Please wait a minute...
《材料导报》期刊社  2017, Vol. 31 Issue (11): 144-150    https://doi.org/10.11896/j.issn.1005-023X.2017.011.020
  金属腐蚀与防护 |
镁合金表面水滑石膜耐蚀性研究进展*
巴志新1,2, 陈永俊1, 董强胜1,2, 马彪1, 吕小雨1
1 南京工程学院材料工程学院,南京211167;
2 江苏省先进结构材料与应用技术重点实验室,南京 211167
Research Progress on Corrosion Resistance of Hydrotalcite Films on Magnesium Alloys
BA Zhixin1,2, CHEN Yongjun1, DONG Qiangsheng1,2, MA Biao1, LU Xiaoyu1
1 School of Materials Science and Engineering, Nanjing Institute of Technology, Nanjing 211167;
2 Jiangsu Province Advanced Structural Materials and Application Technology Laboratory, Nanjing 211167
下载:  全 文 ( PDF ) ( 1835KB ) 
输出:  BibTeX | EndNote (RIS)      
摘要 镁合金由于具有优异的性能受到研究者的关注和重视,但易腐蚀的特性严重制约了其工程应用,故需采取合适的手段增强其耐蚀性。水滑石膜具有良好的离子交换性及物理屏障作用,近年来在镁合金表面改性方面逐步得到发展。介绍了多种镁合金表面水滑石膜层的制备工艺及其成膜原理,初步探讨了其在腐蚀环境下的耐蚀机制,并详述了几种进一步提高水滑石膜质量的改性方法及原理,展望了未来研究的工作重点和发展方向。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
巴志新
陈永俊
董强胜
马彪
吕小雨
关键词:  镁合金  水滑石膜  耐蚀机理  表面改性    
Abstract: Magnesium and its alloys have attracted much attention due to their excellent properties. However, the poor corrosion resistance severely limits its engineering application, therefore suitable methods should be developed to improve the corrosion resistance of magnesium alloys. The investigation of hydrotalcite coatings for surface modification on Mg alloys is increasingly deve-loped owing to good ion exchange ability and physical barrier effect. Several preparation methods of hydrotalcite coatings and their formation mechanism are introduced in this paper. Meanwhile, the anticorrosion mechanism of coatings under corrosive environment condition are preliminarily discussed and various modification methods to further enhance coating properties are described in detail. Finally, the focus of future research and development are expected.
Key words:  magnesium alloy    hydrotalcite coating    anti-corrosion mechanism    surface modification
               出版日期:  2017-06-10      发布日期:  2018-05-04
ZTFLH:  TG1778  
基金资助: 江苏省大学生实践创新训练计划项目(201611276072H);南京工程学院大学生科技创新基金项目(TB201702016);南京工程学院校级科研基金项目(JCYJ201603);江苏省普通高校研究生科研创新计划项目(SJZZ16_0292)
作者简介:  巴志新:女,1979年生,博士,副教授,主要从事材料表面工程及纳米材料方面的研究工作 E-mail:bzhx@njit.edu.cn
引用本文:    
巴志新, 陈永俊, 董强胜, 马彪, 吕小雨. 镁合金表面水滑石膜耐蚀性研究进展*[J]. 《材料导报》期刊社, 2017, 31(11): 144-150.
BA Zhixin, CHEN Yongjun, DONG Qiangsheng, MA Biao, LU Xiaoyu. Research Progress on Corrosion Resistance of Hydrotalcite Films on Magnesium Alloys. Materials Reports, 2017, 31(11): 144-150.
链接本文:  
http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2017.011.020  或          http://www.mater-rep.com/CN/Y2017/V31/I11/144
1 Zeng R C, et al. Review of studies on corrosion of magnesium alloys[J]. Trans Nonferrous Met Soc China,2006,16:s763.
2 Kim W C, et al. Influence of Ca on the corrosion properties of magnesium for biomaterials[J]. Mater Lett,2008,62(25):4146.
3 Cai J S, Cao F H, Chang L R, et al. The preparation and corrosion behaviors of MAO coating on AZ91D with rare earth conversion precursor film[J]. Appl Surf Sci,2011,257(8):3804.
