Abstract: The present work aimed to find an appropriate calculation model for the stacking fault energy (SFE) of Fe-Mn-Al-C low-density steels so as to facilitate the relevant research upon the SFE of this representative species of high-strength steel. We discussed and depicted the SFE calculation model established based on the pertinent thermodynamics theory and the experimental met-hods for determining SFE. Based on the Olson-Cohen thermodynamics model, we then calculated the SFE of some Fe-Mn-Al-C steels which had been determined in previous works to evaluate the reliability of Olson-Cohen model, and subsequently carried out the inverse correction for main parameters in the model. The computer-assisted theoretical calculation results of the SFE for the series of Fe-(10-30)Mn-(0-12)Al-(0-1.2)C (wt%) low-density steels showed that more Mn, Al or C elements will all lead to larger SFE. SFE’s sensitivity toward Al is the highest and the influence of various elements are γSFE,Al>γSFE,Mn>γSFE,C. In addition, under high temperature range (300-1 000 K) the SFE increases at a higher rate compared with low temperature range (0-300 K).
章小峰, 杨浩, 李家星, 阚中伟, 施琦, 黄贞益. 基于热力学理论的Fe-Mn-Al-C系低密度钢层错能计算模型[J]. 材料导报, 2018, 32(16): 2859-2864.
ZHANG Xiaofeng, YANG Hao, LI Jiaxing, KAN Zhongwei, SHI Qi, HUANG Zhenyi. The Stacking Fault Energy (SFE) Calculation Model for Fe-Mn-Al-C Low-density Steels Based on Thermodynamics Theory. Materials Reports, 2018, 32(16): 2859-2864.
1 Frommeyer G, Brüx U. Microstructures and mechanical properties of high-strength Fe-Mn-Al-C light-weight TRIPLEX steels[J]. Steel Research International,2006,77(9):627. 2 Stout Y J, Kamiya N, Umino R. High-strength Fe-20Mn-Al-C-based alloys with low density[J]. ISIJ International,2010,50(6):893. 3 Chen P C, Chao C G, Liu T F. A novel high-strength, high-ductility and high-corrosion-resistance FeAlMnC low-density alloy[J]. Scripta Materialia,2013,68(6):380. 4 章小峰,杨浩,阚中伟,等.国内外高强韧性低密度钢的研发进展[N].世界金属导报,2017-05-16(B10). 5 Feng Z X, Zhang X Y, Pan F S. Thermodynamic model for the influence of temperature on the stacking fault energy in hcp metals[J]. Rare Metal Materials and Engineering,2012,41 (9):1638(in Chinese). 冯中学,张喜燕,潘复生.温度对六方系金属层错能影响的热力学模型[J].稀有金属材料与工程,2012,41(9):1638. 6 Medvedeva N I, Park M S, Van Aken D C. First-principles study of Mn, Al and C distribution and their effect on stacking fault energies in fcc Fe[J]. Journal of Alloys and Compounds,2014,582(2):475. 7 Dieter G E. Mechanical metallurgy[M]. Berlin: Springer,1993. 8 Lan P, Song L N, Du C W, et al. Research progress on stacking fault energy in high manganese TWIP steel[J]. Journal of Iron and Steel Research,2015,27(1):1(in Chinese). 兰鹏,宋丽娜,杜辰伟,等.高锰TWIP钢层错能的研究进展[J].钢铁研究学报,2015,27(1):1. 9 Xiong R L, Peng H B, Si H T, et al. Thermodynamic calculation of stacking fault energy of the Fe-Mn-Si-C high manganese steels[J]. Materials Science and Engineering A,2014,598(598):376. 10 Gallagher P C J. The influence of alloying, temperature, and related effects on the stacking fault energy[J]. Metallurgical Transactions,1970,1(9):2429. 11 Nakano J, Jacques P J. Effects of the thermodynamic parameters of the hcp phase on the stacking fault energy calculations in the Fe-Mn and Fe-Mn-C systems[J]. Calphad-computer Coupling of Phase Diagrams and Thermochemistry,2010,34(2):167. 12 Ferreira P J, Müllner P. A thermodynamic model for the stacking-fault energy[J]. Acta Materialia,1998,46(13):4479. 