固体氧化物电池金属连接体锰钴涂层材料研究进展

doi:10.11896/cldb.23100253

材料导报

2025, Vol. 39

Issue (8): 23100253-6 https://doi.org/10.11896/cldb.23100253

无机非金属及其复合材料

固体氧化物电池金属连接体锰钴涂层材料研究进展

韩帅文^1,2, 朱可晟¹, 刘长洋^1,2, 刘子良^1,2, 卞刘振^1,2, 杨礼林^1,*

1 内蒙古科技大学材料与冶金学院,内蒙古包头 014010
2 内蒙古自治区先进陶瓷材料与器件重点实验室,内蒙古包头 014010

Research Progress of Manganese-Cobalt Coating Materials on Metal Interconnects of Solid Oxide Fuel Cells

HAN Shuaiwen^1,2, ZHU Kesheng¹, LIU Changyang^1,2, LIU Ziliang^1,2, BIAN Liuzhen^1,2, YANG Lilin^1,*

1 School of Materials and Metallurgy, Inner Mongolia University of Science and Technology, Baotou 014010, Inner Mongolia, China
2 Inner Mongolia Key Laboratory of Advanced Ceramic Materials and Devices, Baotou 014010, Inner Mongolia, China

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摘要金属连接体作为固体氧化物电池(Solid oxide cells,SOCs)的核心组件,在工作温度范围内会发生严重的氧化和高价铬挥发导致阴极Cr中毒,从而降低电池性能与寿命。在金属连接体表面添加锰钴尖晶石涂层是防止其失效的有效手段,但是锰钴涂层存在电导率低、烧结致密度差的问题。本文综述了近年来SOCs金属连接体防护用锰钴涂层的制备方法、成分设计对电导率、热膨胀系数、抗氧化性能等的影响。稀土元素与过渡金属元素的共同掺杂可以协同调控锰钴尖晶石涂层的电导率和抗氧化性能。此外,对锰钴涂层的设计、制备技术和性能改进提出了未来发展方向。

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	韩帅文
	朱可晟
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	卞刘振
	杨礼林

关键词: 固体氧化物电池(SOCs) 金属连接体铁素体不锈钢锰钴尖晶石涂层掺杂

Abstract: As the key component of solid oxide cells (SOCs), the metallic interconnector experiences serious oxidation and high-valence chromium vo-latilization, resulting in the Cr poisoning on the cathode and degradation of cell performance. Manganese cobalt spinel coating on the surfaces of metal interconnectors is an effective strategy to prevent their failure;however, these coatings also have problems, such as relatively low conductivity and poor sintering density. This article reviews the effect of preparation methods and composition design of manganese cobalt coa-tings on the conductivity, thermal expansion coefficient, and oxidation resistance of SOCs metal interconnectors in recent years. The results indicate that the co-doping of rare earth and transition metal elements can synergistically regulate the conductivity and oxidation resistance of manganese cobalt spinel coatings. Finally, we provide future development directions for the design, preparation technology, and performance improvement of manganese cobalt coatings.

Key words: solid oxide cells(SOCs) metal interconnector ferritic stainless steel Mn-Co spinel coating doping

出版日期: 2025-04-25 发布日期: 2025-04-18

ZTFLH:

TG174.44

基金资助: 国家自然科学基金(52202257);内蒙古自治区科技攻关计划(2020GG0155);内蒙古自治区科技创新引导奖励资金项目(0902062001);内蒙古科技大学创新基金(2019QDL-B05)

通讯作者: 杨礼林,博士,内蒙古科技大学材料与冶金学院讲师、硕士研究生导师。目前主要从事新能源相关的金属材料组织与性能调控等方面的研究。yangwillin@163.com

作者简介: 韩帅文,内蒙古科技大学材料与冶金学院硕士研究生,在杨礼林老师的指导下进行研究。目前主要研究领域为新能源相关金属涂层材料。

引用本文:

韩帅文, 朱可晟, 刘长洋, 刘子良, 卞刘振, 杨礼林. 固体氧化物电池金属连接体锰钴涂层材料研究进展[J]. 材料导报, 2025, 39(8): 23100253-6.
HAN Shuaiwen, ZHU Kesheng, LIU Changyang, LIU Ziliang, BIAN Liuzhen, YANG Lilin. Research Progress of Manganese-Cobalt Coating Materials on Metal Interconnects of Solid Oxide Fuel Cells. Materials Reports, 2025, 39(8): 23100253-6.

链接本文:

https://www.mater-rep.com/CN/10.11896/cldb.23100253 或 https://www.mater-rep.com/CN/Y2025/V39/I8/23100253

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