Research Progress on Application of Organic Phosphonic Acid Compounds in Concrete Engineering and Their Retarding Mechanism
LYU Xingdong1,2, WANG Xuebin3, LI Beixing4
1 Changjiang River Scientific Research Institute of Changjiang Water Resources Commission, Wuhan 430010, China 2 National Center for Dam Safety Engineering Technology Research, Wuhan 430010, China 3 Power China Kunming Engineering Corporation Limited, Kunming 650051, China 4 State Key Laboratory of Silicate Materials for Architecture, Wuhan University of Technology, Wuhan 430070, China
Abstract: Reducing the cumulative hydration heat and heat evolution rate of the cementitious system by the means of adding an admixture with hydration heat inhibition is an important measure to reduce the temperature cracks in the concrete. Organic phosphonic acid compounds have more effective hydration heat inhibition and retardation effects on Portland cement. In the past few decades, organic phosphonic acid has been widely used in industrial and civil construction engineering, oil field cementing engineering and some concrete projects with special requirements. The application of organic phosphonic acid compounds in China is mainly concentrated in oilfield cementing concrete engineering. In recent years, it has also been more and more popular applied in civil engineering concrete projects, but the scope and extent of application are still very limited. In summary, organic phosphonic acid compounds have the following characteristics:(1) they can greatly reduce the cumulative hydration heat and heat evolution rate within a certain dosage. (2)They aren't sensitive to changes in cement clinker content, and they have good adaptability with Portland cement, polycarboxylate water reducer and naphthalene water reducer.(3) They can improve the performance of concrete mix and improve the long-term mechanical properties of concrete at a certain dosage ranges. (4) The main chain structure of organic phosphonic acid compounds have high temperature stability, and the applicable temperature is above 200 ℃. They can maintain strong retarding effect on Portland cement at a higher temperature. The effect of organic phosphonic acid compounds on the hydration of Portland cement is complicated, and the mechanism of retardation of Portland cement is not very clear. Different scholars hold different views on this.One of the views proposes that it firstly promotes the dissolution of Ca2+ in the cement, promotes the hydration of the cement mineral on the surface of the aluminum-rich layer, and promotes the hydration of the tricalcium aluminate (C3A). Then, they form a semi-permeable stable chelate on the surface of tricalcium silicate (C3S) in combination with Ca2+, which inhibits the hydration of C3S and inhibits further hydration of cement. Another point of view proposes that the organophosphonic acid compound effectively inhibits the nucleation and growth process of ettringite gel to crystal transformation, and it believes that delaying the growth of ettringite crystals is the main cause of retardation of Portland cement. In this paper, the application of organic phosphonic acid compounds in concrete engineering is summarized. The study progress of organic phosphonic acid compounds on hydration kinetics and retardation mechanisms of Portland cement are also summarized.Based on this, in order to further expand the application range of organic phosphonic acid compounds in concrete engineering, it is proposed to further study the effects of organic phosphonic acid compounds on the mechanical properties, volume stability, thermodynamic properties and durability of concrete.And the effect of organic phosphonic acid compounds on hydration kinetics of Portland cement and its retardation mechanism are further studied.
作者简介: 吕兴栋,2015年6月毕业于武汉理工大学硅酸盐国家重点实验室,获得工学硕士学位。现为长江水利委员长江科学院工程师,主要从事水工混凝土和固体废弃物再利用研究。主持长江科学院中央级公益性科研院所基本科研业务费1项,参与国家重点研发计划1项,国家自然科学基金2项。主持或参与横向科研项目10余项。Journal of Cleaner Production、《长江科学院院报》等学术期刊审稿人。以第一作者发表SCI论文5篇,EI或CPCI论文4篇,中文核心论文9篇,授权国家发明专利4项。
引用本文:
吕兴栋, 王学斌, 李北星. 有机膦酸类化合物在混凝土工程中的应用及缓凝机理研究进展[J]. 材料导报, 2020, 34(15): 15184-15189.
LYU Xingdong, WANG Xuebin, LI Beixing. Research Progress on Application of Organic Phosphonic Acid Compounds in Concrete Engineering and Their Retarding Mechanism. Materials Reports, 2020, 34(15): 15184-15189.