4 Yang H Y, Chen X B, Guo X W, et al. Coating pretreatment for Mg alloy AZ91D[J]. Appl Surf Sci,2012,258(14):5472.
5 Song G. Recent progress in corrosion and protection of magnesium alloys[J]. Adv Eng Mater,2005,7(7):563.
6 Zeng R, Kainer K U, Blawert C, et al. Corrosion of an extruded magnesium alloy ZK60 component—The role of microstructural features[J]. J Alloys Compd,2011,509(13):4462.
7 Staiger M P, Pietak A M, et al. Magnesium and its alloys as orthopedic biomaterials: A review[J]. Biomaterials,2006,27(9):1728.
8 Narayanan T S N S, Park I S, Min H L. Strategies to improve the corrosion resistance of microarc oxidation (MAO) coated magnesium alloys for degradable implants: Prospects and challenges[J]. Prog Mater Sci,2014,60(3):1.
9 Zhang R F,Zhang Y Q,Zhang S F, et al. Corrosion degradation behaviors of micro arc oxidation coatings on Mg-1.0Ca alloys in simulated body fluid[J]. Chinese J Nonferrous Met,2015,25(5):1220(in Chinese).
张荣发,张勇强,张淑芳,等.Mg-1.0Ca合金微弧氧化膜在模拟体液中的腐蚀降解行为 [J]. 中国有色金属学报,2015,25(5):1220.
10 Thirumalaikumarasamy D, Shanmugam K, Balasubramanian V. Influence of chloride ion concentration on immersion corrosion beha-viour of plasma sprayed alumina coatings on AZ31B magnesium alloy[J]. J Magn Alloys,2014,2(4):325.
11 Tao X W, Wang Z Z, Zhang X B, et al. Nanomechanical and corrosion properties of ZK60 magnesium alloy improved by Gd ion implantation [J]. Surf Rev Lett,2014,21(6):1450085.
12 Carcel B, Sampedro J, Ruescas A, et al. Corrosion and wear resis-tance improvement of magnesium alloys by laser cladding with Al-Si[J]. Phys Procedia,2011,12(1):353.
13 Hirahara H, Aisawa S, Akiyama T, et al. Intercalation of polyhydric alcohols into Mg-Al layered double hydroxide by calcination-rehydration reaction[J]. Clay Sci,2005,13(1):27.
14 Costa F R, Leuteritz A, Wagenknecht U, et al. Intercalation of Mg-Al layered double hydroxide by anionic surfactants: Preparation and characterization[J]. Appl Clay Sci,2008, 38(3-4):153.
15 Chen J, Zhang Q Y, Song Y W, et al. Research progress of hydrotalcite-like compounds and their application in corrosion protection[J]. J Xihua University:Nat Sci Ed,2014,33(5):64.(in Chinese).
陈君, 张勤勇, 宋影伟, 等. 水滑石类化合物及其在腐蚀防护应用中的研究进展 [J]. 西华大学学报: 自然科学版,2014,33(5):64.
16 Javierre E, et al. Tailoring the release of encapsulated corrosion inhibitors from damaged coatings: Controlled release kinetics by overlapping diffusion fronts[J]. Prog Org Coat,2012,75(1-2):20.
17 Terry P A. Characterization of Cr ion exchange with hydrotalcite[J]. Chemosphere,2004, 57(7):541.
18 Williams G, Mcmurray H N, Williams G, et al. Inhibition of filiform corrosion on polymer coated AA2024-T3 by hydrotalcite-like pigments incorporating organic anions[J]. Electrochem Solid-State Lett,2004,7(5):B13.
19 Lin J K, et al. Characterization of Mg,Al-hydrotalcite conversion film on Mg alloy and Cl- and CO32- anion-exchangeability of the film in a corrosive environment[J]. Scr Mater,2007,56(11):927.
20 Uan J Y, Lin J K, Sun Y S, et al. Surface coatings for improving the corrosion resistance and cell adhesion of AZ91D magnesium alloy through environmentally clean methods[J]. Thin Solid Films,2010,518(24):7563.
21 Lin J K, Uan J Y. Formation of Mg,Al-hydrotalcite conversion coa-ting on Mg alloy in aqueous HCO3-/CO32- and corresponding protection against corrosion by the coating[J]. Corros Sci,2009,51(5):1181.
