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材料导报  2022, Vol. 36 Issue (16): 20100089-9    https://doi.org/10.11896/cldb.20100089
  无机非金属及其复合材料 |
工业副产铁矾渣资源化利用研究进展
刘明坤1,2, 孙振华2, 李少鹏2,*, 王启宝1,*, 王栋民1, 李会泉2
1 中国矿业大学(北京)化学与环境工程学院,北京 100083
2 中国科学院过程工程研究所战略金属资源绿色循环利用国家工程研究中心,绿色过程与工程重点实验室,北京 100190
Research Progress in Resource Utilization of Industrial Output Jarosite Residues
LIU Mingkun1,2, SUN Zhenhua2, LI Shaopeng2,*, WANG Qibao1,*, WANG Dongmin1, LI Huiquan2
1 School of Chemical and Environmental Engineering, China University of Mining and Technology(Beijing), Beijing 100083, China
2 CAS Key Laboratory of Green Process and Engineering, National Engineering Research Center of Green Recycling for Strategic Metal Resources, Institute of Process Engineering, Chinese Academy of Sciences,Beijing 100190, China
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摘要 铁矾渣是湿法冶金工业利用黄铁矾法除铁产生的典型固体废弃物,因其组成复杂、附加值低且通常含少量重金属元素,无害化、规模化利用难度大,目前其处理方式以直接堆存和填埋为主。随着冶锌行业和锂电池回收等行业的迅速发展,铁矾渣产生量将大幅增长,其资源化利用技术和途径也将具有愈加重要的环保价值和经济价值。
   针对铁矾渣资源化、无害化利用技术的研究目前已取得一些有益成果,主要表现在三个方面。(1)利用湿法冶金、火法冶金、火法-湿法联用等方式可实现铁矾渣中Pb、Cu、Cd、Ni、Zn和Ag等有价金属元素的回收,其中部分金属元素的回收率超过90%;(2)将铁矾渣用于水泥、烧结砖等建筑材料的生产,以及作为水泥掺合料应用到建造工程的施工中;(3)利用铁矾渣制备其他高附加值材料(如用于储能系统的电极材料等)。本文主要回顾和总结了针对铁矾渣的金属回收技术和资源化利用技术的国内外研究进展,并分析和探讨了可能存在的问题及今后的研究方向。
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刘明坤
孙振华
李少鹏
王启宝
王栋民
李会泉
关键词:  铁矾渣  金属回收  建筑材料  资源利用    
Abstract: Jarosite residues are a kind of typical solid waste generated in the process of iron removal in hydrometallurgical industry. Because of its complex composition, low value and containing some heavy metal elements, the large-scale and harmless utilization of jarosite residues is a quite challenging issue and the current prevailing disposal methods are direct storage and landfill. Since a large increase of the production of jarosite residues is nearly undoubted in the foreseeable future as the rapid development of zinc hydrometallurgy and lithium battery recycling, the specific and effective utilization of techniques will be of greater urgency and of more environmental and economic significance.
Till now the research of element extraction and utilization routes of jarosite residues has acquired some potentially promising achievements which mainly include three aspects as follows: Ⅰ.recovering valuable metal elements such as Pb, Cu, Cd, Ni, Zn and Ag from jarosite residues by means of hydrometallurgy, pyrometallurgy or their combination, with the recovery rates of some metal elements higher than 90%; Ⅱ.applying jarosite residues to the production of building materials such as cement and sintering brick, or even directly to civil construction to serve as additives of cement; Ⅲ.using jarosite residues to prepare other high-value materials exemplified by electrodes for energy storage systems. In this review, we intend to provide systematic retrospect and summary of worldwide academic and engineering efforts on developing techniques of element recycling and resource utilization of jarosite residues, as well as a prospective discussion on the existing problems and future trends of this field.
Key words:  jarosite residues    metal recycling    building material    resource utilization
出版日期:  2022-08-25      发布日期:  2022-08-29
ZTFLH:  TF803  
基金资助: 国家重点研发计划(2017YFC0703205;2018YFC1901803);中科院重点部署项目(ZDRW_CN_2020-1);中国科学院青年促进会项目以及中国科学院绿色制造创新研究院自主部署项目(IAGM-2019-A15)
通讯作者:  *shpli@ipe.ac.cn; wqb@cumtb.edu.cn   
作者简介:  刘明坤,2018年6月毕业于中国矿业大学(北京),获得工学学士学位。现为中国矿业大学(北京)化学与环境工程学院硕士研究生,在李少鹏副研究员的指导下进行研究。目前主要研究领域为硫酸盐固体废弃物资源化工艺及机理研究。李少鹏,博士,副研究员,硕士研究生导师。2010年毕业于华东理工大学资源与环境工程学院,获博士学位,同年进入中国科学院过程工程研究所开展博士后研究,2012年出站后留所工作。主要从事固体废弃物/危险废弃物资源化利用的基础研究、技术开发与工程化推进。主持/参与重点研发计划、863计划、科技支撑计划、自然科学基金、博士后基金、协同创新基金、中石化合作等项目20余项,发表论文30余篇,其中SCI收录论文20余篇,申请专利50余项,授权20余项。王启宝,博士,教授,博士研究生导师。1989年毕业于安庆师范学院化学系,获理学学士学位;1992年、1995年毕业于中国矿业大学(北京)研究生部矿物加工工程专业,分别获工学硕士、博士学位。主要研究方向为无机非金属材料、精细化学品化学、有机合成等,发表学术论文50余篇,其中10余篇次被SCI、EI、ISTP等收录。
引用本文:    
刘明坤, 孙振华, 李少鹏, 王启宝, 王栋民, 李会泉. 工业副产铁矾渣资源化利用研究进展[J]. 材料导报, 2022, 36(16): 20100089-9.
LIU Mingkun, SUN Zhenhua, LI Shaopeng, WANG Qibao, WANG Dongmin, LI Huiquan. Research Progress in Resource Utilization of Industrial Output Jarosite Residues. Materials Reports, 2022, 36(16): 20100089-9.
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http://www.mater-rep.com/CN/10.11896/cldb.20100089  或          http://www.mater-rep.com/CN/Y2022/V36/I16/20100089
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