An Overview on Study of the Mica-based Glass-Ceramic Composites
TIAN Qingbo1, 2, LI Chunzhen3, LI Haiwen3, WANG Yue2, LYU Zhijie2
1 Co-innovation Center for Green Building of Shandong Province, Shandong Jianzhu University, Jinan 250101 2 School of Materials Science and Engineering, Shandong Jianzhu University, Jinan 250101 3 Shandong Academy of Building Research, Jinan 251010
Abstract: Mica-based glass-ceramics (MGCs) have gained extensive interests due to some interesting features of good machinability, high thermal shock resistance and fracture toughness etc., especially the machinability, exhibiting a variety of engineering applications. However, the MGCs show low strength because of the weak bonds between the layer structures of mica crystals. Therefore, it has always been one of the key points to increasing the strength in investigation of MGCs for many years. Up to now, there have been many methods to increase the strength of MGCs, in which, the strength could be increased by:(i) increasing the bonding force between the interlayers of mica structure by introducing the varieties of ions; (ii) tailoring the microstructure by adjusting the composition of base glasses and thermal treatments; (iii) the preferential crystallization by extruding or hot pressing processes, and (iv) fabricating the composites by adding or precipitating reinforced second phases. Among them, the MGC composites have been made obvious advances because of the wide choices of the reinforced phases, the controlled adding amounts and the improved excellent properties. The reinforced phases in MGC composites mainly include two types: particle and fiber. The particle phases compose inert particles that they are inert, there are not phase transition of themselves and would not react with components of parent glasses in the fabricating processes of MGC composites, un-active particles that they could not take place phase transition of themselves but might react with components of parent glasses, and active particles that they could react of themselves or with components of parent glasses. Those particles were introduced into composites by adding into base glasses or parent glasses before the thermal treatment. The formation of particle reinforced phases could influence the sintering processes of MGC composites by changing the components of composites or compositions of the parent glasses, or altering the crystallizing cha-racteristics owing to the reaction between particles and glasses. In particle-reinforced MGC composites, the types of particles and the precipitation of particles are two significant factors that influence the final properties of MGC composites. The choices of reinforced particles and MGC compo-sites with special functions will be main aspects to be explored. The fibers were usually introduced into composites by mixing with grains of the parent glasses before thermal treatment. The addition of the fibers were beneficial to improve the toughness strength of MGC materials. Nowadays, carbon fiber, SiO2/Al2O3 fiber and AlN fiber have been reported to be used for the fabrication of MGC composites. In fiber-reinforced MGC composites, the interfaces bonding between fiber and the parent glasses is a key factor, which affects the properties of MGC composites. In this paper, the development of MGC composites is reviewed. The varieties, preparation and properties of the MGC composites are summarized, in which, the effects and characteristics of the reinforced phases are emphasisly discussed. Also the development trends of MGC compo-sites are referred.
田清波, 李春珍, 李海文, 王玥, 吕志杰. 云母微晶玻璃复合材料的研究进展[J]. 材料导报, 2019, 33(13): 2191-2196.
TIAN Qingbo, LI Chunzhen, LI Haiwen, WANG Yue, LYU Zhijie. An Overview on Study of the Mica-based Glass-Ceramic Composites. Materials Reports, 2019, 33(13): 2191-2196.
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2019, Vol. 33 
