应变玻璃统一形成判据的研究进展

doi:10.11896/cldb.24060225

材料导报

2025, Vol. 39

Issue (11): 24060225-10 https://doi.org/10.11896/cldb.24060225

无机非金属及其复合材料

应变玻璃统一形成判据的研究进展

范孟娜, 陶雪飞^*, 宗洪祥, 丁向东

西安交通大学金属材料强度国家重点实验室,西安 710049

Research Progress of the Unified Formation Criterion of Strain Glass

FAN Mengna, TAO Xuefei^*, ZONG Hongxiang, DING Xiangdong

State Key Laboratory for Mechanical Behavior of Materials, Xi’an Jiaotong University, Xi’an 710049, China

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摘要应变玻璃作为一种新型的铁性功能玻璃,可以通过在形状记忆合金中引入缺陷获得,在微观上表现为长程无序的纳米马氏体畴冻结态。同时应变玻璃作为一种形状记忆合金,具有形状记忆效应和超弹性行为,获得了人们的关注,并且被广泛地应用在手机、医疗等日常生活和航空航天等高科技领域。此外,与传统的马氏体合金相比,应变玻璃合金具有Invar效应和智能阻尼效应等奇异性能。应变玻璃转变作为一种全新的结构相变现象,研究发现不仅点缺陷可以引起应变玻璃转变,而且位错和析出物也可以引起应变玻璃转变,这三种应变玻璃转变具有统一的微观物理图像。本文主要总结了点缺陷型应变玻璃的形成判据,并且通过分子动力学模拟的方法成功复现了位错型应变玻璃的转变过程以及形成判据,据此得到了析出物型应变玻璃的形成判据,最终建立了多种应变玻璃形成条件的统一判据。

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	范孟娜
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	丁向东

关键词: 应变玻璃应变网络缺陷分子动力学微观机制

Abstract: Strain glass, as a new type of ferroic functional glass, can be obtained by introducing defects into shape memory alloys. Microscopically, it manifests as a frozen state of long-range disordered nano-martensitic domains. As a shape memory alloy, strain glass exhibits shape me-mory effects and superelastic behavior, garnering widespread attention. It has been widely applied in everyday life, such as in mobile phones and medical devices, as well as in high-tech fields like aerospace. Additionally, compared to traditional martensitic alloys, strain glass alloys possess unique properties such as the Invar effect and smart damping effect. As a brand-new structural phase transition phenomenon, it has been disco-vered that not only point defects can induce strain glass transitions, but dislocations and precipitates can also cause these transitions. These three types of strain glass transitions share a unified microscopic physical image. In this paper, the formation criterion of point defect strain glass is summarized, and the transformation process of dislocation strain glass and its formation criterion are successfully reproduced by molecular dynamics simulation method, and the formation criterion of precipitated strain glass is obtained accordingly, and the unified criterion of various strain glass formation conditions is finally established.

Key words: strain glass strain network defect molecular dynamics microscopic mechanism

发布日期: 2025-05-29

ZTFLH:

TG139+.6

基金资助: 国家自然科学基金(51931004)

通讯作者: *陶雪飞,博士,目前主要研究领域为应变玻璃的微观转变机制。taoxuefei@stu.xjtu.edu.cn

作者简介: 范孟娜,西安交通大学材料科学与工程学院硕士研究生,在宗洪祥教授的指导下进行研究。目前主要研究领域为W颗粒对3D打印NiTi形状记忆合金的微观结构和性能的影响。

引用本文:

范孟娜, 陶雪飞, 宗洪祥, 丁向东. 应变玻璃统一形成判据的研究进展[J]. 材料导报, 2025, 39(11): 24060225-10.
FAN Mengna, TAO Xuefei, ZONG Hongxiang, DING Xiangdong. Research Progress of the Unified Formation Criterion of Strain Glass. Materials Reports, 2025, 39(11): 24060225-10.

链接本文:

https://www.mater-rep.com/CN/10.11896/cldb.24060225 或 https://www.mater-rep.com/CN/Y2025/V39/I11/24060225

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