Bernd Nowack.Water Research, 2014, 37, 2533.2 Fang Liu, Lu Xianhui, Yang Wei, et al.Desalination, 2013, 313,193 Shen Liang, Wang Fangqian, Tian Lian, et al. Journal of Membrane Science, 2018, 563, 285.4 Dyhrman S T, Chappell P D, Haley S T, et al. Nature, 2010, 439, 69. 5 Huang J L, Su Z C, Xu Y.Journal of Molecular Evolution, 2011, 61, 686. 6 Dyhrman S T, Chappell P D, Haley S T, et al. Nature, 2010, 439, 69. 7 Huang J L, Su Z C, Xu Y.Journal of Molecular Evolution, 2011, 61, 685. 8 Dyhrman S T, Chappell P D, Haley S T, et al. Nature, 2010, 439, 70. 9 Lesueur C,Pfeffer M,Fuerhacker M.Chemosphere, 2005, 59, 688.10 Lupu C, Arvidson R S, Luttge A, et al.Chemical Communications, 2005,4, 2355.11 Engel R.Chemical Reviews, 1977, 77(3), 355.12 Ramachandran V S, Lowery M S, Wise T,et al.Materials and Structures, 1993, 26(7), 431.13 Johann Plank. In: Concrete admixture and its application technology conference. Beijing, 2004, pp.15.14 Conveney P V, Davey R J, Griffin J L W, et al.Chemical Communications,1998, 14, 146715 Li Bing.Jiangxi Building Materials, 2018(10), 22 (in Chinese).李兵.江西建材, 2018(10), 22.16 Lin Yankun, Zhang Dechen, Xu Jianzhao.Ready-mixed Concrete, 2018(8), 28 (in Chinese).林炎坤, 张德琛, 许建钊.商品混凝土, 2018(8), 28.17 Wang Jingjing, Chen Jing, Liu Yongdao, et al.Ready-mixed Concrete, 2017(1), 65 (in Chinese).王晶晶,陈景, 刘永道, 等.商品混凝土, 2017(1), 65.18 Chen Jing, Lu Jialin, Xu Fenlian, et al.China Concrete and Cement Pro-ducts, 2014(11), 26 (in Chinese).陈景, 卢佳林, 徐芬莲, 等.混凝土与水泥制品, 2014(11), 26.19 Wang Yingchun. Study on specific characteristics and qualification requirements of lift joints in roller compacted concrete. Ph. D. Thesis, Zhejiang University, China, 2007 (in Chinese).王迎春. 碾压混凝土层面结合特性和质量标准研究. 博士学位论文, 浙江大学, 2007.20 Lv Xingdong, Li Beixing, Shi Yan, et al.Advances in Engineering Research, 2016, 44, 1. 21 Zou Jianlong, Qu Jiansheng, Xu Yongshen, et al.Oilfield Chemistry, 2008, 25(4), 388 (in Chinese).邹建龙, 屈建省, 许涌深, 等.油田化学, 2008, 25(4), 388.22 Smith D K. In: Cementing. Society of Petroleum Engineers. New York, 1990.23 Thomas Hurnaus, Johann Plank. Journal of Natural Gas Science and Engineering, 2016,33,168.24 Andrew CJupe, Angus PWilkinson, Gayr Pfunkhouser.Cement and Concrete Research, 2012,42(8),1085.25 Brothers L E. U.S. patent application, US 5340397, 1994.26 Casabonne J M, Jouve M, Nelson E. U.S. patent application, US 5503671, 1996.27 Barlet-Gouedard V, Brand F J, Maroy P, et al. U.S. patent application, US 6511537, 2003.28 Wen Xueli, Wei Zhousheng, Li Bo, et al.Drilling Fluid & Completion Fluid, 2011, 28(5), 51 (in Chinese).温雪丽, 魏周胜, 李波, 等.钻井液与完井液, 2011, 28(5), 51.29 Qi Zhigang, Xu Yiji, Wang Huaiping, et al. Drilling Fluid & Completion Fluid, 2005, 22(5), 25 (in Chinese).齐志刚, 徐依吉, 王槐平, 等.钻井液与完成液, 2005, 22(5), 25.30 Zhao Yue, Sha Linhao, Wang Jiandong.Drilling Fluid & Completion Fluid, 2011, 28(11), 55 (in Chinese).赵岳, 沙林浩, 王建东.钻井液与完成液, 2011, 28(11),55.31 Wang Hongke, Wang Ye, Jin Jianxia, et al.Drilling Fluid & Completion Fluid, 2016, 33(3), 92 (in Chinese).王红科, 王野, 靳剑霞, 等.钻井液与完成液, 2016, 33(3), 92.32 Gu P, Ramachandran V S, Beaudoin J J, et al.Advanced Cement based Materials,1995, 2(5),185.33 Ramachandran V S. In:Fourth International Conference on Superplasticizers and Other Chemical Admixtures in Concrete. Montreal, 1995, pp.131.34 Johann Plank, Andreas Brandl, Nils Recalde Lummer.Journal of Applied Polymer Science, 2007,106(6),3892.35 Liu Ming. Effects and related mechanisms of polycarboxylate superplasticizers on cement hydration. Master's Thesis, Wuhan University of Technology, China, 2015 (in Chinese).刘明. 聚羧酸减水剂对水泥水化的影响及相关机理研究. 硕士学位论文,武汉理工大学, 2015.36 Li Beixing, Lyu Xingdong, Wei Yunquan, et al. Journal of Building Materials, 2016,19(3),420 (in Chinese).李北星,吕兴栋, 魏运权, 等.建筑材料学报, 2016,19(3), 420.37 Li Beixing, Lyu Xingdong, Dong Yun, et al.Construction and Building Materials, 2018, 168, 960.38 Li Gaoming. Regulation and mechanism of adjustable solidification agent on cement hydration process. Master's Thesis, Wuhan University of Technology, China, 2011 (in Chinese).李高明. 调凝剂对水泥水化历程的调控及作用机理研究. 硕士学位论文, 武汉理工大学, 2011.39 Maximilienne Bishop, Simon G Bott, Andrew R Barron.Chemistry of Materials, 2003, 15, 3076.40 Corina Lupu, Rolf S Arvidson, Andreas Luttge, et al. Chemical Communication, 2005,18, 2355. 41 Joerg Rickert, Gerd Thielen.Cement,Concrete, and Aggregates, 2004, 26(2), 98.42 Coveney P V, Humphries W.Journal of the Chemical Society Faraday Transactions, 2009, 92(5), 835.43 Billingham J, Coveney P V.Journal of the Chemical Society Faraday Transactions, 2006, 89(16), 3025.
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