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材料导报  2018, Vol. 32 Issue (16): 2733-2737    https://doi.org/10.11896/j.issn.1005-023X.2018.16.006
  无机非金属及其复合材料 |
碱式硫酸镁水泥耐酸腐蚀性能研究
李振国, 刘博, 吴运强, 王博, 郭江涛, 余四文
哈尔滨理工大学建筑工程学院,哈尔滨 150080
Research on Acid Corrosion Resistance Properties of Basic Magnesium Sulfate Cement
LI Zhenguo, LIU Bo, WU Yunqiang, WANG Bo, GUO Jiangtao, YU Siwen
College of Civil Engineering and Architecture, Harbin University of Science and Technology, Harbin 150080
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摘要 为了研究碱式硫酸镁水泥耐酸腐蚀性能,将不同配比的水泥试样分别在柠檬酸溶液及水中浸泡不同龄期,再进行质量变化测定及抗折强度和抗压强度试验。采用XRD与SEM技术分析不同配比水泥试样浸泡于两种溶液后的物相组成和显微形貌。结果表明,掺入的矿渣和粉煤灰对碱式硫酸镁水泥具有良好的密实填充作用,降低了水泥的孔隙率,有效阻止了侵蚀介质的进入,其耐酸腐蚀性能与未掺矿渣和粉煤灰的碱式硫酸镁水泥相比有明显提升,其中,掺矿渣的碱式硫酸镁水泥耐酸腐蚀性能更优。
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李振国
刘博
吴运强
王博
郭江涛
余四文
关键词:  碱式硫酸镁水泥  抗蚀系数  质量变化  水化产物    
Abstract: In order to study acid corrosion resistance properties of basic magnesium sulfate cement with different ratios, the mass variation, flexural strength and compressive strength of cement sample were texted at different curing age after immersing in water and citric acid solution. The phase composition and microstructure of hydration products after immersing in the two solutions were analyzed by XRD and SEM. The experimental results show that the addition of slag and fly ash can decrease the porosity and fine the pore size in the hardened paste. Thus the microstructure of cement samples becomes more compact and preventing the corrosion substance effectively. Due to these effects, basic magnesium sulfate cement with slag and fly ash has higher acid corrosion resis-tance than that without slag and fly ash. Moreover, the acid corrosion resistance of basic magnesium sulfate cement with slag is superior to that with fly ash.
Key words:  basic magnesium sulfate cement    corrosion resistance coefficient    mass change    hydration products
               出版日期:  2018-08-25      发布日期:  2018-09-18
ZTFLH:  TQ177.5  
基金资助: 国家重点研发计划(2017YFC0806100);国家自然科学基金青年科学基金(11502061)
作者简介:  李振国:男,1975年生,副教授,主要从事新型建筑材料的研究 E-mail:lzgfree@163.co
引用本文:    
李振国, 刘博, 吴运强, 王博, 郭江涛, 余四文. 碱式硫酸镁水泥耐酸腐蚀性能研究[J]. 材料导报, 2018, 32(16): 2733-2737.
LI Zhenguo, LIU Bo, WU Yunqiang, WANG Bo, GUO Jiangtao, YU Siwen. Research on Acid Corrosion Resistance Properties of Basic Magnesium Sulfate Cement. Materials Reports, 2018, 32(16): 2733-2737.
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http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2018.16.006  或          http://www.mater-rep.com/CN/Y2018/V32/I16/2733
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