phys,2003,81(1):104.
41 Kalita H,Mandal M,Karak N.Biodegradable solvent-induced shape-memory hyperbranched polyurethane[J]. J Polym Res,2012,19(10):9982.
42 Lu H B,Liu Y J,Leng J S,et al.Qualitative separation of the effect of the solubility parameter on the recovery behavior of shape-memory polymer[J].Smart Mater Structures,2009,18(8):5003.
43 Weems A C,Raymond J E,Wacker K T,et al.Examination of radio-opacity enhancing additives in shape memory polyurethane foams[J].J Appl Polym Sci,2015,132(23):42054.
44 Wache H M,Tartakowska D J,Hentrich A,et al.Development of a polymer stent with shape memory effect as a drug delivery system[J].J Mater Sci: Mater in Medicine,2003,14(2):109.
45 Chai Q Y, Huang Y S, Ayres N.Shape memory biomaterials prepared from polyurethane/ureas containing sulfated glucose[J].J Polym Sci Part A-Polym Chem,2015,53(19):2252.
46 Song J J, Chang H H, Naguib H E.Biocompatible shape memory polymer actuators with high force capabilities[J].Eur Polym J,2015,67:186.
47 Liu Y,Lu J,Hu J L,et al.Study on the bagging behavior of knitted fabrics by shape memory polyurethane fiber[J].J Textile Institute,2013,104(11):1230.
48 Mondal S, Hu J L, Yong Z.Free volume and water vapor permeabi-lity of dense segmented polyurethane membrane[J].J Membr Sci,2006,280(1-2):427.
49 Su J C,Liu P S.A novel solid-solid phase change heart storage material with polyurethane block copolymer structure[J].Energy Conversion Management,2006,47:3185.
50 Chen Y,Liu Y,Fan H J,et al.The polyurethane membranes with temperature sensitivity for water vapor permeation[J].J Membr Sci,2007,287:192.
51 Keihl M M,Bortolin R S,Sanders B,et al.Mechanical properties of shape memory polyurethane for aircraft applications[C]//Smart Structures and Materials 2005,Industrial and Commercial Applications of Smart Structues Technollogies. San Diego,CA,2005.
52 Sokolowski W, Hayashi S.Application of cold hibernated elastic memory structures[C]//Proceeding of SPIE 10th International Symposium on Smart Structures and Materials. San Diego,CA,2003.
53 Li X J,Wang Y R,Zheng Z H,et al.Structural design and property study of shape memory polymer network[J].Prog Chem,2013,25(10):1727.
54 Miller J R.Interpenetrating polymer networks styrene-diving benzene copolymers with two and three interpenetrating networks and their sulphonates[J].J Chem Soc,1960,26(3):1311.
55 Martin W, Reimund S. Hydrophilic-hydrophobic two-component polymer networks: 2. Synthesis and characterization of poly(ethy-lene oxide)-linked-polybutadiene[J].Polymer,1988,29(6):1071.
[1] 马攀龙, 张忠厚, 韩琳, 陈荣源. 交联剂和无纺布增强聚丙烯腈凝胶聚合物电解质膜的研究[J]. 材料导报, 2019, 33(z1): 457-461.
[2] 高科, 李万万. 近红外二区光声成像造影剂的研究进展[J]. 材料导报, 2019, 33(z1): 481-484.
[3] 薛晓武, 王新闻, 刘红波, 卿宁. 水性聚碳酸酯型聚氨酯的制备及性能[J]. 材料导报, 2019, 33(z1): 488-490.
[4] 路小彬. 基于嵌段共聚物的硅表面聚合物刷点阵组装[J]. 材料导报, 2019, 33(z1): 505-509.
[5] 刘国军, 张生义, 钟明月, 张桂霞, 王艳, 余大平. BEM含量对MAA-EA-MMA共聚物乳液的pH响应性研究[J]. 材料导报, 2019, 33(8): 1422-1426.
[6] 张默, 王诗彧. 常温制备赤泥-低钙粉煤灰基地聚物的试验和微观研究[J]. 材料导报, 2019, 33(6): 980-985.
[7] 崔龙辰, 王军军, 黄伟九. 类聚合物碳薄膜的制备及其摩擦学研究进展[J]. 材料导报, 2019, 33(5): 797-804.
[8] 朱继红, 曾碧榕, 罗伟昂, 袁丛辉, 陈凌南, 毛杰, 戴李宗. Fe3O4@P(St-co-OBEG)核壳结构微球负载银/铂纳米粒子复合催化剂的构筑及催化性能[J]. 材料导报, 2019, 33(4): 571-576.
