含Al耐热合金高温氧化行为研究现状

doi:10.11896/cldb.24050040

材料导报

2025, Vol. 39

Issue (6): 24050040-10 https://doi.org/10.11896/cldb.24050040

金属与金属基复合材料

含Al耐热合金高温氧化行为研究现状

姚通睿¹, 王曼¹, 席晓丽^1,2,*

1 北京工业大学材料循环低碳再生全国重点实验室,北京 100124
2 北京工业大学材料科学与工程学院,首都资源循环材料技术省部共建协同创新中心,北京 100124

Research Status of High-temperature Oxidation Behavior of Al-containing Heat-resistant Alloys

YAO Tongrui¹, WANG Man¹, XI Xiaoli^1,2,*

1 State Key Laboratory of Materials Low-Carbon Recycling, Beijing University of Technology, Beijing 100124, China
2 Collaborative Innovation Center of Capital Resource-Recycling Material Technology, College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China

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摘要耐热合金因其优异的抗氧化性能在高温领域具有重要的应用,其中镍基和铁基耐热合金的应用更为广泛。随着“双碳”战略目标的提出,航空航天及能源技术不断发展使耐热合金的服役环境更加苛刻,这对耐热合金服役性能提出了更大挑战,因此亟需开发具有更优异高温抗氧化性能的新型耐热合金。合金化元素Al所形成的Al₂O₃膜具有较低生长速率、较高致密性及优异的热稳定性,因此含Al耐热合金成为近年来的研究热点。本文通过系统梳理相关研究成果,比较了3种抗氧化元素所形成保护性氧化膜的优劣,回顾了含Al耐热合金的发展历程,归纳了影响含Al镍基和铁基合金氧化行为的关键因素,总结分析了其高温氧化的微观机制并归纳了共性规律。最后,对含Al耐热合金现阶段存在的问题及未来发展方向进行了展望。

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关键词: 含Al耐热合金高温抗氧化保护性氧化膜成分设计显微组织

Abstract: Heat-resistant alloys have important applicationsin high-temperature servicing environment due to their excellent oxidation resistance, among which nickel-based and iron-based heat-resistant alloys are more widely used. With the proposal of “dual carbon” strategic target, the continuously developed aerospace and energy technologies make the servicing environment harsher, which puts forward a greater challenge to heat-resistant alloys. Therefore, it is urgent to develop new types of heat-resistant alloys with superior high-temperature oxidation resistance. Protective Al₂O₃ film formed through addition of Al exhibits characteristics of low growth rate, high densification and excellent thermal stability, making Al-containing heat-resistant alloys apopular research topic recently. In this summary,the advantages and disadvantages of three kinds of protective oxide films were compared. Then, the development of Al-containing heat-resistant alloys was reviewed. Moreover, the key factors affecting the oxidation behavior of Al-containing nickel-based and iron-based alloys were analyzed, and the microscopic oxidation mechanism and common laws of the these alloys under high temperature were extracted. Finally, the problems existing at the present stage and the future development direction of Al-containing heat-resistant alloys were prospected.

Key words: Al-containing heat-resistant alloy high temperature oxidation resistance protective oxide film composition design microstructure

出版日期: 2025-03-25 发布日期: 2025-03-24

ZTFLH:

TG14

基金资助: 国家重点研发计划(2023YFB3811800);国家自然科学基金-国家杰出青年科学基金(52025042)

通讯作者: *席晓丽,北京工业大学材料科学与工程学院教授、博士研究生导师。国家杰出青年科学基金、国家自然科学基金优秀青年科学基金获得者。主要从事稀缺金属材料高效循环再造、难熔金属材料与环境电化学、冶金过程仿真模拟等科研工作。xixiaoli@bjut.edu.cn

作者简介: 姚通睿,北京工业大学材料科学与工程学院硕士研究生,在席晓丽教授的指导下进行研究。目前主要从事含Al耐热合金成分设计、制备及氧化行为研究。

引用本文:

姚通睿, 王曼, 席晓丽. 含Al耐热合金高温氧化行为研究现状[J]. 材料导报, 2025, 39(6): 24050040-10.
YAO Tongrui, WANG Man, XI Xiaoli. Research Status of High-temperature Oxidation Behavior of Al-containing Heat-resistant Alloys. Materials Reports, 2025, 39(6): 24050040-10.

