Thermal Effect on the Failure of Cement Hydration Products Under High Velocity Flow Cavitation
HE Yang1,2, QIAN Wenxun1,2, ZHANG Yanchi1,2, CAI Yuebo1,2, WANG Xin1,2
1 Nanjing Hydraulic Research Institute, Nanjing 210029; 2 Research Center on New Materials in Hydraulic Structures, Ministry of Water Resources, Nanjing 210029
Abstract: With the development of dam construction skills and further utilization of water power resources, the construction of high dams improves rapidly. It leads to a major problem of protection against the cavitation erosion caused by high velocity and large flow of flood discharge. Instead of the conventional way of mechanical analysis on cavitation, this paper was devoted to illustrate the thermal impact on the kind of erosion. Ultrasonic cavitation device was utilized for the test of various kinds of cement paste, with a combination analysis of erosion surface of hardened cement paste and micro-analysis of hydration product, the article studied the thermal effect of cavitation on the surface of hardened cement paste. The thermal effect of cavitation erosion on cement hydration products was initially discussed in this paper. Results indicated that cavitation erosion on cement paste is not only a simply mechanical failure but also conducts a thermal decomposition on hydration of cement, which could cause the partial decomposition of cement hydration products. To be specific, the mass loss of hydration gel substances is no less than 40% so as the loss of hydrated lime is more than 25% during a 6 hours ultrasonic cavitation experiment. In that way, the considerable hydration mass loss could lead to a significant impact on cement paste deterioration.
何旸, 钱文勋, 张燕迟, 蔡跃波, 王新. 高速水流下空蚀热效应对水泥水化产物的破坏[J]. 材料导报, 2018, 32(24): 4281-4285.
HE Yang, QIAN Wenxun, ZHANG Yanchi, CAI Yuebo, WANG Xin. Thermal Effect on the Failure of Cement Hydration Products Under High Velocity Flow Cavitation. Materials Reports, 2018, 32(24): 4281-4285.
1 Zhou J P. Development of hydropower and dam construction in China[J].Journal of Hydraulic Engineering,2000(9):6(in Chinese). 周建平.中国水力发电的发展及大坝建设[J].水利学报,2000(9):6. 2 Momber A W. Short-time cavitation erosion of concrete[J].Wear,2000,241(1):47. 3 Van W L. Mechanics of collapsing cavitation bubbles[J].Ultrasonics Sonochemistry,2016,29:524. 4 Zhang J S. Cavitation damage and prevention measures of turbine in Yangling Hydropower Station[J].Mechanical & Electrical Technique of Hydropower Station,2006,29(6):25(in Chinese). 张建胜.杨凌水电站水轮机空蚀危害及防抗措施[J].水电站机电技术,2006,29(6):25. 5 Peshkovsky S L, Peshkovsky A S. Shock-wave model of acoustic cavitation[J].Ultrasonics Sonochemistry,2008,15(4):618. 6 Mitropetros K, Hieronymus H, Steinbach J. Single bubble ignition after shockwave impact[J].Chemical Engineering Science,2018,61(2):397. 7 Emil. A. B. Shock wave emission from laser-induced cavitation bubbles in polymer solutions[J].Ultrasonics,2008,48(5):423. 8 Hu Y Y. Numerical study of the VOF method and bubble collapse and cavitation flow [D].Beijing:Tsinghua University,2001(in Chinese). 胡影影.VOF方法的改进及空泡溃灭和空化流的数值研究[D].北京:清华大学,2001. 9 Wang Z Y, Long N D, Zhu J H. Review on material resistant to cavitation erosion and its application[J].Development and Application of Materials,2001,16(6):34(in Chinese). 王再友,龙霓东,朱金华.抗空蚀材料研究应用进展[J].材料开发与应用,2001,16(6):34. 10 Söhnholz H, Kurz T. Thermal effects upon collapse of laser-induced cavitation bubbles[C]∥International Symposium on Cavitation, Singapore,2012. 11 Xue W, Chen Z Y. The micro-cours of the cavitation erosion[J].Materials for Mechanical Engineering,2005,29(2):59(in Chinese). 薛伟,陈昭运.空蚀破坏的微观过程研究[J].大电机技术,2005,29(2):59. 12 Chen Z Y. The role of oxidization in cavitation damage[J].Journal of Harbin Engineering University,2007,28(9):1056(in Chinese). 陈昭运.空蚀破坏的微观氧化过程[J].哈尔滨工程大学学报,2007,28(9):1056. 13 Long T P, Carino N J. Review of mechanical properties of HSC at elevated temperature[J].Journal of Materials in Civil Engineering,1998,10(1):58. 14 Huang J T, Long Z M. Experimental study on cavitation corrosion resistance of silica fume concrete[J].Journal of Hydraulic Enginee-ring,1991,1(1):65(in Chinese). 黄继汤,龙再明.硅粉混凝土抗空蚀性能的试验研究[J].水利学报,1991,1(1):65. 15 Bonaccorsi E. Modular microporous minerals: Cancrinite-davyne group and CSH phases[J].Reviews in Mineralogy & Geochemistry,2005,57(1):241.