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材料导报  2022, Vol. 36 Issue (1): 20090152-7    https://doi.org/10.11896/cldb.20090152
  金属与金属基复合材料 |
溶液pH和温度对X65管线钢焊缝非均匀腐蚀的影响
朱烨森1,2, 刘梁1, 徐云泽1, 王晓娜3, 刘刚1, 黄一1
1 大连理工大学船舶工程学院,辽宁 大连 116024
2 中国电建集团华东勘测设计研究院有限公司,杭州 311122
3 大连理工大学物理学院,辽宁 大连 116024
The Influence of Solution pH and Temperature on the Non-uniform Corrosion of X65 Pipeline Weldment
ZHU Yesen1,2, LIU Liang1, XU Yunze1, WANG Xiaona3, LIU Gang1, HUANG Yi1
1 School of Naval Architecture and Ocean Engineering, Dalian University of Technology, Dalian 116024, Liaoning, China
2 Power China Huadong Engineering Corporation Limited, Hangzhou 311122, China
3 School of Physic and Optoelectronic Engineering, Dalian University of Technology, Dalian 116024, Liaoning, China
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摘要 本工作利用阵列多环组腐蚀监测传感器对X65管线钢焊缝在不同溶液pH和温度的饱和二氧化碳溶液中的非均匀腐蚀行为进行了研究。实验结果表明,管线钢焊缝的360°全周向区域以及沿管长轴向区域的非均匀腐蚀情况可以被有效监测。结合电化学测试及腐蚀形貌表征发现,在溶液pH为5.85时,管线钢焊缝表面难以形成具有保护性的腐蚀产物膜,随着溶液温度升高,焊缝三个区域(母材区、热影响区和焊缝区)的二氧化碳腐蚀加剧,其中焊缝区腐蚀最为严重;在溶液pH为6.86时,随着溶液温度升高,焊缝三个区域的腐蚀速率由于保护性腐蚀产物膜的形成而降低。魏氏体和针状铁素体在焊缝区的富集,导致焊缝区的成膜时间滞后于母材区和热影响区。
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朱烨森
刘梁
徐云泽
王晓娜
刘刚
黄一
关键词:  阵列多环组腐蚀监测传感器  管线钢焊缝  二氧化碳腐蚀  非均匀腐蚀    
Abstract: In this work, the non-uninform corrosion behaviors of X65 pipeline weldments in the saturated CO2 solutions of different solution pH and temperature were studied using a multi-ring array corrosion monitoring sensor . The result shows that both the non-uniform corrosion of the pipeline weldment with the 360° full circumference and along the pipe-length axis could be effectively monitored. Combining the electrochemical test and corrosion morphology characterization, it can be seen that when the pH of the solution was 5.85, the protective corrosion product film was difficult to form on the surface, CO2 corrosion of all three welding areas (base metal, heat affected zone and welding metal) aggravated with the increase of temperature, and the corrosion of the welding metal was the most severe. When the pH of the solution was 6.86, the protective corrosion product layer would form on all three welding areas which could slow down the corrosion rate with the increase of temperature. Due to the enrichment of widmanstatten ferrite and acicular ferrite in the welding metal, the film formation time of the welding metal would lag behind the base metal and the heat affected zone.
Key words:  multi-ring array corrosion monitoring sensor    pipeline weldment    carbon dioxide corrosion    non-uniform corrosion
出版日期:  2022-01-13      发布日期:  2022-01-13
ZTFLH:  TG406  
基金资助: 中央高校基本科研业务费专项资金(DUT21RC(3)093);国家自然科学基金(52001055)
通讯作者:  xuyuze123@163.com   
作者简介:  朱烨森,大连理工大学船舶工程学院博士研究生,师从黄一教授。研究方向为船舶与海洋结构物的焊接结构腐蚀问题。
徐云泽,大连理工大学助理研究员,博士。2016—2018年澳大利亚迪肯大学联合培养博士,2019年毕业于大连理工大学船舶工程学院。研究方向为海洋结构物的局部腐蚀监测技术与损伤机理。
引用本文:    
朱烨森, 刘梁, 徐云泽, 王晓娜, 刘刚, 黄一. 溶液pH和温度对X65管线钢焊缝非均匀腐蚀的影响[J]. 材料导报, 2022, 36(1): 20090152-7.
ZHU Yesen, LIU Liang, XU Yunze, WANG Xiaona, LIU Gang, HUANG Yi. The Influence of Solution pH and Temperature on the Non-uniform Corrosion of X65 Pipeline Weldment. Materials Reports, 2022, 36(1): 20090152-7.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.20090152  或          http://www.mater-rep.com/CN/Y2022/V36/I1/20090152
[1] Liu F, Zhou G T, Wu S K, et al. Transactions of the China Welding Institution, 2019, 40(1),131(in Chinese).
刘方,周广涛,吴世凯,等. 焊接学报, 2019, 40(1), 131.
[2] Pessu F, Barker R, Neville A. Corrosion, 2015,71 (12),1452.
[3] Tanupabrungsun T, Brown B, Nesic S. In: NACE Corrosion Conference & Expo. Orlando, United States, 2013.
[4] Nazari M H, Allahkaram S R, Kermani M B. Materials and Design, 2010,31(7),3559.
[5] Sun J B, Zhang G A, Liu W, et al. Corrosion Science, 2012,57,131.
[6] Huang H, Tsai W, Lee J. Corrosion Science, 1994,36(6), 1027.
[7] Deen K M, Ahmad R, Khan I H, et al. Materials and Design, 2010,31(6), 3051.
[8] Barker R, Hu X, Neville A. Tribology International, 2013,68,17.
[9] Fan C, Mclaury B. In: SPE Eastern Regional Meeting. Columbus, Uni-ted States, 2011, pp. 187.
[10] Gan F, Wan Z, Li Y, et al. Measurement, 2015,63,137.
[11] Xu Y, Huang Y, Wang X, et al. Sensors and Actuators, B: Chemical, 2016,224,37.
[12] Huang Y, Xu Y, Li B, et al. Corrosion Engineering Science and Techno-logy, 2016,51(3),211.
[13] Zhu Y S, Xu Y Z, Li K T, et al. Measurement, 2019,138,8.
[14] Zhu Y S, Xu Y Z, Wang M Y, et al. Ocean Engineering, 2019,189,106351.
[15] Dugstad A. In: NACE-International Corrosion Conference Series. San Diego, United States, 1998.
[16] Nordsveen M, Nesic S, Nyborg R, et al. Corrosion, 2003,59,443.
[17] Singer M. Corrosion, 2003,73,1030.
[18] Zhu Y S, Xu Y Z, Song S D, et al. Materials and Corrosion, 2020,71,1386.
[19] Xu Y, Yang L, He L, et al. Corrosion Engineering Science and Technology, 2016,51(8),606.
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