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材料导报  2020, Vol. 34 Issue (Z2): 128-131    
  无机非金属及其复合材料 |
玻璃黏温曲线的全温度段拟合
崔介东1,2, 曹欣1,2, 王萍萍1,2, 石丽芬1,2, 仲召进1,2, 赵凤阳1,2, 高强1,2, 李金威1,2
1 中建材蚌埠玻璃工业设计研究院有限公司,浮法玻璃新技术国家重点实验室,蚌埠 233010
2 硅基材料安徽省实验室,蚌埠 233010
Full Temperature Range Fitting of Glass Viscosity-Temperature Curve
CUI Jiedong1,2, CAO Xin1,2, WANG Pingping1,2, SHI Lifen1,2, ZHONG Zhaojin1,2, ZHAO Fengyang1,2, GAO Qiang1,2, LI Jinwei1,2
1 State Key Laboratory of Advanced Technology for Float Glass Technology, CNBM Bengbu Design & Research Institute for Glass Industry Co.Ltd, Bengbu 233010, China
2 Silica-based Materials Laboratory of Anhui Province, Bengbu 233010,China
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摘要 基于电子信息显示屏盖板玻璃的黏度温度测试数据,运用Vogel-Fulcher-Tammann方程(VFT 方程)与Mauro-Yue-Ellison-Gupta-Allan方程 (MYEGA 方程) 对全温度段玻璃黏度进行拟合与比较,结果表明:在玻璃退火点与浮法成型温度范围内的黏温拟合曲线,两个方程的拟合结果较为接近,而温度低于退火点和高于成型温度时,两个方程的拟合结果开始出现较大的偏差。同时,VFT方程拟合结果对数据选取的敏感性较强,数据量的选取对拟合结果的影响较大,而MYEGA方程对数据量的依赖性较小,数据的选取对结果影响较小,且其拟合值与实测值的偏差更小。在旋转黏度、平板黏度、退火点、应变点数据的基础上,以MYEGA方程进行自玻璃应变点开始至熔化温度的全温度段拟合,可以得到较为理想的玻璃黏温曲线。
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崔介东
曹欣
王萍萍
石丽芬
仲召进
赵凤阳
高强
李金威
关键词:  黏度  拟合  VFT方程  MYEGA方程    
Abstract: Based onthe measured viscosity-temperature data of display cover glass, the Vogel Fulcher Tammann equation (VFT) and Mauro-Yue-Ellison-Gupta-Allan equation (MYEGA) were used to fit and compare the viscosity temperature of glass in the full temperature range. The results showed that the fitting results of the two equations were close in the range of annealing point and forming point for float process, while the fitting results of the two equations began to appear large deviation when the temperature was lower than the annealing point or higher than the for-ming point. At the same time, the VFT equation fitting results are more sensitive to the data selection, the number of data has a greater impact on the fitting results, while the MYEGA equation was less dependent on the data selection, and the difference between the fitting value and the measured value is smaller. Based on the data of rotational viscosity, parallel plates viscosity, annealing point and strain point, an ideal glass viscosity temperature curve can be obtained by fitting the full temperature range from strain point to melting point with MYEGA equation.
Key words:  viscosity    fitting    VFT equation    MYEGA equation
               出版日期:  2020-11-25      发布日期:  2021-01-08
ZTFLH:  TQ171.112  
基金资助: 安徽省重点研发计划项目(202004a05020031)
通讯作者:  dargoncao@126.com   
作者简介:  崔介东,中建材蚌埠玻璃工业设计研究院有限公司,浮法玻璃新技术国家重点实验室,高级工程师。2008 年1 月毕业于中国科学院研究生院,获得材料学硕士学位。目前主要研究领域为特种功能玻璃新技术。曹欣,教授级高工,博士。2004年毕业于武汉理工大学,长期从事玻璃新材料领域的相关研究及产业化工作,包括电子信息显示玻璃,航空玻璃,具有特殊热、电性能的玻璃粉体新品种开发及浮法玻璃新技术、新方法探索与实践等方面,共承担了2项国家课题,包括十三五重点研发计划(2016YFB0303700),973国家重点研发计划(2012CB724608)等;主持和参与安徽省科技攻关计划、自然科学基金、科技重大专项、国际合作、上海市创新计划等省级项目共计14项。授权国际专利1项,发明专利19项,实用新型专利31项,发表论文20余篇。
引用本文:    
崔介东, 曹欣, 王萍萍, 石丽芬, 仲召进, 赵凤阳, 高强, 李金威. 玻璃黏温曲线的全温度段拟合[J]. 材料导报, 2020, 34(Z2): 128-131.
CUI Jiedong, CAO Xin, WANG Pingping, SHI Lifen, ZHONG Zhaojin, ZHAO Fengyang, GAO Qiang, LI Jinwei. Full Temperature Range Fitting of Glass Viscosity-Temperature Curve. Materials Reports, 2020, 34(Z2): 128-131.
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