Please wait a minute...
材料导报  2021, Vol. 35 Issue (Z1): 108-111    
  无机非金属及其复合材料 |
醇-水体系无表面活性剂纳米ZnO的制备及表征
廖培义, 陈延明, 王立岩, 高洁
沈阳工业大学石油化工学院,辽阳 111003
Synthesis and Characterization of ZnO Nanocrystals in Alcohol-Water Without Surfactants
LIAO Peiyi, CHEN Yanming, WANG Liyan, GAO Jie
School of Petrochemical Engineering, Shenyang University of Technology, Liaoyang 111003, China
下载:  全 文 ( PDF ) ( 4025KB ) 
输出:  BibTeX | EndNote (RIS)      
摘要 以乙酸锌为前驱物,乙醇、正丙醇和正丁醇为溶剂,不加入表面活性剂,通过改变反应体系中醇水体积比、pH值、前驱物浓度,在反应温度80 ℃、反应时间30 min的条件下,制备得到不同尺寸和形貌的纳米氧化锌粒子。通过透射电子显微镜(TEM)、X射线衍射和紫外-可见吸收光谱等方法对纳米氧化锌进行了表征。结果表明:所合成的纳米氧化锌样品在350~365 nm范围内具有较为明显的吸收峰,减小醇水体积比、减弱溶剂极性、增加前驱物乙酸锌浓度,均可以导致纳米氧化锌粒子尺寸变大、团聚加重,前驱物溶液pH值的改变对纳米氧化锌的吸收峰影响不大。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
廖培义
陈延明
王立岩
高洁
关键词:  醇-水反应体系  氧化锌纳米粒子  溶剂极性    
Abstract: ZnO nanocrystals with different sizes and morphologies were synthesized through using zinc acetate as precursor without surfactants under reaction temperature 80 ℃ and reaction time 30 min in different kinds of alcohols as solvent (ethanol, n-propanol and 1-butanol) by changing alcohol to water ratio, pH and precursor concentrations. The synthesized ZnO nanocrystals were characterized by using transmission electron microscopy (TEM), X-ray diffraction (XRD) and UV-visible absorption spectrum. The results show that the obtained ZnO nanocrystalline samples could give apparent absorption peaks in the range of 350—365 nm. The sizes and aggregations of the synthesized ZnO nanocrystals could increase by decreasing alcohol to water ratio and the polarity of alcohol. At the same time, the absorption peaks did not changed anymore by changing the precursor pH values.
Key words:  alcohol-water reaction system    zinc oxide nanocrystals    solvent polarity
                    发布日期:  2021-07-16
ZTFLH:  O781  
通讯作者:  yanmchen@163.com   
作者简介:  廖培义,沈阳工业大学硕士研究生,师从陈延明教授,从事纳米材料制备及应用研究。陈延明,教授,研究生导师。主要研究方向:有机高分子/无机纳米杂化功能材料。
引用本文:    
廖培义, 陈延明, 王立岩, 高洁. 醇-水体系无表面活性剂纳米ZnO的制备及表征[J]. 材料导报, 2021, 35(Z1): 108-111.
LIAO Peiyi, CHEN Yanming, WANG Liyan, GAO Jie. Synthesis and Characterization of ZnO Nanocrystals in Alcohol-Water Without Surfactants. Materials Reports, 2021, 35(Z1): 108-111.
链接本文:  
http://www.mater-rep.com/CN/  或          http://www.mater-rep.com/CN/Y2021/V35/IZ1/108
1 Wu C, Qiao X, Chen J, et al. Materials Chemistry & Physics, 2007, 102(1), 7.
2 郭梦雅, 李晓意, 易凯, 等.包装工程, 2019, 40(19), 172.
3 尉金枝, 卫灵君, 崔政伟.功能材料, 2020, 51(7), 97.