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https://www.mater-rep.com/CN/10.11896/cldb.24050040 或 https://www.mater-rep.com/CN/Y2025/V39/I6/24050040

1 Li D H, Wang K, Zhu X Y, et al. Materials and Corrosion-Werkstoffe Und Korrosion, 2022, 73(11), 1865.
2 Teng J W, Gong X J, Yang B B, et al. Corrosion Science, 2022, 198, 110141.
3 Ren J, Yu L M, Liu C X, et al. Corrosion Science, 2022, 195, 110008.
4 Wang M. Study on microstructure stability and mechanical properties of new austenitic steel. Ph. D. Thesis, Beijing University of Science and Technology, China, 2017 (in Chinese).
王曼. 新型奥氏体钢显微组织结构稳定性及力学性能的研究. 博士学位论文, 北京科技大学, 2017.
5 Sui X M, Hu J, Zhang L, et al. Surface Technology, 2020, 49(10), 18 (in Chinese).
隋欣梦, 胡记, 张林, 等. 表面技术, 2020, 49(10), 18.
6 Tang S F, Yang J, Tang P J, et al. Materials Engineering, 2023, 51(3), 12 (in chinese).
汤素芳, 杨嘉, 唐鹏举, 等. 材料工程, 2023, 51(3), 12.
7 Suryanarayana C, Al-Aqeeli N. Progress in Materials Science, 2013, 58(4), 383.
8 Li M S, Qian Y H, Xin L. Corrosion Science and Protection Technology, 1999, 11(5), 284 (in chinese).
李美栓, 钱余海, 辛丽. 腐蚀科学与防护技术, 1999, 11(5), 284.
9 Birks N, Meier G H, Pettit F S. Introduction to the high temperature oxidation of metals, Cambridge University Press, UK, 2006, pp. 134.
10 Ahmad B, Fox P. Oxidation of Metals, 1999, 52(1-2), 113.
11 Nguyen T D, Zhang J Q, Young D J. Corrosion Science, 2020, 170(1), 108702.
12 Ma S Y. The effect of alloying elements cr, al, and si on the oxidation resistance of nickel based high-temperature alloys. Master's Thesis, Zhejiang University, China, 2023 (in Chinese).
马苏钰. 合金元素Cr、Al和Si对镍基高温合金抗氧化性的影响. 硕士学位论文, 浙江大学, 2023.
13 Li X L, Chen B, Xing W W, et al. Journal of Materials Research, 2018, 32(12), 9 (in Chinese).
李小亮, 陈波, 邢炜伟, 等. 材料研究学报, 2018, 32(12), 9.
14 Yamamoto Y, Brady M P, Lu Z P, et al. Science, 2007, 316(5823), 433.
15 Berthod P. Oxidation of Metals, 2005, 64(3), 235.
16 Airiskallio E, Nurmi E, Heinonen M, et al. Corrosion Science, 2010, 52(10), 3394.
17 Niu Y, Zhang X J, Wu Y, et al. Corrosion Science, 2006, 48(12), 4020.
18 Xu Q, Zhang X H, Han C J, et al. Solid Rocket Technology, 2002, 25(3), 5 (in chinese).
徐强, 张幸红, 韩杰才, 等. 固体火箭技术, 2002, 25(3), 5.
19 Giggins C S, Pettit F S. Journal of the Electrochemical Society, 1971, 118(11), 1782.
20 Wang Q Z. Steel, 1981(4), 75 (in chinese).
王庆珠. 钢铁, 1981(4), 75.
21 Xu Y L, Fu H, Fan L J, et al. Corrosion Science, 2019, 161, 108192.
22 Yan J J, Huang X F, Huang W G. International Journal of Minerals, Metallurgy and Materials, 2020, 27(9), 1244.
23 Zhang Y B, Zou D N, Li Y N, et al. Journal of Materials Research and Technology, 2021, 11, 1730.
24 Kvernes I, Oliveira M, Kofstad P. Corrosion Science, 1977, 17(3), 237.
25 Brady M P, Yamamoto Y, Santella M L, et al. Scripta Materialia, 2007, 57(12), 1117.
26 Brady M P, Unocic K A, Lance M J, et al. Oxidation of Metals, 2011, 75(5-6), 337.
27 Brady M P, Yamamoto Y, Santella M L, et al. Oxidation of Metals, 2009, 72(5-6), 311.
28 Stott F H, Wood G C, Stringer J. Oxidation of Metals, 1995, 44(1-2), 113.
29 Brady M P, Wright I G, Gleeson B. JOM, 2000, 52(1), 16.
30 Xu X Q, Zhang X F, Chen G L, et al. Materials Letters, 2011, 65(21-22), 3285.