22 Lin J K, Jeng K L, Uan J Y. Crystallization of a chemical conversion layer that forms on AZ91D magnesium alloy in carbonic acid[J]. Corros Sci,2011,53(11):3832.
23 Chen J, Song Y W, Shan D Y, et al. In situ growth of Mg-Al hydrotalcite conversion film on AZ31 magnesium alloy[J]. Corros Sci,2011,53(10):3281.
24 Chen J, Song Y W, Shan D Y, et al. In situ growth process of Mg-Al hydrotalcite conversion film on AZ31 Mg alloy[J]. J Mater Sci Technol,2015,31(4):384.
25 Chen J, Song Y W, Shan D Y, et al. Study of the in situ growth mechanism of Mg-Al hydrotalcite conversion film on AZ31 magnesium alloy[J]. Corros Sci,2012,63:148.
26 Chen J, Song Y W, Shan D Y, et al. Study of the corrosion mechanism of the in situ grown Mg-Al-CO32- hydrotalcite film on AZ31 alloy[J]. Corros Sci,2012,65:268.
27 Chen J, Song Y W, Shan D Y, et al. Influence of alloying elements and microstructure on the formation of hydrotalcite film on Mg alloys[J]. Corros Sci,2015,93:90.
28 Ba Z X, Dong Q S, Kong S X, et al. Formation and corrosion resis-tance of Mg-Al hydrotalcite film on Mg-Gd-Zn alloy[J]. Surf Rev Lett,2017,24(1):1750003-1.
29 Ba Z X, Wang Z Z, Dong Q S, et al. Preparation and properties of Mg, Al-hydrotalcite conversion film on magnesium alloy by ultrasonic assisted process[J]. Trans Mater Heat Treatment,2014,7(7):48.(in Chinese).
巴志新, 王章忠, 董强胜, 等. 超声辅助镁合金镁铝水滑石膜制备及性能 [J]. 材料热处理学报, 2014, 7(7): 48.
30 Ba Z X, Zhang X B, et al. The influence of ultrasonic wave on the corrosion resistance of Mg,Al-hydrotalcite conversion film on magnesium alloy[J]. J Funct Mater,2015,46(20):20092(in Chinese).
巴志新, 章晓波, 等. 超声波对镁合金镁铝水滑石膜耐蚀性的影响 [J]. 功能材料,2015,46(20):20092.
31 Ba Z X, Zhang X B, Wang Z Z, et al. Electric field assisted chemical conversion process of AZ91D magnesium alloy in HCO3-/CO32- solution[J]. Trans Nonferrous Metals Soc China, 2014,24(12):3818.
32 Chen J, Xu Q, Song Y W, et al. Characterization of the in situ growth manasseite/carbonates composite conversion film on Mg2Zn alloy[J]. Mater Lett,2015,150:65.
33 Chen J, Song Y W, Shan D Y, et al. Properties of dawsonite conversion film on AZ31 magnesium alloy[J]. Trans Nonferrous Met Soc China,2011,21(4):936.
34 Zeng R C, et al. Corrosion resistance of in-situ Mg-Al hydrotalcite conversion film on AZ31 magnesium alloy by one-step formation[J]. Trans Nonferrous Met Soc China,2015,25(6):1917.
35 Li S F, et al. One-step fabrication of oriented Mg/Al-layered double hydroxide film on magnesium substrate with urea hydrolysis and its corrosion resistance[J]. Compos Interfaces,2012,19(8):489.
36 Zhang F, Liu Z G, Zeng R C, et al. Corrosion resistance of Mg,Al-LDH coating on magnesium alloy AZ31[J]. Surf Coat Technol,2014,258:1152.
37 Wang J, et al. Hydrotalcite conversion coating on Mg alloy and its corrosion resistance[J]. J Alloys Compd,2010,494(1-2):271.
38 Ishizaki T, Cho S P, Saito N. Morphological control of vertically self-aligned nanosheets formed on magnesium alloy by surfactant-free hydrothermal synthesis[J]. CrystEngComm, 2009,11(11):2338.
39 Wang L, Zhang K Y, Sun W, et al. Hydrothermal synthesis of corrosion resistant hydrotalcite conversion coating on AZ91D alloy[J]. Mater Lett,2013,106:111.
40 Zhang F Z, Sun M, Xu S L, et al. Fabrication of oriented layered double hydroxide films by spin coating and their use in corrosion protection[J]. Chem Eng J,2008,141(1-3):362.