13 Tian X, Li H, Zhang Y S. Effect of Al content on stacking fault energy in austenitic Fe-Mn-Al-C alloys[J]. Journal of Materials Science,2008,43(18):6214. 14 Yang W S, Wan C M. The influence of aluminium content to the stacking fault energy in Fe-Mn-Al-C alloy system[J]. Journal of Materials Science,1990,25(3):1821. 15 Olson G B, Cohen M. A general mechanism of martensitic nucleation—Part Ⅰ: General concepts and the FCC→HCP transformation[J]. Metallurgical and Mate-rials Transactions A,1976,7(12):1897. 16 Curtze S, Kuokkala V T, Oikari A, et al. Thermodynamic modeling of the stacking fault energy of austenitic steels[J]. Acta Materialia,2011,59(3):1068. 17 Zhang X F, Leng D P, Zhang L, et al. Influence of aluminum content on stacking fault energy and mechanical twin of low-density Fe-Mn-Al-C steels[J]. Transactions of Materials and Heat Treatment,2015,36(12):128(in Chinese). 章小峰,冷德平,张龙,等.Al含量对Fe-Mn-Al-C系低密度钢层错能及形变孪晶的影响[J].材料热处理学报,2015,36(12):128. 18 Tian X, Zhang Y S. Effect of Aluminum, Chromium and Silicon on the lattice parameter for Fe-Mn-C austenite[J]. Materials Science Progress,1991,5(1):48(in Chinese). 田兴,张彦生.Al,Cr,Si对Fe-Mn-C奥氏体点阵参数的影响[J].材料科学进展,1991,5(1):48. 19 Dai Y J, Tang D, Mi Z L, et al. The influence of manganese on the stacking fault Energy and deformation mechanisms of the TWIP steel[J]. Journal of Materials Engineering,2009(7):39(in Chinese). 代永娟,唐荻,米振莉,等.锰元素对TWIP钢层错能和变形机制的影响[J].材料工程,2009(7):39. 20 Jeong J S, Woo W, Oh K H, et al. In situ neutron diffraction study of the microstructure and tensile deformation behavior in Al-added high manganese austenitic steels[J]. Acta Materialia,2012,60(5):2290. 21 Kim J, Cooman B C D. On the stacking fault energy of Fe-18Pct Mn-0.6 Pct C-1.5 Pct Al twinning-induced plasticity steel[J]. Metallurgical and Materials Transactions A,2011,42(4):932. 22 Noskva R P, Pavlov V A.Stacking faults in nickel solid solutions[J]. The Physics of Metals and Metallography,1962,14(6):86 23 Reed R P, Schramm R E. Relationship between stacking-fault energy and X-ray measurements of stacking-fault probability and microstrain[J]. Journal of Applied Physics,1974,45(11):4705. 24 Zambrano O A. Stacking fault energy maps of Fe-Mn-Al-C-Si steels: Effect of temperature, grain size, and variations in compositions[J]. Journal of Engineering Materials and Technology,2016,138(4):041010. 25 Jin J E, Lee Y K. Effects of Al on microstructure and tensile pro-perties of C-bearing high Mn TWIP steel[J]. Acta Materialia,2012,60(4):1680. 26 Kim J, Lee S J, Cooman B C D. Effect of Al on the stacking fault energy of Fe-18Mn-0.6C twinning-induced plasticity[J]. Scripta Materialia,2011,65(4):363. 27 Saeed A, Imlau J, Prahl U, et al. Derivation and variation in composition-dependent stacking fault energy maps based on subregular solution model in high-manganese steels[J]. Metallurgical and Mate-rials Transactions A,2009,40(13):3076. 28 Das A. Revisiting stacking fault energy of steels[J]. Metallurgical and Materials Transactions A,2016,47(2):748. 29 Remy L, Pineau A. Twinning and strain-induced FCC→HCP transformation in the Fe-Mn-Cr-C system[J]. Materials Science and Engineering,1977,28(1):99. 30 Han Y S, Hong S H. The effect of Al on mechanical properties and microstructures of Fe-32Mn-12Cr-xAl-0.4C cryogenic alloys[J]. Materials Science and Engineering A,1997,222(1):76.