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材料导报  2025, Vol. 39 Issue (10): 24040169-9    https://doi.org/10.11896/cldb.24040169
  无机非金属及其复合材料 |
硫族半导体催化剂用于高效光催化CO2还原的研究进展
于慧敏, 郭少红*, 贾美林, 贾晶春, 常迎
内蒙古师范大学化学与环境科学学院,呼和浩特 010000
Progress on Efficient Photocatalytic Reduction of CO2 Using Sulfide Semiconductor Catalysts
YU Huimin, GUO Shaohong*, JIA Meilin, JIA Jingchun, CHANG Ying
College of Chemistry and Environmental Science, Inner Mongolia Normal University, Hohhot 010000, China
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摘要 化石燃料的持续消耗和二氧化碳的过量排放造成严重的能源危机和环境问题。因此,开发清洁能源是缓解以上两个问题的重要方法之一。光催化CO2还原是以清洁的太阳光为能量来源,在催化剂的作用下将温室气体CO2高效还原为CO、CH4和CH3OH等高附加值的化学产品,因此,这是一种可持续碳循环的“绿色”技术。硫族半导体材料具有合适的带隙和宽的光响应范围的优势,本文从硫族半导体的简介和分类、光催化CO2还原机理以及提高半导体催化活性的方法三个方面展开论述,总结了硫化物半导体催化剂近几年在光催化还原CO2中取得的研究进展。本综述将为解决金属硫化物在光催化CO2还原中的相关挑战以及未来开发新型优异性能的复合材料提供研究思路和想法。
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于慧敏
郭少红
贾美林
贾晶春
常迎
关键词:  二氧化碳还原  光催化  硫族半导体  清洁能源    
Abstract: The continuous consumption of fossil fuels and excessive emission of carbon dioxide have caused severe energy crises and environmental problems. Therefore, the development of clean energy is one of the important methods to alleviate these two issues. Using clean solar energy as a source, photocatalytic CO2 reduction efficiently converts greenhouse gas CO2 into high-value chemical products such as CO, CH4, and CH3OH under the action of catalysts. Thus, sulfide semiconductor materials are a sustainable “green” technology for carbon cycling due to their suitable band gaps and wide range of light response. This review discusses sulfide semiconductors in terms of introduction and classification, photocatalytic CO2 reduction mechanism, and methods for improving catalytic activity of semiconductors on recent advancements made by sulfide semiconductor catalysts. This review will provide research ideas for addressing challenges related to metal sulfides in photocatalytic CO2 reduction and the future development of novel composite materials with excellent performance.
Key words:  CO2 reduction    photocatalysis    sulfide semiconductor    clean energy
出版日期:  2025-05-25      发布日期:  2025-05-13
ZTFLH:  X701  
  O643.36  
基金资助: 内蒙古自然科学基金(2021BS02019);内蒙古师范大学基本科研业务费专项资金资助(2023JBQN045)
通讯作者:  *郭少红,讲师、博士。长期从事功能材料制备及光催化性能研究。20200043@imnu.edu.cn   
作者简介:  于慧敏,内蒙古师范大学硕士研究生。在贾美林教授和郭少红老师的指导下进行研究,目前主要从事光催化CO2还原性能的研究。
引用本文:    
于慧敏, 郭少红, 贾美林, 贾晶春, 常迎. 硫族半导体催化剂用于高效光催化CO2还原的研究进展[J]. 材料导报, 2025, 39(10): 24040169-9.
YU Huimin, GUO Shaohong, JIA Meilin, JIA Jingchun, CHANG Ying. Progress on Efficient Photocatalytic Reduction of CO2 Using Sulfide Semiconductor Catalysts. Materials Reports, 2025, 39(10): 24040169-9.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.24040169  或          https://www.mater-rep.com/CN/Y2025/V39/I10/24040169
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