41 Li L Q, Wang S Y, Li Q. Preparation of metal matrix-containing hydrotalcite sol-gelself-healing coating and its corrosion resistance[J]. J Funct Mater,2013,44(23):3470(in Chinese).
李龙芹, 王韶音, 李青. 金属基掺杂水滑石自修复型溶胶-凝胶膜层制备及机理研究 [J]. 功能材料,2013,44(23):3470.
42 Lin J K, Uan J Y, Wu C P, et al. Direct growth of oriented Mg-Fe layered double hydroxide (LDH) on pure Mg substrates and in vitro corrosion and cell adhesion testing of LDH-coated Mg samples[J]. J Mater Chem,2011,21(13):5011.
43 Yi J L, Zhang X M, Chen M A, et al. Effect of Na2CO3 on corrosion resistance of cerium conversion film on Mg-Gd-Y-Zr magnesium alloy surface[J]. Scr Mater,2008,59(9):955.
44 Syu J H, Uan J Y, Lin M C, et al. Optically transparent Li-Al-CO3 layered double hydroxide thin films on an AZ31 Mg alloy formed by electrochemical deposition and their corrosion resistance in a dilute chloride environment[J]. Corros Sci,2013,68:238.
45 Wu F X, Liang J, Peng Z J, et al. Electrochemical deposition and characterization of Zn-Al layered double hydroxides (LDHs) films on magnesium alloy[J]. Appl Surf Sci,2014,313: 834.
46 Yu B L, Lin J K, Uan J Y. Applications of carbonic acid solution for developing conversion coatings on Mg alloy[J]. Trans Nonferrous Metals Soc China,2010,20(7):1331.
47 Yu B L, Pan X L, Uan J Y. Enhancement of corrosion resistance of Mg-9 wt.% Al-1 wt.% Zn alloy by a calcite (CaCO3) conversion hard coating[J]. Corros Sci,2010,52(5):1874.
48 Kamiyama N, Panomsuwan G, Yamamoto E, et al. Effect of treatment time in the Mg(OH)2/Mg-Al LDH composite film formed on Mg alloy AZ31 by steam coating on the corrosion resistance[J]. Surf Coat Technol,2016,286:172.
49 Ishizaki T, Kamiyama N, Watanabe K, et al. Corrosion resistance of Mg(OH)2/Mg-Al layered double hydroxide composite film formed directly on combustion-resistant magnesium alloy AMCa602 by steam coating[J]. Corros Sci,2015,92:76.
50 Ba Z, Dong Q, Zhang X, et al. Properties of Zr2ON2 film deposited on Mg-Gd-Zn alloy with Mg-Al hydrotalcite film by arc ion plating[J]. Surf Coat Technol,2016,294:67.
51 Ba Z X, Wang Z Z, Dai Y M, et al. Preparation and corrosion resis-tance of carbonate composite conversion film on magnesium alloy[J]. Heat Treat Met,2014,39(10): 57(in Chinese).
巴志新, 王章忠, 戴玉明, 等. 镁合金表面碳酸盐复合转化膜的制备及耐蚀性能 [J]. 金属热处理,2014,39(10):57.
52 Dong Q S, Ba Z X, Wang Z Z, et al. Cerium-based sealing treatment of Mg-Al hydrotalcite film on AZ91D magnesium alloy[J]. Acta Metall Sinica (English Letters),2016,29(11):993.
53 Ba Z X, Dong Q S, Zhang X B, et al. Cerium-based modification treatment of Mg-Al hydrotalcite film on AZ91D Mg alloy assisted with alternating electric field[J]. J Alloys Compd,2017,695:106.
54 Chen J, Song Y W, et al. Modifications of the hydrotalcite film on AZ31 Mg alloy by phytic acid: The effects on morphology, composition and corrosion resistance[J]. Corros Sci,2013,74:130.
55 Zhang M, Cai S, et al. In-situ defect repairing in hydroxyapatite/phytic acid hybrid coatings on AZ31 magnesium alloy by hydrothermal treatment[J]. J Alloys Compd,2016,658: 649.
56 Zeng R C, et al. Corrosion of molybdate intercalated hydrotalcite coating on AZ31 Mg alloy[J]. J Mater Chem A,2014,2(32):13049.
