Cu离子分子筛催化材料在去除NOx方面应用的研究进展

doi:10.11896/cldb.22030122

材料导报

2024, Vol. 38

Issue (2): 22030122-9 https://doi.org/10.11896/cldb.22030122

无机非金属及其复合材料

Cu离子分子筛催化材料在去除NO_x方面应用的研究进展

孟令钦¹, 崔素萍^1,*, 甘延玲², 王亚丽¹, 马晓宇¹

1 北京工业大学材料与制造学部,北京 100124
2 中山大学环境科学与工程学院,广州 510275

Research Progress on Application of Cu Ion Zeolite Catalyst for NO_x Removal

MENG Lingqin¹, CUI Suping^1,*, GAN Yanling², WANG Yali¹, MA Xiaoyu¹

1 Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing 100124, China
2 School of Environmental Science and Engineering, Sun Yat-Sen University, Guangzhou 510275, China

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摘要控制大气中氮氧化物的排放对环境和人体健康有着至关重要的作用,应用于NO_x去除的技术有很多,其中选择性催化还原(NH₃-SCR)技术是去除NO_x极有效的技术之一,利用CO去除NO_x为烟气脱硝(CO-SCR)提供了一种简单且低成本的技术,直接催化分解NO_x被认为是去除NO_x最理想、最环保的技术。Cu离子分子筛作为去除NO_x的高效催化剂,具有宽温度窗口和良好的水热稳定性。本文综述了Cu交换分子筛在去除NO领域的研究进展,讨论了Cu离子分子筛在NH₃-SCR、CO-SCR以及直接催化分解NO中的应用,着重总结了Cu离子参与去除NO的反应机理,归纳了分子筛中Cu活性位点对脱硝性能的影响,还讨论了铜离子分子筛的抗H₂O和SO₂中毒性能,展望了Cu离子分子筛未来可能的发展方向。

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关键词: Cu离子分子筛 NO_x去除 NH₃-SCR NO直接分解 CO-SCR

Abstract: It is crucial to control NO_x emissions into the atmosphere for the environment and health. Many technologies are available for NO_x removal, selective catalytic reduction(SCR) is one of the most effective technologies for NO_x removal. The reduction of NO by CO offers a simple and low-cost technology for flue gas denitrification (CO-SCR), and direct decomposition of NO is regarded as the most ideal and environmentally friendly technology for the removal of NO_x. As an efficient catalyst for NO_x removal, Cu ion zeolite catalysts have wide temperature windows and good hydrothermal stability. In this review, the research progress of Cu ion zeolite catalysts in NO_x removal is studied. The NH₃-SCR, CO-SCR, and direct catalyst decomposition of NO on the Cu ion zeolite catalysts are discussed, involving the reaction mechanism of Cu ions zeolite catalysts as well as the effect Cu active sites. In addition, the poison-resistant properties of Cu ion zeolite catalysts to H₂O and SO₂ are also summarized. And the future development of Cu ion zeolite has been discussed.

Key words: Cu ion zeolite catalyst NO_x removal NH₃-SCR NO direct decomposition CO-SCR

出版日期: 2024-01-25 发布日期: 2024-01-26

ZTFLH:

X511

基金资助: 国家自然科学基金(52072009);国家自然科学基金创新研究群体项目(51621003)

通讯作者: *崔素萍,北京工业大学材料与制造学部教授、博士、博士研究生导师。目前主要从事高性能水泥、生态建筑材料、材料LCA、环境材料等方面的研究工作。成果获得国家科技进步二等奖2项、省部级科技奖励9项、国家级教学成果二等奖1项、北京市教学成果奖2项,其中第一完成人获国家科技进步二等奖1项、省部级科技进步一等奖3项。专/译著7部,发表学术论文160多篇,授权发明专利80多件,参与制定标准5项。cuisuping@bjut.edu.cn

作者简介: 孟令钦,2020年6月于北京工业大学获得工学学士学位。现为北京工业大学材料与制造学部硕士研究生,在崔素萍教授的指导下进行研究。目前主要研究领域为烟气脱硝催化材料。

引用本文:

孟令钦, 崔素萍, 甘延玲, 王亚丽, 马晓宇. Cu离子分子筛催化材料在去除NO_x方面应用的研究进展[J]. 材料导报, 2024, 38(2): 22030122-9.
MENG Lingqin, CUI Suping, GAN Yanling, WANG Yali, MA Xiaoyu. Research Progress on Application of Cu Ion Zeolite Catalyst for NO_x Removal. Materials Reports, 2024, 38(2): 22030122-9.

链接本文:

http://www.mater-rep.com/CN/10.11896/cldb.22030122 或 http://www.mater-rep.com/CN/Y2024/V38/I2/22030122

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