化学石膏制备α-半水石膏的研究进展

材料导报

2021, Vol. 35

Issue (z2): 241-247

无机非金属及其复合材料

化学石膏制备α-半水石膏的研究进展

董一苇¹, 徐祖顺^1,2, 杨婷婷^1,2, 高庆^1,2

1 湖北大学材料科学与工程学院,功能材料绿色制备与应用教育部重点实验室,高分子材料湖北省重点实验室,武汉 430062
2 有机化工新材料湖北省协同创新中心,武汉 430062

Research Progress on the Preparation of α-Calcium Sulfate Hemihydrate from Chemical Gypsum

DONG Yiwei¹, XU Zushun^1,2, YANG Tingting^1,2, GAO Qing^1,2

1 Key Laboratory for the Green Preparation and Application of Functional Materials of Ministry of Education, Hubei Key Laboratory of Polymer Materials, School of Materials Science and Engineering, Hubei University, Wuhan 430062, China
2 Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Wuhan 430062, China

摘要
参考文献
相关文章
推荐阅读
Metrics

下载:

全文 ( PDF ) ( 15820KB )
输出: BibTeX | EndNote (RIS)

摘要随着我国经济和工业的高速发展,化学石膏(磷石膏、烟气脱硫石膏、钛石膏等)的年排放量日益增长,这些化学石膏通常以堆积填埋的方式处理,占用大量土地,严重污染大气和地下水。最有前景和效益的处理方式是将化学石膏转化为α-半水石膏(α-CaSO₄·0.5H₂O,α-HH)。α-HH的性能和应用方向很大程度依赖于其形貌控制,其中短柱状和晶须状的α-HH因综合性能优越而尤为引人注目。本文在分析化学石膏处理现状的基础上,综述了国内外利用化学石膏制备短柱状和晶须状α-HH的研究进展。文章讨论了α-HH的制备方法,晶体形貌对α-HH性能及应用的影响和转晶剂对α-HH形貌的影响及相关机理,指出了现有制备方法的不足,并对未来α-HH制备工艺的发展进行了展望。

	服务
	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	董一苇
	徐祖顺
	杨婷婷
	高庆

关键词: 化学石膏 α-半水石膏晶体形貌转晶剂

Abstract: With the rapid development of China's economy and industry, the annual emissions of chemical gypsum (phosphogypsum, flue gas desulfurization gypsum, titanium gypsum, etc.) are increasing. Most of the chemical gypsum is deposited in landfill sites, which occupies a lot of land and seriously pollutes the atmosphere and groundwater. The most promising and effective treatment is to convert chemical gypsum into α-calcium sulfate hemihydrate (α-CaSO₄·0.5H₂O, α-HH). The performance and application direction of α-HH largely depend on its morphology control. The short columnar and whisker-like α-HH are particularly eye-catching due to its superior comprehensive performance. Based on the analysis of current status of chemical gypsum treatment, this paper reviews the research progress at home and abroad on the preparation of short columnar and whisker-like α-HH with chemical gypsum. The paper discusses the preparation methods of α-HH, the effect of crystal morphology on the performance and application of α-HH, the effect of modifier on the crystal morphology of α-HH and related mechanism. The shortcomings of existing preparation methods are pointed out, and the future development of α-HH preparation process is prospected.

Key words: chemical gypsum α-calcium sulfate hemihydrate crystal morphology modifier

发布日期: 2021-12-09

ZTFLH:	O614.23
	TB321
	TQ132.3

通讯作者: gaoqing1969@126.com

作者简介: 董一苇,2017年6月毕业于湖北大学,获得工学学士学位。现为湖北大学材料科学与工程学院研究生,目前主要研究方向为固体废弃物资源化利用。
徐祖顺,教授,博士研究生导师,湖北大学“秦园学者”特聘教授,湖北省政府专项津贴专家。主要从事乳液聚合及聚合物乳液、功能性高分子微球、耐高温高分子材料、生物医用材料、环境友好型涂料及胶黏剂等领域的研究。近年来,承担国家、省部级科研项目多项,在Biomateirals, Macromolecules 等国内外刊物上发表论文200多篇,出版学术专著2部,申请发明专利多项。研制开发的多种产品已转让企业生产,产生了良好的经济效益和社会效益。
高庆,副教授,2007年获武汉科技大学材料学博士学位,主要研究方向包括水溶性高分子反相乳液聚合、两性聚丙烯酰胺高效水处理剂、固体废弃物资源化利用等。先后承担及参与国家863高新计划、湖北省自然科学基金及横向项目多项,在国内外学术期刊发表论文30余篇。

引用本文:

董一苇, 徐祖顺, 杨婷婷, 高庆. 化学石膏制备α-半水石膏的研究进展[J]. 材料导报, 2021, 35(z2): 241-247.
DONG Yiwei, XU Zushun, YANG Tingting, GAO Qing. Research Progress on the Preparation of α-Calcium Sulfate Hemihydrate from Chemical Gypsum. Materials Reports, 2021, 35(z2): 241-247.

链接本文:

http://www.mater-rep.com/CN/ 或 http://www.mater-rep.com/CN/Y2021/V35/Iz2/241

1 Duan P X, Li Y, Wang H Y, et al. U.S. patent, US10040696B2, 2018.
2 Zhang Y H, Wang F, Huang H W, et al. Environmental Technology, 2016, 37(9), 1094.
3 Ma X L, Tan H B, He X C. Energy Sources, 2018, 40(17), 2055.
4 Li X B, Zhang Q, Ke B L, et al. Journal of Crystal Growth, 2018, 493, 34.
5 Tian T, Yan Y, Hu Z H, et al. Construction and Building Materials, 2016, 115, 143.
6 Rashad A M. Journal of Cleaner Production, 2017, 166, 732.
7 Li X P, Mao Y M, Liu X C. Ecological Engineering, 2015, 82, 566.
8 Yang J C, Wu H D, Teng N C, et al. Ceramics International, 2012, 38(1), 381.
9 Li X, Xu C P, Hou Y L, et al. Biomedical Materials, 2014, 9(4), 045010.
10 Fu H L, Jia C Y, Chen Q S, et al. Particuology, 2018, 40, 98.
11 Jia C Y, Wu L C, Chen Q S, et al. Chemosphere, 2020, 255, 126936.
12 Jia C Y, Chen Q S, Zhou X, et al. Industrial & Engineering Chemistry Research, 2016, 55(34), 9189.
13 张咏青. α半水硫酸钙的制备及其性能研究. 硕士学位论文, 北京化工大学, 2017.
14 Zürz A, Odler I, Thiemann F, et al. Journal of the American Ceramic Society, 1991, 74(5), 1117.
15 Guan B H, Yang L C, Wu Z B, et al. Fuel, 2009, 88(7), 1286.
16 Yang B J, Dong Y Z, Wang B N, et al. Materials Research Express, 2019, 6(4), 045507.
17 桂苗苗, 丛钢.重庆建筑大学学报, 2001, 23(1), 62.
18 Jiang N, Zhang C, Xue C H, et al. Materials Research Express, 2018, 5(7), 075004.
19 Chen J M, Gao J, Yin H B, et al. Materials Science and Engineering C, 2013, 33(6), 3256.
20 Guan B H, Kong B, Fu H L, et al. Fuel, 2012, 98, 48.
21 蒋光明. α半水石膏亚稳定特性及其在醇水溶液中的结晶规律及颗粒特性.博士学位论文,浙江大学, 2015.
22 冯驸, 胡超, 张苏萌, 等. 硅酸盐通报, 2020, 39(6), 1842.
23 Ma B G, Lu W D, Su Y, et al. Journal of Cleaner Production, 2018, 195, 396.
24 Sonnier R, Leroy E, Clerc L, et al. Polymer Testing, 2007,26(2), 274.
25 Wang P, Lee E J, Park C S, et al. Journal of the American Ceramic Society, 2008, 91(6), 2039.
26 Shen Z X, Guan B H, Fu H L, et al. Journal of the American Ceramic Society, 2009, 92(12), 2894.
27 Chen C R, Qin S Y, Li S X, et al. Materials Science and Engineering:A, 2000, 278(1-2), 96.
28 Feldmann T, Demopoulos G P. Journal of Crystal Growth, 2012, 351(1), 9.
29 Duan Z Y, Li J X, Li T G, et al. Construction and Building Materials, 2017, 133, 323.
30 Li F, Liu J L, Yang G Y, et al. Journal of Crystal Growth, 2013, 374, 31.
31 Li X B, Zhang Q, Shen Z H, et al. Journal of Crystal Growth, 2019, 511, 48.
32 何玉龙, 陈德玉, 蔡攀, 等.人工晶体学报, 2016, 45(1), 192.
33 Yuan W J, Cui J Y, Cai Y B, et al. Journal of Polymer Research, 2015, 22, 173.
34 Li L X, Hao H Q, Yuan Z T. Crystals, 2018, 8(11), 417.
35 马园园, 王铭佳, 刘在彤, 等. 无机盐工业, 2018, 50(8), 52.
36 Feng X, Zhang Y, Wang G L, et al. Powder Technology, 2015, 271, 1.
37 陈绍鹏. 钛白废酸制备α半水石膏及形貌控制.硕士学位论文,郑州大学,2015.
38 Guan Q J, Hu Y H, Tang H H, et al. Journal of Colloid and Interface Science, 2018, 530, 292.
39 Guan Q J, Tang H H, Sun W, et al. Industrial & Engineering Chemistry Research, 2017, 56(35), 9831.
40 Guan Q J, Sun W, Hu Y H, et al. RSC Advances, 2017, 7(44), 27807.
41 Shen Z X, Guan B H, Fu H L, et al. Journal of the American Ceramic Society, 2009, 92(12), 2894.
42 Yang L, Cao J X, Luo T. Journal of Crystal Growth, 2018, 486, 30.
43 Fan H, Song X F, Liu T J. Journal of Crystal Growth, 2018, 495, 29.
44 吴峰, 吴硕琮, 马家玉, 等. 化工进展, 2018, 37(4), 1536.
45 Guan Q J, Sun W, Liu R Q, et al. Journal of Central South University, 2018, 25(3), 526.
46 Guan Q J, Sun W, Hu Y H, et al. Scientific Reports, 2017, 7(1), 1.
47 Jiang G M, Fu H L, Savino K, et al. Crystal Growth & Design, 2013, 13(11), 5128.
48 Yang L C, Wu Z B, Guan B H, et al. Journal of Crystal Growth, 2009, 311(20), 4518.
49 Jiang G M, Wang H, Chen Q S, et al. Fuel, 2016, 174, 235.
50 方羊. 水热法制备半水硫酸钙晶须及其长径比的可控研究.硕士学位论文, 合肥工业大学, 2017.
51 Rashad M M, Mahmoud M H H, Ibrahim I A, et al. Journal of Crystal Growth, 2004, 267(1-2), 372.
52 付文健, 林美庆, 何慧艳, 等. 华东理工大学学报, 2019, 45(2), 266.
53 Ballirano P, Maras A, Meloni S, et al. European Journal of Mineralogy, 2001, 13(5), 985.
54 Bezou C, Nonat A, Mutin J C. Journal of Solid State Chemistry, 1995, 117(1), 165.
55 Freyer D, Voigt W. Monatshefte für Chemie, 2003, 134(5), 693.
56 Van Der Sluis S, Witkamp G J, Van Rosmalen G M. Journal of Crystal Growth, 1986, 79(1-3), 620.
57 Kong B, Guan B H, Yates M Z, et al. Langmuir, 2012, 28(40), 14137.