31 Xu X Q, Zhang X F, Sun X Y, et al. Oxidation of Metals, 2012, 78(5), 349.
32 Li Q, Song P, Li Z H, et al. Nuclear Materials and Energy, 2023, 34, 101381.
33 Narukawa T, Kondo K, Fujimura Y, et al. Journal of Nuclear Materials, 2023, 587(15), 154736.
34 Lipkina K, Hallatt D, Geiger E, et al. Journal of Nuclear Materials, 2020, 541(1), 152305.
35 Gamanov Š, Holzer J, Roupcová P, et al. Corrosion Science, 2022, 206, 110498.
36 Li Z Y, Chen L J, Zhang H Y, et al. Materials, 2021, 14(3), 526.
37 Stratil L, Horník V, Dymáek P, et al. Metals, 2020, 10(11), 1478.
38 McGurty J A. U. S. patent, 05/788396, 1978.
39 Ramakrishnan V, McGurty J A, Jayaraman N. Oxidation of Metals, 1988, 30(3), 185.
40 Rybicki G C, Smialek J L. Oxidation of Metals, 1989, 31(3), 275.
41 Brumm M, Grabke H J. Corrosion Science, 1992, 33, 1677.
42 Huang Y C, Peng X, Chen X Q. Journal of Alloys and Compounds, 2021, 863, 158666.
43 Huang Y C. Research on the phase transformation mechanism of high temperature thermal growth of aluminum oxide. Ph. D. Thesis, University of Science and Technology of China, China, 2019 (in Chinese).
黄渊超. 高温热生长氧化铝相变机理研究. 博士学位论文, 中国科学技术大学, 2019.
44 Lipkin D M, Clarke D R, Pompe W. Corrosion Science, 1997, 39(2), 231.
45 Peng X, Li T, Pan W P. Scripta Materialia, 2001, 44(7), 1033.
46 Yun D W, Seo S M, Jeong H W, et al. Journal of Alloys and Compounds, 2017, 710, 8.
47 Tang H P, Wang Y, Liu Y, et al. Journal of Central South University, 2013, 20(12), 3345.
48 Liu T, Wang C X, Shen H L, et al. Corrosion Science, 2013, 76, 310.
49 Liu T, Wang L B, Wang C X, et al. Corrosion Science, 2016, 104, 17.
50 Xia Y, Wang J, Meng H J, et al. Corrosion Science and Protection Technology, 2019, 31(2), 7(in Chinese).
夏焱, 王剑, 孟浩杰, 等. 腐蚀科学与防护技术, 2019, 31(2), 7.
51 Qiao Y J, Wang P, Qi W, et al. Journal of Alloys and Compounds, 2020, 828, 154310.
52 Palm M. Intermetallics, 2005, 13(12), 1286.
53 Airiskallio E, Nurmi E, Heinonen M H, et al. Corrosion Science, 2010, 52(10), 3394.
54 Zhang Z G, Gesmundo F, Hou P Y, et al. Corrosion Science, 2006, 48(3), 741.
55 Wagner C. Corrosion Science, 1965, 5(11), 751.
56 Josefsson H, Liu F, Svensson J E, et al. Materials and Corrosion, 2005, 56(11), 801.
57 Li D Q, Guo H B, Wang D, et al. Corrosion Science, 2013, 66, 125.
58 Pint B A, More K L, Tortorelli P F, et al. Materials Science Forum, 2001, 369, 411.
59 Cotell C M, Yurek G J, Hussey R J, et al. Oxidation of Metals, 1990, 34(3), 173.
60 Li D Q, Zhou L X, Xi Y P, et al. Journal of Alloys and Compounds, 2017, 692, 427.
61 Burtin P, Brunelle J P, Pijolat M, et al. Applied Catalysis, 1987, 34, 239.
62 Pint B A. Oxidation of Metals, 1996, 45(1), 1.
63 Gao W, Liu Z Y, Li Z. Advanced Materials, 2001, 13(12-13), 1001.
64 Li Q, Peng X, Zhang J Q, et al. Corrosion Science, 2010, 52(4), 1213.
65 Wang X Y, Xin L, Wang F H, et al. Journal of Materials Science & Technology, 2014, 30(9), 867.
66 Wang F S. Optimal Control Applications and Methods, 1993, 14(1), 39.
67 Rittenhouse J, Luebbe M, Hoffman A, et al. Corrosion Science, 2024, 226, 111688.
68 Sun D J, Liang C Y, Shang J L, et al. Applied Surface Science, 2016, 385, 587.
69 Stringer J, Wilcox B A, Jaffee R I. Oxidation of Metals, 1972, 5(1), 11.

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