4 Seelig E W, Tang B, Alexey Y, et al.Materials Chemistry and Physics, 2016, 80(1), 257.
5 Kaluza S, Schröter M K, d'Alnoncourt R N, et al.Advanced Functional Materials, 2008, 18(22), 3670.
6 Joo J, Kwon S G, Yu J H, et al.Advanced Materials, 2005, 17(15), 1873.
7 Sikora B, Fronc K, Kaminska I, et al. Journal of Sol Gel Science & Technology, 2012, 61(1), 197.
8 Dem'Yanets L N, Kostomarov D V, Kuz'Mina I P.Inorganic Materials, 2002, 38(2), 124.
9 Fahmy A M, Hamza M A, Medien H A, et al.Chemical Education, 2002, 23(12), 26.
10 Li W, Shi E, Tian M, et al. Science in China, 1998, 41(5), 449.
11 Hosono E, Fujihara S, Kimura T, et al. Journal of Colloid & Interface Science, 2004, 272(2), 391.
12 Fonscca A S, Figueira P A, Pereira A S, et al.Journal of Nanoparticles Research, 2017, 19(2), 75.
13 Zhang J, Liu H, Wang Z, et al. Advanced Functional Materials, 2007, 17(18), 3897.
[1] 刘杭, 李明伟, 王鹏飞, 胡志涛, 尹华伟. 二维圆周平动法ADP单晶生长流动与传质数值模拟[J]. 材料导报, 2020, 34(20): 20022-20027.
[2] 李志巍, 李明伟, 胡志涛, 尹华伟. 喷流转晶法KDP晶体生长系统的流动与传质模拟[J]. CLDB, 2018, 32(8): 1362-1366.
[3] 尹华伟, 李明伟, 曹亚超, 程旻, 宋洁. ZTS晶体(100)面生长过程的实时AFM研究*[J]. 《材料导报》期刊社, 2017, 31(12): 15-20.
[4] 周川, 李明伟, 尹华伟, 崔启栋, 胡志涛. 不同运动方式KDP单晶生长流动与物质输运数值分析*[J]. 《材料导报》期刊社, 2017, 31(2): 136-141.
[1] Huimin PAN,Jun FU,Qingxin ZHAO. Sulfate Attack Resistance of Concrete Subjected to Disturbance in Hardening Stage[J]. Materials Reports, 2018, 32(2): 282 -287 .
[2] Xu LI,Ziru WANG,Li YANG,Zhendong ZHANG,Youting ZHANG,Yifan DU. Synthesis and Performance of Magnetic Oil Absorption Material with Rice Chaff Support[J]. Materials Reports, 2018, 32(2): 219 -222 .
[3] WANG Tong, BAO Yan. Advances on Functional Polyacrylate/Inorganic Nanocomposite Latex for Leather Finishing[J]. Materials Reports, 2017, 31(1): 64 -71 .
[4] HUANG Dajian, MA Zonghong, MA Chenyang, WANG Xinwei. Preparation and Properties of Gelatin/Chitosan Composite Films Enhanced by Chitin Nanofiber[J]. Materials Reports, 2017, 31(8): 21 -24 .
[5] ZHANG Le, ZHOU Tianyuan, CHEN Hao, YANG Hao, ZHANG Qitu, SONG Bo, WONG Chingping. Advances in Transparent Nd∶YAG Laser Ceramics[J]. Materials Reports, 2017, 31(13): 41 -50 .
[6] CHEN Bida, GAN Guisheng, WU Yiping, OU Yanjie. Advances in Persistence Phosphors Activated by Blue-light[J]. Materials Reports, 2017, 31(21): 37 -45 .
[7] ZHANG Yong, WANG Xiongyu, YU Jing, CAO Weicheng,FENG Pengfa, JIAO Shengjie. Advances in Surface Modification of Molybdenum and Molybdenum Alloys at Elevated Temperature[J]. Materials Reports, 2017, 31(7): 83 -87 .
[8] JIN Chenxin, XU Guojun, LIU Liekai, YUE Zhihao, LI Xiaomin,TANG Hao, ZHOU Lang. Effects of Bulk Electrical Resistivity and Doping Type of Silicon on the Electrochemical Performance of Lithium-ion Batteries with Silicon/Graphite Anodes[J]. Materials Reports, 2017, 31(22): 10 -14 .
[9] FANG Sheng, HUANG Xuefeng, ZHANG Pengcheng, ZHOU Junpeng, GUO Nan. A Mechanism Study of Loess Reinforcing by Electricity-modified Sodium Silicate[J]. Materials Reports, 2017, 31(22): 135 -141 .
[10] ZHOU Dianwu, HE Rong, LIU Jinshui, PENG Ping. Effects of Ge, Si Addition on Energy and Electronic Structure of ZrO2 and Zr(Fe,Cr)2[J]. Materials Reports, 2017, 31(22): 146 -152 .
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed