Research Progress on the Recovery and Reuse of Rhenium in Industrial Waste
ZHANG Chunwei1,2, SUN Yuan2, TANG Junjie2,3, FANG Dawei1
1 College of Chemistry, Liaoning University, Shenyang 110036, China 2 Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China 3 College of Biomedical and Chemical Engineering, Liaoning Institute of Science and Technology, Benxi 117004, China
Abstract: Metal rhenium has the physical properties of high hardness, high mechanical strength, good plasticity and good mechanical stability as well as excellent catalytic activity and corrosion resistance chemical properties,so it has important application value and broad application prospect in the fields of superalloy and petrochemical industry. However, reserves of rhenium in nature are very small, and the abundance of rhenium in the crust is about 6.57×10-10.Rhenium resources are relatively scarce in China, and there are no rhenium deposits available for industrial exploitation. Most of these rhenium exist in the form of associated minerals, mostly distribute in molybdenite and copper-rhenium sulfide. Currently, the proved rhenium ore reserves are only about 237 tons. With the rapid development of aerospace and petrochemical fields, the demand for rhenium resources is increasing.About 80% of rhenium in China is used in the field of superalloys, mainly used to make turbine engine blades of aerospace and aviation, and 20% of rhenium is used as catalysts for catalytic cracking reforming of petroleum.The alloy waste produced in the manufacturing process accounts for about 70% of the an-nual output.Domestic enterprises paid little attention to the recovery of rhenium secondary resources, and the recovery technology was relatively weak, which led to serious resource waste.The global resource recovery and reuse industry is developing rapidly. Western developed countries attach great importance to the recovery and reuse of rhenium secondary resources.The United States and Germany are the major countries for the recovery of rhenium resources, and the recovery amount of rhenium in superalloy in the United States reached 6 tons in 2014.The reuse of rhe-nium will aggravate the deterioration of energy and resources, so it is of great significance to study the recycling process of rhenium resources in a scientific, economic and environmental way to alleviate the problem of energy shortage in China. There are mainly two kinds of rhenium wastes produced in industry: one is the rhenium-containing smoke, waste catalysts,superalloys and other solid waste, which can be recovered mainly by means of oxidative acid leaching, high-temperature alkali melting, electrolytic dissolution, etc, and then enriched rhenium through treatment.The second is the rhenium waste liquid produced by smelting concentrate, etc. The recovery methods mainly include ion exchange extraction, activated carbon adsorption, biological adsorption and other recovery processes. The key problem is how to improve the recovery rate of rhenium, reduce the cost and no pollution to the environment.Since rhenium and molybdenum are similar in nature, the biggest challenge for China is how to effectively separate rhenium and molybdenum and extract them in a more efficient, economical and environmentally friendly way to achieve industrialization. Based on the specific situation of rhenium resources in industrial wastes, this paper summarizes the research progress on the recovery and reuse of rhenium secondary resources, and separately summarizes and introduces the recovery methods of rhenium in rhenium solid waste and rhenium waste liquid.Different process of rhenium secondary resources recovery characteristics and the problems are analyzed, the technology for the future development direction is forecasted, in order to realize the maximum recovery and reuse efficiency of rhenium resources and alleviate the current situation of rhenium metal material supply shortage in China.
张春伟, 孙元, 唐俊杰, 房大维. 工业废料中铼元素的回收与再利用研究进展[J]. 材料导报, 2020, 34(15): 15145-15152.
ZHANG Chunwei, SUN Yuan, TANG Junjie, FANG Dawei. Research Progress on the Recovery and Reuse of Rhenium in Industrial Waste. Materials Reports, 2020, 34(15): 15145-15152.
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2020, Vol. 34 
