Microelectrode Array Technology Used for Investigating the Corrosion of Alloys
BU Hongmei1, LI Xiaowei2, QI Jiantao3, LI Yan1
1 College of Materials Science and Engineering, China University of Petroleum (East China), Qingdao 266580 2 China Petroleum Engineering Construction Corp., Beijing Company, Beijing 100000 3 College of Chemical Engineering, China University of Petroleum (East China), Qingdao 266580
Abstract: With the booming development and improvement of the industries, the employment of alloy materials also increases. However, the corrosion problem of alloy materials has caused incalculable losses to industrial production and ecological environment. In order to reduce the da-mage and impact of various aspects caused by alloy corrosion, domestic and foreign scholars have carried out a large number of researches on alloy corrosion mechanism and protection, and some research progress has been made. Microelectrode array technology is a new type of electrochemical test method between macroscopic classical electrochemical technology and micro-area scanning probe technology. It can not only obtain the overall average information of the large-area electrode of the alloy, but also detect the characteristics of potential and current distribution in the local micro-area of the alloy. Compared with the macroscopic classical electrochemical technology, it can more accurately test the heterogeneous electrochemical information in the local corrosion process of the alloy. The optimization of such microelectrode arrays has been realized with the continuous research and development of scholars at home and abroad. By the combination of other electrochemical testing techniques and surface science and technology methods, the physical, chemical and electrochemical information of the alloy/corrosion solution interface has been enriched. In recent years, a great deal of experts and scholars have used this microelectrode array technology combined with other testing techniques to study the local corrosion process and mechanism of common alloys under diffe-rent environments and corrosion conditions, and achieved important research progress. The research on the galvanic corrosion behavior and evolution law of different material metals has made a major breakthrough. In addition, the development and application of real-time coupled multi-electrode array sensor (CMAS) probes play an important role in online monitoring/detection of local corrosion of alloys. In this paper, we reviewed the progress of microelectrode array technology in the study of galvanic corrosion, surface coating failure and the influence of corrosion environment on alloy. Then we summarized the merits and demerits of microelectrode array technology in characterizing the local electrochemical heterogeneity of the alloy and the future trend was prospected.
作者简介: 卜红梅,2017年6月毕业于中国石油大学(华东),获得工学学士学位。现为中国石油大学(华东)材料科学与工程学院硕士研究生,在李焰教授和齐建涛副教授的联合指导下进行研究。目前主要研究领域为镁合金表面功能性转化膜材料的多尺度表征及可控制备。 齐建涛,中国石油大学(华东)化学工程学院副教授,硕士研究生导师。山东省暨青岛市腐蚀与防护学会理事。2011年6月本科毕业于中国石油大学(华东)化学工程学院,2015年9月在英国曼彻斯特大学腐蚀与防护专业取得博士学位,2015—2018年分别在英国曼彻斯特大学(LATEST2项目,合作导师Prof. George Thompson院士)和法国国家科学研究中心(NEPAL FUI项目,合作导师Prof. Philippe Marcus)进行博士后研究工作。主要从事金属材料的表面改性、纳米材料光谱分析及耐蚀性能评估等方面的研究工作。近年来,在腐蚀与防护研究领域发表论文10余篇,包括Mater. Let.、Electrochem. Commun.、Electrochim. Acta、J. Electrochem. Soc.、Appl. Surf. Sci.、Thin Solid Films.和Surf. Coat. Technol等SCI学术期刊。
引用本文:
卜红梅, 李肖蔚, 齐建涛, 李焰. 利用微电极阵列技术研究合金的腐蚀[J]. 材料导报, 2019, 33(23): 3963-3970.
BU Hongmei, LI Xiaowei, QI Jiantao, LI Yan. Microelectrode Array Technology Used for Investigating the Corrosion of Alloys. Materials Reports, 2019, 33(23): 3963-3970.
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2019, Vol. 33 
