竹纸老化的热解特性及其老化程度的量化评价

doi:10.11896/cldb.21040180

材料导报

2022, Vol. 36

Issue (13): 21040180-5 https://doi.org/10.11896/cldb.21040180

高分子与聚合物基复合材料

竹纸老化的热解特性及其老化程度的量化评价

陈彪^1,†, 谭静^1,†, 付小航¹, 卢郁静¹, 朱玥玮¹, 黄晶¹, 狄雨萌¹, 丁延伟^2,*

1 中国科学技术大学科技史与科技考古系,合肥 230026
2 中国科学技术大学合肥微尺度物质科学国家研究中心,合肥 230026

Study on Pyrolysis Characteristics of Bamboo Paper After Aging and Quantitative Evaluation of Its Aging Degree

CHEN Biao^1,†, TAN Jing^1,†, FU Xiaohang¹, LU Yujing¹, ZHU Yuewei¹, HUANG Jing¹, DI Yumeng¹, DING Yanwei^2,*

1 Department of History of Science and Scientific Archaeology, University of Science and Technology of China, Hefei 230026, China
2 Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei 230026,China

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摘要为探讨表征纸张老化特性的新指标,对竹纸进行不同条件的干热老化处理,利用热重法(TG)研究竹纸老化后的热解特性,并测定纸张的抗张强度,计算抗张指数保留率(Ri)。实验结果表明,随老化温度升高,竹纸的TG曲线及DTG曲线中的特征温度依次降低,其热稳定性变差。热解特征温度T_0.5随老化程度加剧而不断下降,其差值ΔT_0.5可作为评价竹纸老化程度的参数。对不同老化条件下竹纸的ΔT_0.5与Ri进行回归分析,结果显示竹纸的ΔT_0.5与Ri之间存在指数关系,可建立评价竹纸老化程度的量化模型。以实验所测其他种类竹纸样品的ΔT_0.5和Ri通过平均绝对百分比误差和后验差检验来综合验证指数模型的精度,所得结果均符合两种指标对模型高精度拟合等级的划分标准,表明该模型对不同种类竹纸的老化程度评价具有较好的有效性,尤其对珍贵纸张的老化研究具有微损分析的独特优势。

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	陈彪
	谭静
	付小航
	卢郁静
	朱玥玮
	黄晶
	狄雨萌
	丁延伟

关键词: 竹纸干热老化热重法热解性质老化评价

Abstract: There are new indicators of paper aging that need to be explored in cultural relics conservation. In this work, based on the accelerated heat aging of bamboo paper, its pyrolysis characteristics after aging were studied via the thermogravimetry, and the retention rate of tensile index (Ri) of bamboo paper was tested. The results show that with rising aging temperatures, the characteristic temperatures of TG curve of bamboo paper as well as DTG curve has gradually reduced in turn, which reflects that the thermal stability of bamboo paper decreased after aging. With the aging degree of bamboo paper aggravated, the temperature of its 50% weight loss (T_0.5) has declined. Therefore, the T_0.5 can be used as one of the indicators to reflect the aging characteristics of paper, the different value of T_0.5 (ΔT_0.5) between bamboo paper before and after aging can be used as the parameter to evaluate its aging degree. The ΔT_0.5 and Ri of bamboo paper under different aging conditions were used for regression analysis, it is found that there is an exponential quantitative relationship between ΔT_0.5 and Ri, which indicates the evaluation model for the aging degree of bamboo paper can be established. The ΔT_0.5 and Ri of other bamboo paper samples tested were used to verify the accuracy of the quantitative model by two methods (Mean Absolute Percentage Error and Posterior-Variance-Test), which indicates the model has high-precision fitting level and can be used to evaluate the aging of bamboo paper with different raw materials and paper-making technologies, especially for studying some precious or small amounts of paper.

Key words: bamboo paper heat aging thermogravimetry pyrolysis characteristics aging evaluation

出版日期: 2022-07-10 发布日期: 2022-07-12

ZTFLH:

O642

基金资助: 国家自然科学基金(31200455)

通讯作者: * ywding@ustc.edu.cn

作者简介: 陈彪,中国科学技术大学科技史与科技考古系副教授、硕士研究生导师。2001年7月于中国科学技术大学高分子科学与工程系获得学士学位;2001年9月—2006年6月,于中国科学技术大学高分子科学与工程系硕博连读,获得博士学位。现主要从事传统手工纸、考古材料方面的研究,发表文章100多篇。
谭静,2017年7月于西北民族大学文物保护技术专业获得学士学位;2017年09月至今,中国科学技术大学科技史与科技考古系硕博连读在读研究生,研究方向为科技考古与文化遗产保护,发表核心文章数篇。
丁延伟, 1999年7月,曲阜师范大学化学系获得学士学位;2002年7月,中国科学技术大学化学物理系获得硕士学位;2009年07月,中国科学技术大学化学物理系获得博士学位。现为中国科学技术大学合肥微尺度物质科学国家研究中心教授级高级工程师、理化科学实验中心副主任、质量负责人、热分析与吸附机组负责人。自2002年开始从事热分析与吸附技术的分析测试、实验方法研究等工作,并担任中国化学会化学热力学与热分析专业委员会委员、全国教育装备标准化委员会化学分委会委员、中国分析测试协会青年学术委员会委员。承担国家自然科学基金青年基金、中国科学院仪器功能开发项目、安徽省教学研究项目等多个重大项目,以主要作者发表SCI论文30余篇,获授权专利7项。出版《热分析实验方案设计与曲线解析概论》《热分析基础》《热分析与量热技术》等学术著作。
†共同第一作者

引用本文:

陈彪, 谭静, 付小航, 卢郁静, 朱玥玮, 黄晶, 狄雨萌, 丁延伟. 竹纸老化的热解特性及其老化程度的量化评价[J]. 材料导报, 2022, 36(13): 21040180-5.
CHEN Biao, TAN Jing, FU Xiaohang, LU Yujing, ZHU Yuewei, HUANG Jing, DI Yumeng, DING Yanwei. Study on Pyrolysis Characteristics of Bamboo Paper After Aging and Quantitative Evaluation of Its Aging Degree. Materials Reports, 2022, 36(13): 21040180-5.

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http://www.mater-rep.com/CN/10.11896/cldb.21040180 或 http://www.mater-rep.com/CN/Y2022/V36/I13/21040180

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