沉淀强化高熵合金研究进展

doi:10.11896/cldb.20070199

材料导报

2022, Vol. 36

Issue (21): 20070199-7 https://doi.org/10.11896/cldb.20070199

金属与金属基复合材料

沉淀强化高熵合金研究进展

白曦¹, 方伟^1,2,*, 常若斌¹, 于浩洋¹, 闫皎辉¹, 殷福星^1,2,*

1 河北工业大学材料科学与工程学院,能源装备材料技术研究院,天津 300132
2 天津市材料层状复合与界面控制技术重点实验室,天津 300132

Precipitation-strengthening in High Entropy Alloys: a Review

BAI Xi¹, FANG Wei^1,2,*, CHANG Ruobin¹, YU Haoyang¹, YAN Jiaohui¹, YIN Fuxing^1,2,*

1 Key Research Institute for Energy Equipment Materials, School of Materials Science and Engineering, Hebei University of Technology, Tianjin 300132, China
2 Key Tianjin Key Laboratory of Materials Laminating Fabrication and Interface Control Technology, Tianjin 300132, China

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摘要高熵合金是一类由多种主要元素共同组成的新型金属材料,其具有独特的微观结构和可调性能,在国内外已获得广泛关注。沉淀强化被证明是提高高熵合金屈服强度的一种非常有效的手段,并且沉淀相和基体之间的共格界面对于实现强度和塑性的良好结合非常重要。合理控制沉淀相的类型、形状、大小和体积分数是提高合金强塑性的关键因素。研究证实,采用不同的轧制、退火和时效等热处理工艺可调控合金的基体微观组织、沉淀相特征。沉淀强化高熵合金虽然表现出优异的拉伸性能和热稳定性,但目前对其疲劳、蠕变和氧化行为及相关机理等尚不清晰。因此,应对材料进行综合评价以促进性能优越的高温器件的合理设计和制造。使用计算模拟的方式对沉淀相的元素分布、电子结构、成键状态等内在特性进行量化研究,对沉淀相的演化过程进行针对性的预测和控制,有助于合理设计合金成分体系。本文综述了沉淀强化高熵合金的相形成、力学性能、热稳定性和计算机建模等方面的研究进展,归纳总结了相关问题,对今后设计沉淀强化高熵合金具有一定的指导意义。

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	白曦
	方伟
	常若斌
	于浩洋
	闫皎辉
	殷福星

关键词: 高熵合金沉淀强化沉淀行为性能计算模拟

Abstract: High entropy alloys (HEAs), as multiple principal element alloys, represent a new field of metallurgy, which has attracted extensive attention due to their unique microstructure and properties. Precipitation strengthening has been proved to be a very effective method to improve the yield strength of HEAs. The coherent interface between the precipitates and the matrix is important in achieving a good combination of strength and ductility. Controlling the type, shape, size and volume fraction of the precipitates is the key factor to improve the strength and ductility of HEAs. It is proved that different heat treatment processes such as rolling, annealing and aging could regulate the matrix microstructure and characteristics of precipitates. Although precipitation-hardened high entropy alloys exhibit excellent tensile properties and thermal stability, their fatigue, creep, oxidation behaviors and related mechanisms are still unclear. Therefore, comprehensive evaluation of materials should be carried out to promote the rational design and manufacture of high-temperature devices with excellent performance. In order to predict and control the evolution process of the precipitates and design the alloy composition system reasonably, an in-depth and quantitative study on the intrinsic properties of the precipitates, such as element distribution, electronic structure and bonding state, is supposed to be carried out by means of calculation and simulation. This paper reviews the progress in phase formation, properties, thermal stability, calculation and simulation of precipitation-hardened HEAs, and summarizes the correlative problems, which is helpful and instructive to design precipitation-hardened HEAs in the future.

Key words: high entropy alloys precipitation strengthening precipitation behavior property calculation and simulation

出版日期: 2022-11-10 发布日期: 2022-11-03

ZTFLH:

TG139

基金资助: 国家自然科学基金(51701061);河北省自然科学基金(E2019202059)