[9] 翟乐, 吉海峰, 姚艳梅, 瞿雄伟. 利用聚丙烯酸正丁酯@聚甲基丙烯酸甲酯核/壳结构聚合物增韧氰酸酯树脂[J]. 材料导报, 2019, 33(4): 705-708.
[10] 魏波，周金堂，姚正军，钱逸，钱崑. 环氧树脂基体的原位增韧技术研究进展[J]. 材料导报, 2019, 33(17): 2976-2988.
[11] 王玉龙, 侯立杰, 刘志勇, 李世宇, 李卓辉. 水性聚氨酯改性环氧树脂乳液的涂膜性能研究[J]. 材料导报, 2019, 33(14): 2456-2460.
[12] 毛虎,杨宏亮,史晓斌. 纳米晶NiTi形状记忆合金的研究进展[J]. 材料导报, 2019, 33(13): 2237-2242.
[13] 马骁, 谢雪鹏, 叶雄伟, 何巨鹏, 朱杰. 基于氮气吸附法的钙基地聚合物孔隙结构分形特征[J]. 材料导报, 2019, 33(12): 1989-1994.
[14] 刘泓吟, 杨宏宇, 陈明凤. 异氰酸酯指数对聚氨酯硬泡阻燃、热稳定性及燃烧性能的影响[J]. 材料导报, 2019, 33(12): 2071-2075.
[15] 董雨菲, 马建中, 刘超, 鲍艳, 林阳, 吴英柯. SiO2的功能化改性及其与聚合物基体的界面研究进展[J]. 材料导报, 2019, 33(11): 1910-1918.
[1] Bingwei LUO,Dabo LIU,Fei LUO,Ye TIAN,Dongsheng CHEN,Haitao ZHOU. Research on the Two Typical Infrared Detection Materials Serving at Low Temperatures: a Review[J]. Materials Reports, 2018, 32(3): 398 -404 .
[2] Huimin PAN,Jun FU,Qingxin ZHAO. Sulfate Attack Resistance of Concrete Subjected to Disturbance in Hardening Stage[J]. Materials Reports, 2018, 32(2): 282 -287 .
[3] Siyuan ZHOU,Jianfeng JIN,Lu WANG,Jingyi CAO,Peijun YANG. Multiscale Simulation of Geometric Effect on Onset Plasticity of Nano-scale Asperities[J]. Materials Reports, 2018, 32(2): 316 -321 .
[4] Xu LI,Ziru WANG,Li YANG,Zhendong ZHANG,Youting ZHANG,Yifan DU. Synthesis and Performance of Magnetic Oil Absorption Material with Rice Chaff Support[J]. Materials Reports, 2018, 32(2): 219 -222 .
[5] Ninghui LIANG,Peng YANG,Xinrong LIU,Yang ZHONG,Zheqi GUO. A Study on Dynamic Compressive Mechanical Properties of Multi-size Polypropylene Fiber Concrete Under High Strain Rate[J]. Materials Reports, 2018, 32(2): 288 -294 .
[6] XU Zhichao, FENG Zhongxue, SHI Qingnan, YANG Yingxiang, WANG Xiaoqi, QI Huarong. Microstructure of the LPSO Phase in Mg98.5Zn0.5Y1 Alloy Prepared by Directional Solidification and Its Effect on Electromagnetic Shielding Performance[J]. Materials Reports, 2018, 32(6): 865 -869 .
[7] ZHOU Rui, LI Lulu, XIE Dong, ZHANG Jianguo, WU Mengli. A Determining Method of Constitutive Parameters for Metal Powder Compaction Based on Modified Drucker-Prager Cap Model[J]. Materials Reports, 2018, 32(6): 1020 -1025 .
[8] WANG Tong, BAO Yan. Advances on Functional Polyacrylate/Inorganic Nanocomposite Latex for Leather Finishing[J]. Materials Reports, 2017, 31(1): 64 -71 .
[9] HUANG Dajian, MA Zonghong, MA Chenyang, WANG Xinwei. Preparation and Properties of Gelatin/Chitosan Composite Films Enhanced by Chitin Nanofiber[J]. Materials Reports, 2017, 31(8): 21 -24 .
[10] YUAN Xinjian, LI Ci, WANG Haodong, LIANG Xuebo, ZENG Dingding, XIE Chaojie. Effects of Micro-alloying of Chromium and Vanadium on Microstructure and Mechanical Properties of High Carbon Steel[J]. Materials Reports, 2017, 31(8): 76 -81 .
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed