溶胶-凝胶法制备Eun+x∶SiO2薄膜及其性能研究

材料导报

2019, Vol. 33

Issue (Z2): 165-168

无机非金属及其复合材料

溶胶-凝胶法制备Euⁿ⁺_x∶SiO₂薄膜及其性能研究

王海风^1,2, 王若轩¹, 董云谷¹, 刘鑫¹

1 东华大学材料科学与工程学院,上海 201620;
2 东华大学先进玻璃制造技术教育部工程研究中心,上海 201620

Preparation of Euⁿ⁺_x∶SiO₂ Thin Film by Sol-gel Method and Its Property

WANG Haifeng^1,2, WANG Ruoxuan¹, DONG Yungu¹, LIU Xin¹

1 College of Materials Science and Engineering, Donghua University, Shanghai 201620;
2 Engineering Research Center of Advanced Glass Manufacturing Technology, Ministry of Education, Donghua University, Shanghai 201620

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摘要使用溶胶-凝胶法制备了Eu掺杂SiO₂ (Euⁿ⁺_x∶SiO₂)薄膜,Eu与SiO₂的物质的量比分别为5%、10%、15%和20%。利用X射线衍射仪(XRD)、傅里叶红外光谱仪(FT-IR)、显微维氏硬度计、万能试验机以及接触角测量仪等研究了薄膜结构及其性能。研究结果表明,Eu掺杂使SiO₂薄膜更容易析晶;Eu掺杂可以提高SiO₂薄膜的透过率,提高基体的硬度并改善其弯曲强度,同时,Eu掺杂还能进一步提高薄膜的亲水性。但Eu掺杂量过高时(Eu与SiO₂的物质的量比大于10%),薄膜的强度有所下降,脆性增加,对基体薄膜性能产生不利影响。

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关键词: 溶胶-凝胶法 Eu³⁺掺杂薄膜光学性能力学性能

Abstract: Eu doping SiO₂ (Euⁿ⁺_x∶SiO₂) thin films were prepared by sol-gel method, and the molar ratio of Eu to SiO₂ were 5%, 10%, 15% and 20% respectively. The structure and properties of the films were studied by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), microscopic Vickers hardness tester, universal testing machine and contact angle measuring instrument. The results show that the Eu doping can make the film easier to crystallize, and it can improve the sample transmittance significantly, improve the bending strength of the sample and raise its hardness. Eu doping can also further improve the hydrophilic of the film. However, excessive Eu doping (the molar ratio of Eu to SiO₂ is greater than 10%) can have an adverse effect on the film.

Key words: sol-gel method Eu³⁺-doped film optical properties mechanical property

出版日期: 2019-11-25 发布日期: 2019-11-25

ZTFLH:

TB383

通讯作者: whf2008@dhu.edu.cn

作者简介: 王海风,东华大学副教授,2002.9—2006.3于东华大学获得博士学位。2006.4—2008.3于东华大学从事博士后研究工作,2008.4至今,任教于东华大学材料科学与工程学院,其中2013.2—2014.2至澳大利亚新南威尔士大学进行访学。研究工作主要围绕无机非金属材料、特种玻璃以及复合介质材料等,以第一作者在国内外学术期刊上发表论文数十篇,申请国家发明专利十余项,其中授权5项。主持包括国家军工配套项目、上海市自然科学基金、中央高校基本科研业务费以及多项企业合作项目,参与科技部重点研发项目2项。获省部级科技进步二等奖一项。已培养硕士十余名,本科生近百名。

引用本文:

王海风, 王若轩, 董云谷, 刘鑫. 溶胶-凝胶法制备Euⁿ⁺_x∶SiO₂薄膜及其性能研究[J]. 材料导报, 2019, 33(Z2): 165-168.
WANG Haifeng, WANG Ruoxuan, DONG Yungu, LIU Xin. Preparation of Euⁿ⁺_x∶SiO₂ Thin Film by Sol-gel Method and Its Property. Materials Reports, 2019, 33(Z2): 165-168.

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http://www.mater-rep.com/CN/ 或 http://www.mater-rep.com/CN/Y2019/V33/IZ2/165

1 Gouadria S, Najeh I, El Mir L. Journal of Physics and Chemistry of So-lids,2017,110,290.
2 Laura Vivar Mora, Sanjeev Naik, Shiladitya Paul, et al. Surface & Coa-tings Technology,2017,327,368.
3 Man Y R, Li Z H, Shu M, et al. Surface and Interface Analysis,2017,49,843.
4 Ji Z H, Bao L, Wang H N, et al. Materials Letters,2017,207,21.
5 马胜红,赵玉文,王斯成.太阳能,2005(4),10.
6 熊华山.溶胶-凝胶法制备SiO₂增透膜的研究.硕士学位论文,四川大学,2004.
7 Guo Z Q, Liu Y, Tang M Y, et al. Solar Energy Materials and Solar Cells,2017,170,143.
8 Hu G X, Que W X, Chen Z L, et al. Journal of Sol-Gel Science Technology,2017,83,666.
9 孙继红,范文浩,徐耀,等.光学技术,1999(4),27.
10 Schilling J H, Johnson L K. Journal of Propulsion and Power,2002,18(4),339.
11 关欣,王衍行.中国建材科技,2002,34-36,58.
12 Rajesh D, Tapati J, Swati R. Solar Energy Materials and Solar Cells,2005,86(2),207.
13 Ohta M, Yasuda M, Takami M. Journal of Alloys and Compounds,2000,303-304,320.
14 Nakata R, Hashimoto N, Kawano K, et al. Japanese Journal of Applied Physics,1996,35(2),90.
15 张思远.稀土离子的光谱学——光谱性质和光谱理论,科学出版社,2008.
16 张锐,秦丹丹,王海龙,等.郑州大学学报,2006,27(3),119.
17 丽秋,刘丽萍.齐齐哈尔师范学院学报,1997,17(4),40.
18 何飞,赫晓东,李垚.材料工程,2006(1),72.
19 李晨松,徐廷献.硅酸盐通报,2003(2),23.

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