磁性多壁碳纳米管的制备及用于类芬顿反应催化降解橙黄Ⅱ

doi:10.11896/cldb.22120166

材料导报

2024, Vol. 38

Issue (9): 22120166-7 https://doi.org/10.11896/cldb.22120166

无机非金属及其复合材料

磁性多壁碳纳米管的制备及用于类芬顿反应催化降解橙黄Ⅱ

苗青山, 杨璟, 张铁成, 李文鹏, 陕绍云, 苏红莹^*

昆明理工大学化学工程学院,昆明 650500

Preparation of Magnetic Multi-walled Carbon Nanotubes as Catalyst for Degradation of Orange Ⅱ by Fenton-like Reaction

MIAO Qingshan, YANG Jing, ZHANG Tiecheng, LI Wenpeng, SHAN Shaoyun, SU Hongying^*

Faculty of Chemical Engineering, Kunming University of Science and Technology, Kunming 650500, China

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摘要为了提高非均相类芬顿体系的催化效率,采用原位生长法和直接混合法分别合成了Fe₃O₄修饰的磁性多壁碳纳米管(Fe₃O₄-MWCNTs)纳米复合材料,并对其作为类芬顿催化剂降解偶氮染料橙黄Ⅱ的效果进行了研究。通过X射线衍射(XRD)、傅里叶变换红外光谱(FTIR)、透射电镜(TEM)、热重分析(TGA)和磁学性能(VSM)检测对制备的Fe₃O₄-MWCNTs磁性纳米复合材料的组成、结构、形貌及性能等进行了表征,结果表明:原位生长法获得的Fe₃O₄-MWCNTs纳米复合材料具有良好的磁学性能,且Fe₃O₄纳米粒子均匀分布于碳纳米管的表面。降解实验结果表明:在Fe₃O₄-MWCNTs磁性纳米复合催化剂用量为0.025 g、H₂O₂用量为555 μL、pH值为2.5、反应温度为25 ℃、橙黄Ⅱ溶液初始浓度为50 mg/L的条件下,6 h后橙黄Ⅱ的去除率达到99.9%。该复合材料也表现出良好的稳定性和可重复使用性,磁分离循环使用四次后对橙黄Ⅱ的去除率仍能保持在97%以上。

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关键词: 类芬顿反应 Fe₃O₄ 多壁碳纳米管橙黄Ⅱ 降解

Abstract: In order to enhance the catalyst efficiency of heterogeneous Fenton-like system, Fe₃O₄-modified multi-walled carbon nanotubes (Fe₃O₄-MWCNTs) nanocomposites were synthesized by in situ growth and direct mixing methods, respectively. And their effectiveness as Fenton-like catalysts for the degradation of the azo dye orange Ⅱ was studied in this work. The composition, structure, morphology, and properties of the prepared Fe₃O₄-MWCNTs magnetic nanocomposites were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), and magnetic property detection (VSM). The results show that the Fe₃O₄-MWCNTs nanocomposites obtained by in situ growth method have better magnetic properties and the Fe₃O₄ nanoparticles are uniformly distributed on the surface of carbon nanotubes. The degradation experiments indicated that the removal efficiency of orange Ⅱ reached up to 99.9% after 6 h at 25 ℃ under the following conditions: concentration of orange Ⅱ at 50 mg/L, H₂O₂ dosage was 555 μL, Fe₃O₄-MWCNTs magnetic nanocomposites dosage was 0.025 g, pH 2.5. The Fe₃O₄-MWCNTs composite also shows excellent stability and reproducibility, with the removal of orange Ⅱ remaining above 97% after four cycles of magnetic separation.

Key words: Fenton-like reaction Fe₃O₄ multi-walled carbon nanotubes orange Ⅱ degradation

出版日期: 2024-05-10 发布日期: 2024-05-13

ZTFLH:

TQ426.64

基金资助: 云南省基础研究计划项目(202201AT070140);云南省“万人计划”青年拔尖人才专项(YNWR-QNBJ-2019-085)

通讯作者: * 苏红莹,昆明理工大学化学工程学院副教授、硕士研究生导师。2012年毕业于四川大学国家生物医学材料工程技术研究中心,获高分子化学与物理博士学位。目前主要从事天然高分子的改性及应用、环境响应型水凝胶微/纳米粒子的构建及作为生物材料的应用等方面的研究工作。hongyingsu@kust.edu.cn

作者简介: 苗青山,2019年7月于潍坊医学院获得工学学士学位。现为昆明理工大学化学工程学院硕士研究生,在苏红莹副教授的指导下进行研究。目前主要研究领域为功能纳米材料。

引用本文:

苗青山, 杨璟, 张铁成, 李文鹏, 陕绍云, 苏红莹. 磁性多壁碳纳米管的制备及用于类芬顿反应催化降解橙黄Ⅱ[J]. 材料导报, 2024, 38(9): 22120166-7.
MIAO Qingshan, YANG Jing, ZHANG Tiecheng, LI Wenpeng, SHAN Shaoyun, SU Hongying. Preparation of Magnetic Multi-walled Carbon Nanotubes as Catalyst for Degradation of Orange Ⅱ by Fenton-like Reaction. Materials Reports, 2024, 38(9): 22120166-7.

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https://www.mater-rep.com/CN/10.11896/cldb.22120166 或 https://www.mater-rep.com/CN/Y2024/V38/I9/22120166

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