通讯作者: * fangwei@hebut.edu.cn;yinfuxing@hebut.edu.cn

作者简介: 白曦,2018年6月毕业于沈阳航空航天大学,获得工学学士学位。现为河北工业大学硕士研究生,在殷福星教授的指导下进行研究,目前主要研究领域为沉淀强化型高熵合金。2019年以第一作者身份在Materials Science and Engineering: A发表研究论文1篇。
方伟,河北工业大学助理研究员、硕士研究生导师。2008年7月本科毕业于北京科技大学材料科学与工程学院,2014年1月毕业于北京科技大学新材料技术研究院并取得博士学位。主要从事高熵合金的研究工作。近年来,在金属材料领域发表论文30余篇,包括Scripta Materialia、Journal of Materials Science & Technology、Materials Characterization、Materials Science and Engineering: A、Journal of Alloys and Compounds、Powder Technology、Powder Metallurgy等。
殷福星,博士研究生导师,长江学者特聘教授,第六届中国侨界贡献(创新人才)奖获得者。1984年于河北工业大学金属材料专业获学士学位;1987年于河北工业大学金属材料专业获硕士学位;1996年于日本甲南大学应用化学专业获博士学位。在超高强度钢铁材料中利用纤维状细晶组织实现了材料韧性变化的逆温度效应,该工作发表在Science(2008)、同成果获得德国2009年度Gottfried Wagener Prize一等奖。在开发新型高阻尼合金和应用技术等领域发表学术论文30篇;获得和在申请的日本基础专利共8项;研制成功了世界首创的Ti基高阻尼合金,成果发表在Advanced Materials。至今共发表论文200余篇,获得专利12项,参与编著书籍5册,主持多项国家级及省部级重点研发项目。主要研究方向:钢铁等金属结构材料的组织控制和评价技术;钛基高温阻尼合金的机理研究及开发;铁锰硅系形状记忆合金以及锰铜基阻尼合金的工程应用技术研究。

引用本文:

白曦, 方伟, 常若斌, 于浩洋, 闫皎辉, 殷福星. 沉淀强化高熵合金研究进展[J]. 材料导报, 2022, 36(21): 20070199-7.
BAI Xi, FANG Wei, CHANG Ruobin, YU Haoyang, YAN Jiaohui, YIN Fuxing. Precipitation-strengthening in High Entropy Alloys: a Review. Materials Reports, 2022, 36(21): 20070199-7.

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http://www.mater-rep.com/CN/10.11896/cldb.20070199 或 http://www.mater-rep.com/CN/Y2022/V36/I21/20070199

