VO2(M)粉体合成与表征

doi:10.11896/cldb.21010087

材料导报

2022, Vol. 36

Issue (13): 21010087-5 https://doi.org/10.11896/cldb.21010087

无机非金属及其复合材料

VO₂(M)粉体合成与表征

张堃¹, 袁新强^1,2,*, 王丹¹, 梅晶¹, 蒋鹏^1,2, 张伟^1,2

1 陕西理工大学材料科学与工程学院,陕西汉中 723000
2 陕西理工大学矿渣综合利用环保技术国家地方联合工程实验室,陕西汉中 723000

Synthesis and Characterization of VO₂ (M) Powder

ZHANG Kun¹, YUAN Xinqiang^1,2,*, WANG Dan¹, MEI Jing¹, JIANG Peng^1,2, ZHANG Wei^1,2

1 School of Materials Science and Engineering, Shaanxi University of Technology,Hanzhong 723000, Shaanxi, China
2 National and Local Joint Engineering Laboratory for Slag Comprehensive Utilization and Environmental Technology, Shaanxi University of Technology,Hanzhong 723000, Shaanxi, China

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摘要 M相二氧化钒(VO₂(M))是一种具有太阳光选择性透过/反射的隔热材料,以填充方式与聚甲基丙烯酸甲酯(PMMA)结合可开发出智能隔热有机玻璃,因此,高质量VO₂(M)粉体的合成尤为重要。本工作以五氧化二钒(V₂O₅)为钒源,采用水热氧化还原法制备VO₂(M)粉体,通过X射线衍射仪(XRD)、场发射电子扫描电镜(FESEM)、紫外-可见-近红外分光光度计分析退火前后二氧化钒(VO₂)的晶型结构、结晶形态、太阳光(200~2 500 nm)透光率/反射率及其变化情况,通过差示扫描量热仪(DSC)分析退火后VO₂相变温度及其变化情况。研究表明,在185 ℃水热反应48 h、800 ℃氩气保护退火6 h合成出晶型完整、大小均匀的规则球状VO₂(M)粉体,其相变温度最低(66.02 ℃)。

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	张堃
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	张伟

关键词: VO₂(M) 水热合成智能隔热窗有机玻璃

Abstract: Mphase vanadium dioxide(VO₂(M)) is a kind of thermal insulation material with selective sunlight transmission and reflection. Intelligent thermal insulation plexiglass can be developed by combining polymethyl methacrylate (PMMA) and VO₂(M) powder with filling mode. It is particularly important to synthesize high quality VO₂(M) powder. In this work, VO₂(M) powder was prepared by hydrothermal redox process using vanadium pentoxide (V₂O₅) as vanadium source. The crystal structure, crystal morphology, solar transmittance and reflectance from 200 nm to 2 500 nm and their changes of vanadium dioxide(VO₂) before and after annealing were analyzed by X-ray diffractometer(XRD), field emission scanning electron microscopy (FESEM) and ultraviolet-visible-near infrared spectrophotometer respectively. The phase transition temperature and its change of VO₂(M) after annealing were analyzed by differential scanning calorimetry(DSC). It was found that regular spherical VO₂(M) powder with complete crystal shape and uniform size was synthesized by hydrothermal reaction at 185 ℃ for 48 h and argon protective annealing at 800 ℃ for 6 h. The corresponding synthetic VO₂(M) has the lowest phase transition temperature (66.02 ℃).

Key words: VO₂ (M) hydrothermal synthesis intelligent insulation window plexiglass

出版日期: 2022-07-10 发布日期: 2022-07-12

ZTFLH:

TB34

基金资助: 矿渣综合利用环保技术国家地方联合工程实验室开放课题(SLGPT2019KF01-06);陕西理工大学基金项目(SLG1810)

通讯作者: * yxq_hb@126.com

作者简介: 张堃,2018年6月毕业于陕西理工大学,获得工学学士学位。2018年9月至今在陕西理工大学攻读硕士学位,主要从事VO₂(M)粉体制备及其在聚甲基丙烯酸甲酯中应用的研究。
袁新强,副教授,2007年7月毕业于西华大学,获得工学硕士学位,于2007年7月到陕西理工大学任教,主要从事高性能丙烯酸树脂开发及复合材料、功能材料应用研究。在国内外重要期刊发表文章20余篇,授权国家发明专利近20项,申请美国发明专利2项,专利转让4项。

引用本文:

张堃, 袁新强, 王丹, 梅晶, 蒋鹏, 张伟. VO₂(M)粉体合成与表征[J]. 材料导报, 2022, 36(13): 21010087-5.
ZHANG Kun, YUAN Xinqiang, WANG Dan, MEI Jing, JIANG Peng, ZHANG Wei. Synthesis and Characterization of VO₂ (M) Powder. Materials Reports, 2022, 36(13): 21010087-5.

链接本文:

http://www.mater-rep.com/CN/10.11896/cldb.21010087 或 http://www.mater-rep.com/CN/Y2022/V36/I13/21010087

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