纳米多孔硅的多片制备及其性能表征

材料导报

2022, Vol. 36

Issue (Z1): 22010200-6

无机非金属及其复合材料

纳米多孔硅的多片制备及其性能表征

简燕, 杨文静, 杨磊, 宋绍意, 倪婕, 何银芳

重庆大学化学化工学院,重庆 400000

Multi-sheet Preparation and Characterization of Nano-porous Silicon

JIAN Yan, YANG Wenjing, YANG Lei, SONG Shaoyi, NI Jie, HE Yinfang

School of College of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400000, China

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摘要纳米级多孔硅复合含能材料是当前各国军事领域的重要新兴材料,其由于具有较大的比表面积和较高的反应活性,在一定触发条件下发生快速燃烧爆炸,放出高效能量。为实现纳米多孔硅批量生产,采用电化学阳极氧化法小批量制备多孔硅,通过扫描电子显微镜(SEM)、稳态荧光光谱仪对多孔硅的结构形貌、光致发光特性进行分析研究。结果表明:多孔硅的发光强度随腐蚀时间的延长先增后减,与电流密度呈负相关,其荧光特征峰随电解液配比中氢氟酸含量的增加趋向红移;增大电流密度和延长腐蚀时间即可制备出孔隙率大、纵向刻蚀深的多孔硅,且随着腐蚀液体系中氢氟酸浓度配比的增加,在可控的实验范围内制备出的纳米级多孔硅均匀性、致密性和平整度越好,有望实现多孔硅的批量可控生产。

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关键词: 纳米多孔硅电化学阳极氧化法批量生产光致发光性能理化性质

Abstract: Nano-porous silicon(PS) composite energetic material is currently an important emerging material in the military field of various countries. Due to the large specific surface area, high chemical activity and other excellent properties, it can cause rapid combustion and explosion under certain trigger conditions and release high-efficiency energy. In order to realize the mass production of nano-porous silicon, the electrochemical single-cell anodization method was used to prepare porous silicon in small batches, and the structure, morphology and photoluminescence properties of porous silicon were analyzed and studied by scanning electron microscope (SEM) and steady-state fluorescence spectrometer. The results show that the luminescence intensity of porous silicon increases first then decreases with the prolongation of corrosion time, and is neagatively correlated with the increase of current density; its fluorescence peak tends to red-shift with the increase of hydrofluoric acid content in the electrolyte ratio; the increase of current density and etching time benefits the preparation of porous silicon with large porosity and deep longitudinal etching, and with the increase of the concentration ratio of hydrofluoric acid in the etching solution system, better uniformity, compactness and flatness of nano-scale porous silicon can be obtained within the range of controlled experimental conditions, for which the batch controllable production of porous silicon can be effectively realized.

Key words: nano-porous silicon electrochemical etching batch preparation photoluminescence physical and chemical properties

出版日期: 2022-06-05 发布日期: 2022-06-08

ZTFLH:

TN304

基金资助: 重庆市重点实验室开放课题(KFJJ2004)

通讯作者: yangwj308@163.com

作者简介: 简燕,2015年6月毕业于海南师范大学应用化学专业,获得理学学士学位。现为重庆大学硕士研究生,在杨文静教授的指导下进行研究。目前主要研究方向为纳米多孔硅新型材料及其复合含能材料的爆炸性能研究。
杨文静,重庆大学化学化工学院教授、硕士研究生导师。2002年重庆大学应用化学专业本科毕业,2006年重庆大学化学化工学院物理化学专业硕士毕业后在重庆大学任教至今, 2017年博士毕业于重庆大学化学化工学院,获化学工程与技术专业博士学位。目前主要从事于表面工程、硅基含能材料等方面的研究工作。申请获取专利30余篇,发表科技论文30余篇,包括Electrochemical Study,Physical Chemisty Letters,Bioelectrochemistry等。

引用本文:

简燕, 杨文静, 杨磊, 宋绍意, 倪婕, 何银芳. 纳米多孔硅的多片制备及其性能表征[J]. 材料导报, 2022, 36(Z1): 22010200-6.
JIAN Yan, YANG Wenjing, YANG Lei, SONG Shaoyi, NI Jie, HE Yinfang. Multi-sheet Preparation and Characterization of Nano-porous Silicon. Materials Reports, 2022, 36(Z1): 22010200-6.

链接本文:

http://www.mater-rep.com/CN/ 或 http://www.mater-rep.com/CN/Y2022/V36/IZ1/22010200

1 Lu Z, Liu N, Lee H W, et al. ACS Nano, 2015, 9(3), 2540.
2 Tölli M A, Ferreira M, Kinnunen S M. Biomaterials, 2014, 35(29), 8394.
3 Mora M B, Bornacelli J, Nava R, et al. Journal of Luminescence, 2014, 146, 247.
4 Kozak D A, Stievater T H, Pruessner M W, et al. ECS Transactions, 2014, 64(1), 197.
5 Santos H A, Mäkilä E, Airaksinen A J, et al. Nanomedicine, 2014, 9(4),535.
6 Martinpalma R J, Mansosilvan M, Torrescosta V. Journal of Nanophoto-nics, 2010, 4(1),3150.
7 张栋. 周期性硅纳米线和纳米多孔硅的制备及其光电性能研究. 博士学位论文, 上海师范大学, 2016.
8 Costa V T, Martin-Palma R J. Journal of Materials Science, 2010, 45(11), 2823.
9 Diener J, Gross E , Künzer N, et al. patent, US6803244B2, 2004.
10 Kovalev, Timoshenko V Y, Kunzner N, et al. Physical Review Letters,2001,87(6), 11.
11 Clement D, Diener J, Grcss E, et al. Physica Status Solidi (a) , 2005,202(8), 1357.
12 Mccord P, Yau S L, Bard A J. Science, 1992, 257(5066), 68.
13 王晶禹, 张景林, 徐文峥.火炸药学报, 2003, 26(1), 4.
14 许高斌, 卢翌, 陈兴, 等.电子测量与仪器学报, 2014(12),1308.
15 任秀秀, 赵省向, 韩仲熙, 等.材料导报:综述篇, 2019, 33(23), 91.
16 眭俊. 多孔硅的电化学制备及其性能研究.博士学位论文, 南昌航空大学, 2013.
17 张华, 李蛟, 丛日敏.山东理工大学学报: 自然科学版, 2015, 29(3), 20.
18 牟奕轩, 简燕, 陈金, 等.山东化工, 2021,50(4),6.
19 Splinter A, Stürmann J, Benecke W. Sensors and Actuators A: Physical, 2001, 92(1-3), 394.
20 宋晓岚, 喻振兴, 程蕾, 等.中南大学学报(自然科学版), 2010(4),1229.
21 Sujatha L, Bhattachaeya E. Sadhana-Academy Proceeding in Engineering Sciences, 2009, 34(4), 643.

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