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材料导报  2024, Vol. 38 Issue (3): 22100129-7    https://doi.org/10.11896/cldb.22100129
  高分子与聚合物基复合材料 |
酶促咖啡酸制备超疏水棉织物及其油水分离应用
朱飞1,2,3, 杨雪1,2,3, 苏静1,2,3, 王鸿博1,2,3,*
1 江南大学纺织科学与工程学院,江苏 无锡 214122
2 江苏省功能纺织品工程技术研究中心,江苏 无锡 214122
3 生态纺织教育部重点实验室,江苏 无锡 214122
Preparation of Super Hydrophobic Cotton Fabric Based on Caffeic Acid Catalyzed by Enzyme and Its Oil-Water Separation Application
ZHU Fei1,2,3, YANG Xue1,2,3, SU Jing1,2,3, WANG Hongbo1,2,3,*
1 College of Textile Science and Engineering, Jiangnan University, Wuxi 214122, Jiangsu, China
2 Jiangsu Engineering Technology Research Center for Functional Textiles, Wuxi 214122, Jiangsu, China
3 Key Laboratory of Science & Technology of Eco-textiles, Ministry of Education, Wuxi 214122, Jiangsu, China
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摘要 海上溢油事故和工业废水的排放对环境造成的危害日益严重,为此选用棉织物并对其进行超疏水改性使其成为油水分离材料。先利用漆酶、咖啡酸和Fe2+在棉织物表面构建微米级粗糙结构,之后利用低表面能物质十六烷基三甲氧基硅烷(HDTMS)修饰制备出具有复合结构的超疏水改性棉织物。对改性棉织物的表面形貌、化学组成、耐久稳定性、自清洁性能和油水分离性能进行测试。结果表明:当咖啡酸浓度为3 mg/L、硫酸亚铁浓度为12 mg/L、漆酶浓度为0.75 U/mL、HDTMS浓度为1％(质量分数,下同)时,制备的改性棉织物具有良好的超疏水性能,静态接触角高达164.6°,滚动角为6.75°。改性棉织物在耐摩擦、耐酸碱、耐水洗的测试中均表现出稳定的超疏水性能,并表现出良好的自清洁性能,在经过15次油水分离循环后,分离效率能保持在96％以上,在自清洁服装和油水分离的应用方面具有巨大的潜力。
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朱飞
杨雪
苏静
王鸿博
关键词:  超疏水  咖啡酸  漆酶  十六烷基三甲氧基硅烷  棉织物  油水分离    
Abstract: The oil spill accident at sea and the discharge of industrial waste water have caused increasingly serious harm to the environment. Therefore, cotton fabric has been super hydrophobic modified to make it a potential material for oil water separation. Laccase, caffeic acid and Fe2+ were used to construct a micron scale rough structure on the surface of cotton fabric, and then the composite structure of super hydrophobic modified cotton fabric was prepared by modifying the cotton fabric with low surface energy substance hexadecyl trimethoxysilane (HDTMS). The surface morphology, chemical composition, durability, self-cleaning performance and oil-water separation performance of the modified fabric were tested. The results showed that when the concentration of caffeic acid was 3 mg/L, the concentration of ferrous sulfate was 12 mg/L, the concentration of laccase was 0.75 U/mL, and the concentration of HDTMS was 1%, the modified cotton fabric had good super hydrophobic properties. The static contact angle was 164.6°, and the rolling angle was 6.75°. The modified cotton fabric shows stable super hydrophobic perfor-mance in the tests of friction resistance, acid and alkali resistance, and water washing resistance, and shows good self-cleaning performance. After 15 oil-water separation cycles, the separation efficiency can be maintained at more than 96%, which has great potential in the application of self-cleaning clothing and oil-water separation.
Key words:  super hydrophobic    caffeic acid    laccase    hexadecyltrimethoxysilane    cotton fabric    oil-water separation
出版日期:  2024-02-10      发布日期:  2024-02-19
ZTFLH:  TB34  
基金资助: 国家自然科学基金(52003108);中国博士后科学基金资助项目(2022M721359);中央高校基本科研业务费专项资金(JUSRP121027)
通讯作者:  *王鸿博,江南大学纺织科学与工程学院教授、博士研究生导师。2007毕业于江南大学获博士学位。长期从事功能纺织材料、纺织技术、纺织新产品开发研究。主持江苏省重大科技成果转化、江苏省科技攻关、省部级重点实验室等项目10项,主要参与国家“十三五”重大科技专项、国家自然科学基金、博士点基金和其他省部级项目8项。发表学术论文180多篇,其中SCI收录期刊论文40余篇,CSCD论文100余篇。授权发明专利15件。wxwanghb@163.com   
作者简介:  朱飞,自2020年9月以来在江南大学攻读材料与化工专业硕士学位,在王鸿博教授的指导下进行研究。目前主要研究领域为功能性纺织材料的制备理论与技术和功能纺织品设计与开发。
引用本文:    
朱飞, 杨雪, 苏静, 王鸿博. 酶促咖啡酸制备超疏水棉织物及其油水分离应用[J]. 材料导报, 2024, 38(3): 22100129-7.
ZHU Fei, YANG Xue, SU Jing, WANG Hongbo. Preparation of Super Hydrophobic Cotton Fabric Based on Caffeic Acid Catalyzed by Enzyme and Its Oil-Water Separation Application. Materials Reports, 2024, 38(3): 22100129-7.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.22100129  或          https://www.mater-rep.com/CN/Y2024/V38/I3/22100129
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