[1]	王海威, 张华, 杜祖亮. 二十二酸Langmuir膜诱导KNO₃微晶取向生长研究[J]. 材料导报, 2021, 35(Z1): 128-131.

[1]	Lanyan LIU,Jun SONG,Bowen CHENG,Wenchi XUE,Yunbo ZHENG. Research Progress in Preparation of Lignin-based Carbon Fiber[J]. Materials Reports, 2018, 32(3): 405 -411 .
[2]	Haoqi HU,Cheng XU,Lijing YANG,Henghua ZHANG,Zhenlun SONG. Recent Advances in the Research of High-strength and High-conductivity CuCrZr Alloy[J]. Materials Reports, 2018, 32(3): 453 -460 .
[3]	Yanchun ZHAO,Congyu XU,Xiaopeng YUAN,Jing HE,Shengzhong KOU,Chunyan LI,Zizhou YUAN. Research Status of Plasticity and Toughness of Bulk Metallic Glass[J]. Materials Reports, 2018, 32(3): 467 -472 .
[4]	Xinxing ZHOU,Shaopeng WU,Xiao ZHANG,Quantao LIU,Song XU,Shuai WANG. Molecular-scale Design of Asphalt Materials[J]. Materials Reports, 2018, 32(3): 483 -495 .
[5]	Yongtao TAN, Lingbin KONG, Long KANG, Fen RAN. Construction of Nano-Au@PANI Yolk-shell Hollow Structure Electrode Material and Its Electrochemical Performance[J]. Materials Reports, 2018, 32(1): 47 -50 .
[6]	Ping ZHU,Guanghui DENG,Xudong SHAO. Review on Dispersion Methods of Carbon Nanotubes in Cement-based Composites[J]. Materials Reports, 2018, 32(1): 149 -158 .
[7]	Fangyuan DONG,Shansuo ZHENG,Mingchen SONG,Yixin ZHANG,Jie ZHENG,Qing QIN. Research Progress of High Performance ConcreteⅠ:Raw Materials and Mix Proportion Design Method[J]. Materials Reports, 2018, 32(1): 159 -166 .
[8]	Guiqin HOU,Yunkai LI,Xiaoyan WANG. Research Progress of Zinc Ferrite as Photocatalyst[J]. Materials Reports, 2018, 32(1): 51 -57 .
[9]	Jianxiang DING,Zhengming SUN,Peigen ZHANG,Wubian TIAN,Yamei ZHANG. Current Research Status and Outlook of Ag-based Contact Materials[J]. Materials Reports, 2018, 32(1): 58 -66 .
[10]	Jing WANG,Hongke LIU,Pingsheng LIU,Li LI. Advances in Hydrogel Nanocomposites with High Mechanical Strength[J]. Materials Reports, 2018, 32(1): 67 -75 .

Viewed

Full text

Abstract

Cited

Shared

Discussed