1 Yeh J W, Chen S K, Lin S J, et al. Advanced Engineering Materials, 2004, 6(5), 299.
2 Cantor B, Chang I T H, Knight P, et al. Materials Science and Enginee-ring: A, 2004, 375, 213.
3 Miracle D, Senkov O. Acta Materialia, 2017, 122, 448.
4 Senkov O N, Miller J D, Miracle D B, et al. Nature Communications, 2015, 6, 6529.
5 Gludovatz B, Hohenwarter A, Catoor D, et al. Science, 2014, 345(6201), 1153.
6 Jun D, Qin Y, Mark A, et al. Proceedings of the National Academy of Sciences of the United States of America, 2018, 115(36), 8919.
7 Li Z, Zhao S, Ritchie R O, et al. Progress in Materials Science, 2019, 102, 296.
8 Pickering E, Jones N G. International Materials Reviews, 2016, 61(3), 183.
9 Yeh J W. JOM, 2013, 65(12), 1759.
10 Zhang Y, Zuo T T, Tang Z, et al. Progress in Materials Science, 2014, 61, 1.
11 Miracle D B. Nature Communications, 2019, 10(1), 721.
12 Luan H W, Zhao W, Yao K F. Transactions of Materials and Heat Treatment, 2020, 41(1), 1 (in Chinese).
栾亨伟, 赵威, 姚可夫.材料热处理学报, 2020, 41(1), 1.
13 Cantor B. In:Encyclopedia of materials: science and technology, Buschow K H J, Cahn R W, Flemings M C, et al, ed., Elsevier, Netherlands, 2001, pp. 1.
14 He F, Wang Z, Wu Q, et al. Scripta Materialia, 2017, 131, 42.
15 Gludovatz B, Hohenwarter A, Thurston K V S, et al. Nature Communications, 2016, 7, 10602.
16 Laplanche G, Kostka A, Reinhart C, et al. Acta Materialia, 2017, 128, 292.
17 Ma Y, Yuan F, Yang M, et al. Acta Materialia, 2018, 148, 407.
18 Komarasamy M, Shukla S, Ley N, et al. Materials Science and Enginee-ring: A, 2018, 736, 383.
19 Sun S J, Tian Y Z, An X H, et al. Materials Today Nano, 2018, 4, 46.
20 Sun S J, Tian Y Z, Lin H R, et al. Materials & Design, 2017, 133, 122.
21 Sohn S S, Alisson K D S, Ikeda Y, et al. Advanced Materials, 2019, 31(8), 1807142.
22 Yang T, Zhao Y L, Liu W H, et al. Materials Research Letters, 2018, 6(10), 600.
23 He F, Chen D, Han B, et al. Acta Materialia, 2019, 167, 275.
24 Gwalani B, Gorsse S, Choudhuri D, et al. Acta Materialia, 2018, 153, 169.
25 He J Y, Wang H, Huang H L, et al. Acta Materialia, 2016, 102, 187.
26 Zhao Y L, Yang T, Tong Y, et al. Acta Materialia, 2017, 138, 72.
27 Yang T, Zhao Y L, Tong Y, et al. Science, 2018, 362(6417), 933.
28 Zhao Y Y, Chen H W, Lu Z P, et al. Acta Materialia, 2018, 147, 184.
29 Tong Y, Chen D, Han B, et al. Acta Materialia, 2019, 165, 228.
30 Su J, Raabe D, Li Z. Acta Materialia, 2019, 163, 40.
31 Joseph J, Stanford N, Hodgson P, et al. Journal of Alloys and Compounds, 2017, 726, 885.
32 Qin G, Chen R, Zheng H, et al. Journal of Materials Science & Technology, 2019, 35(4), 578.
33 Liang Y J, Wang L J, Wen Y R, et al. Nature Communications, 2018, 9(1), 299.
34 Zhang Y, Zuo T T, Tang Z, et al. Progress in Materials Science, 2014, 61, 1.
35 Wang Q, Ma Y, Jiang B, et al. Scripta Materialia, 2016, 120, 85.
36 Strutt P R, Polvani R S, Ingram J C. Metallurgical Transactions A, 1976, 7A, 23.
37 He J Y, Wang H, Wu Y, et al. Intermetallics, 2016, 79, 41.
38 Bai X, Fang W, Chang R B, et al. Materials Science and Engineering: A, 2019, 767, 138403.
39 Sundararaman M, Mukhopadhyay P, Banerjee S. Acta Metallurgica, 1988, 36(4), 847.
40 He F, Wang Z J, Wang J, et al. Scripta Materialia, 2018, 146, 281.
41 Du X H, Li W P, Chang H T, et al. Nature Communications, 2020, 11(1), 2390.
42 Liu W H, Lu Z P, He J Y, et al. Acta Materialia, 2016, 116, 332.
43 Fan J T, Zhang L J, Yu P F, et al. Materials Science and Engineering: A, 2018, 728, 30.
44 Ming K S, Bi X F, Wang J. International Journal of Plasticity, 2018, 100, 177.
45 Yang T, Zhao Y L, Fan L, et al. Acta Materialia, 2020, 189, 47.
46 Lifshitz I M, Slyozov V V. Journal of Physics and Chemistry of Solids, 1961, 19(1-2), 35.
47 Wagner C Z, Elektrochem Z. Angewandte Physics and Chemistry, 1961, 65, 581.
48 Zhao Y L, Yang T, Han B, et al. Materials Research Letters, 2019, 7(4), 152.
49 He F, Zhang K W, Yeli G M, et al. Scripta Materialia, 2020, 183, 111.
50 Guo L, Gu J, Gong X, et al. Science China Materials, 2020, 63(2), 288.
51 Detrois M, Jablonski P D, Antonov S, et al. Journal of Alloys and Compounds, 2019, 792, 550.
52 Liu C T. International Materials Reviews, 1984, 29(1), 168.
53 Booth-Morrison C, Mao Z, Noebe R D, et al. Applied Physics Letters, 2008, 93(3), 033103.
54 Tu Y, Mao Z, Seidman D N. Applied Physics Letters, 2012, 101(12), 121910.
55 Xu J H, Lin W, Freeman A J. Physical Review B, 1993, 48(7), 4276.
56 Kresse G, Hafner J. Physical Review B, 1993, 47(1), 558.
57 Cao Y, Zhu J, Liu Y, et al. Physica B: Physics of Condensed Matter, 2013, 412, 45.
58 Han B, Wei J, Tong Y, et al. Scripta Materialia, 2018, 48, 42.
59 Niu M, Zhou G, Wang W, et al. Acta Materialia, 2019, 179, 296.
60 Huang S. Scripta Materialia, 2019, 168, 5.
61 Kim S G, Kim W T. Physical Review: E, 1999, 60(6), 7186.
62 Kim S G, Kim W T, Suzuki T, et al. Journal of Crystal Growth, 2004, 261(1), 135.
63 Song J, Field R, Clarke A, et al. Acta Materialia, 2019, 165, 362.

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