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材料导报  2024, Vol. 38 Issue (19): 23010125-6    https://doi.org/10.11896/cldb.23010125
  无机非金属及其复合材料 |
可溶性P2O5对超细硫铝酸盐水泥基双液注浆材料早期水化性能的影响及机理
张建武1,2,*, 管学茂2, 汪潇1, 金彪1, 张小婷1
1 河南城建学院材料与化工学院,河南 平顶山 467036
2 河南理工大学河南省深地材料科学与技术重点实验室,河南 焦作 454000
Effect and Mechanism of Soluble P2O5 on the Early Hydration of Ultra-fine Sulfoaluminate Cement-based Double Liquid Grouting Materials
ZHANG Jianwu1,2,*, GUAN Xuemao2, WANG Xiao1, JIN Biao1, ZHANG Xiaoting1
1 School of Materials and Chemical Engineering, Henan University of Urban Construction, Pingdingshan 467036, Henan, China
2 Henan Key Laboratory of Materials on Deep-Earth Engineering, Henan Polytechnic University, Jiaozuo 454000, Henan, China
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摘要 为了指导磷石膏在超细硫铝酸盐水泥基双液注浆材料(SCBGM)中的高效应用,研究了可溶性P2O5对大水灰比下SCBGM早期水化性能的影响及作用机理。结果表明,可溶性P2O5的加入不显著影响SCBGM浆体的凝结时间。可溶性P2O5掺量为0%~1.5%时,随着其掺量的增加,SCBGM早期强度逐渐增大。在1.5%最佳掺量下,可溶性P2O5可显著提高早期SCBGM中钙矾石的生成量,还可以显著优化硬化体中钙矾石的分布特征,使其由团簇状转变为显著的搭接交错分布状态,进而充分发挥钙矾石晶体的强度骨架效应。
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张建武
管学茂
汪潇
金彪
张小婷
关键词:  可溶性P2O5  硫铝酸盐水泥  注浆材料  水化    
Abstract: In order to guide the efficient application of phosphogypsum in ultra-fine sulfoaluminate cement-based double liquid grouting materials (SCBGM), the effect of soluble P2O5 on the early hydration performance of SCBGM at high water-cement ratio and its mechanism were studied. The results showed that the addition of soluble P2O5 did not significantly affect the setting time of SCBGM slurry. When the soluble P2O5 content was between 0% and 1.5%, the early strength of SCBGM increased with the increase of the soluble P2O5 content. At the optimum dosage of 1.5%, soluble P2O5 can significantly increase the amount of ettringite in early hydration of SCBGM, and also significantly optimize the distribution characteristics of ettringite in the hardened body, which changed from cluster shape to highly lapped staggered distribution, so as to achieve full potential of the strength skeleton effect of ettringite crystal.
Key words:  soluble P2O5    sulfoaluminate cement    grouting material    hydration
出版日期:  2024-10-10      发布日期:  2024-10-23
ZTFLH:  TQ172.7  
基金资助: 河南省重大公益项目(201300311000);河南省深地材料科学与技术重点实验室开放课题(MDE2019-03)
通讯作者:  *张建武,通信作者,河南城建学院材料与化工学院讲师,河南理工大学兼职硕士研究生导师。2011年河南理工大学材料科学与工程学院本科毕业,2018年河南理工大学材料科学与工程学院矿业工程材料专业毕业后到河南城建学院工作至今。目前,主要从事特种水泥基材料、固废资源化利用等方面的研究工作。发表论文20余篇,获河南省科技进步奖1项。20181023@hncj.edu.cn   
引用本文:    
张建武, 管学茂, 汪潇, 金彪, 张小婷. 可溶性P2O5对超细硫铝酸盐水泥基双液注浆材料早期水化性能的影响及机理[J]. 材料导报, 2024, 38(19): 23010125-6.
ZHANG Jianwu, GUAN Xuemao, WANG Xiao, JIN Biao, ZHANG Xiaoting. Effect and Mechanism of Soluble P2O5 on the Early Hydration of Ultra-fine Sulfoaluminate Cement-based Double Liquid Grouting Materials. Materials Reports, 2024, 38(19): 23010125-6.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.23010125  或          http://www.mater-rep.com/CN/Y2024/V38/I19/23010125
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