57 Yu X, Wang J, Zhang M L, et al. One-step synthesis of lamellar molybdate pillared hydrotalcite and its application for AZ31 Mg alloy protection[J]. Solid State Sci,2009,11(2):376.
58 Yu X, Wang J, Zhang M L, et al. Synthesis, characterization and anticorrosion performance of molybdate pillared hydrotalcite/in situ created ZnO composite as pigment for Mg-Li alloy protection[J]. Surf Coat Technol,2008,203(3-4):250.
59 Zhang X, et al. Mitigation of corrosion on magnesium alloy by predesigned surface corrosion[J]. Sci Rep,2015,5:17399.
60 Zhang F, Zhang C L, Zeng R C, et al. Corrosion resistance of the superhydrophobic Mg(OH)2/Mg-Al layered double hydroxide coa-tings on magnesium alloys[J]. Metals,2016,6(4):85.
[1] 刘印, 王昌, 于振涛, 盖晋阳, 曾德鹏. 医用镁合金的力学性能研究进展[J]. 材料导报, 2019, 33(z1): 288-292.
[2] 赵曦, 于振涛, 郑继明, 余森, 王昌. 合金元素影响镁合金弹性性能的第一性原理计算研究[J]. 材料导报, 2019, 33(z1): 293-296.
[3] 彭鹏, 汤爱涛, 佘加, 周世博, 潘复生. 超细晶镁合金的研究现状及展望[J]. 材料导报, 2019, 33(9): 1526-1534.
[4] 李响, 毛萍莉, 王峰, 王志, 刘正, 周乐. 长周期有序堆垛相(LPSO)的研究现状及在镁合金中的作用[J]. 材料导报, 2019, 33(7): 1182-1189.
[5] 宋雨来, 付洪德, 王震, 杨鹏聪. 镁合金的应力腐蚀开裂:机理、影响因素、防护技术[J]. 材料导报, 2019, 33(5): 834-840.
[6] 姚天宇, 杨海燕, 周素洪, 叶兵, 蒋海燕. 镁合金表面电沉积铝工艺的研究进展[J]. 材料导报, 2019, 33(3): 470-478.
[7] 仇磊, 陈鼎, 朱莉莉, 陈耀彤, 王思远, 冯鹏飞. 氧化石墨烯作为润滑油添加剂的分散稳定性[J]. 材料导报, 2019, 33(16): 2638-2643.
[8] 王爱国, 朱愿愿, 李燕, 刘开伟, 徐海燕, 孙道胜, 范良朝. 表面改性硅/铝质材料及其在水泥基材料中应用的研究进展[J]. 材料导报, 2019, 33(15): 2538-2545.
[9] 张娜,程仁菊,董含武,刘文君,詹俊,蒋斌,潘复生. Sr在耐热镁合金中的应用及研究进展[J]. 材料导报, 2019, 33(15): 2565-2571.
[10] 程国君, 产爽爽, 陈晨, 钱家盛, 丁国新, 王周锋. 改性剂对TiN/PS纳米复合材料流变行为的影响[J]. 材料导报, 2019, 33(14): 2444-2449.
[11] 郑博, 赵丽, 董仕节, 胡心彬. 镁铝金属间化合物的第一性原理研究[J]. 材料导报, 2019, 33(14): 2426-2430.
[12] 王春明,杨牧南,黄建辉,刘位江,梁彤祥. 镁合金表面自纳米化研究进展及现状[J]. 材料导报, 2019, 33(13): 2260-2265.
[13] 石磊, 柳翊, 沈俊芳, 金文中, 王黎, 张伟. P-ECAP挤压镁合金空心壁板的晶粒度演变模拟和实验研究[J]. 材料导报, 2019, 33(12): 2019-2024.
[14] 周杰, 李克, 王彪, 艾凡荣. 添加Nd对Mg-Zn-Ca合金非晶形成能力和耐蚀性的影响[J]. 材料导报, 2019, 33(1): 73-77.
[15] 谢红梅, 蒋斌, 彭程, 潘复生. SiO2/MoS2复合纳米基润滑油在镁合金冷轧中的摩擦学性能及润滑机理[J]. 《材料导报》期刊社, 2018, 32(8): 1276-1282.
No Suggested Reading articles found!
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed