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《材料导报》期刊社  2018, Vol. 32 Issue (14): 2370-2375    https://doi.org/10.11896/j.issn.1005-023X.2018.14.009
  无机非金属及其复合材料 |
水灰比对镁系无机轻质材料性能的影响规律
左迎峰1, 肖俊华1, 李萍1,2, 王健1, 李贤军1, 吴义强1
1 中南林业科技大学材料科学与工程学院,长沙 410004;
2 湘南学院美术与设计学院,郴州 423000
Effect of Water Cement Ratio on Properties of Magnesium Inorganic Light Materials
ZUO Yingfeng1, XIAO Junhua1, LI Ping1,2, WANG Jian1, LI Xianjun1, WU Yiqiang1
1 College of Material Science & Engineering, Central South University of Forestry & Technology, Changsha 410004;
2 College of Art & Design, Xiangnan University, Chenzhou 423000
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摘要 以镁系胶凝材料为主料,双氧水为发泡剂,二氧化锰为激发剂,硬脂酸钙为稳定剂,聚丙烯酰胺为增稠剂,通过化学发泡法制备内部含有大量密闭气孔的镁系无机轻质材料。探讨了水灰比(镁盐水用量与氧化镁粉比率)对镁质无机轻质材料表观密度、压缩强度、弯曲强度、孔结构及耐水性的影响规律。实验结果表明,水灰比不仅影响镁系无机轻质材料的孔结构和发泡成型,对晶体结构也有较大影响。随着水灰比增大,浆体稠度降低,镁系无机轻质材料的表观密度减小,孔结构形态逐渐得到改善,力学强度和耐水性则是先增大后减小。在水灰比为1.4时,强度相峰值最大,镁系无机轻质材料压缩强度和弯曲强度最大,耐水性最佳,同时平均孔径较小,孔隙率和圆度值最接近开普勒理想模型数值,表观密度仅为0.41 g/cm3,适合作为节能轻质墙体材料使用。
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左迎峰
肖俊华
李萍
王健
李贤军
吴义强
关键词:  镁系胶凝材料  化学发泡  无机轻质材料  水灰比  孔结构    
Abstract: Magnesium inorganic light material containing a large number of closed pores inside were prepared by chemical foaming process, in which magnesium based cementing material as raw material, hydrogen peroxide as foaming agent, manganese dioxide as activator, calcium stearate as stabilizer and polyacrylamide as thickener. The effect of water cement ratio (the ratio of magnesium salt and magnesium oxide) on the apparent density, compression strength, bending strength, pore structure and water resistance of magnesium inorganic light materials were studied. The experimental results showed that the water cement ratio not only affects the pore structure and foaming formation of magnesium inorganic light materials, but also has a great influence on the crystal structure. With the increasing of water cement ratio, the paste consistency decreased, the apparent density of magnesium inorganic light material decreased, the pore structure shape gradually improved, the mechanical strength and water resistance increased first and then decreased. When the water cement ratio was 1.4, the peak of the intensity phase was the largest, the magnesium inorganic light material had the largest compressive strength, flexural strength and best water resistance. At the same time, the average pore size was smaller, the porosity and the roundness value are close to the Kepler ideal model value, and the apparent density was only 0.41 g/cm3, which is suitable for the use of energy-saving lightweight wall materials.
Key words:  magnesium based cementing material    chemical foaming    inorganic light materials    water cement ratio    pore structure
               出版日期:  2018-07-25      发布日期:  2018-07-31
ZTFLH:  TU55  
基金资助: “十二五”国家科技支撑计划课题(2012BAD24B03);林业专利产业化引导项目(2016-11);国家林业公益性行业科研重大专项(201204704);湖南省科技人才计划项目(2016TP1013);湖南省科技创新平台(2016RS2010)
通讯作者:  吴义强,男,1967年生,教授,博士研究生导师,主要从事农作物资源利用、生物质复合材料、木材科学研究 E-mail:wuyq0506@126.com   
作者简介:  左迎峰:男,1986年生,博士,讲师,主要从事生物质复合材料及胶黏剂改性研究 E-mail:zuoyf1986@163.com
引用本文:    
左迎峰, 肖俊华, 李萍, 王健, 李贤军, 吴义强. 水灰比对镁系无机轻质材料性能的影响规律[J]. 《材料导报》期刊社, 2018, 32(14): 2370-2375.
ZUO Yingfeng, XIAO Junhua, LI Ping, WANG Jian, LI Xianjun, WU Yiqiang. Effect of Water Cement Ratio on Properties of Magnesium Inorganic Light Materials. Materials Reports, 2018, 32(14): 2370-2375.
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http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2018.14.009  或          http://www.mater-rep.com/CN/Y2018/V32/I14/2370
1 Zhou Xiaoyan, Li Jian, Zhou Dingguo. Simulation evaluation of the heat-conducting property of wheat straw-based sandwich wallboard[J]. Scientia Silvae Sinicae,2007,43(2):24(in Chinese).
周晓燕,李键,周定国.轻质秸秆复合墙体传热特性模拟评价[J].林业科学,2007,43(2):24.
2 Zhang Meng, Tian Qingbo, Xu Lina, et al. Status and prospects of research on foamed cement[J]. Bulletin of the Chinese Ceramic Society,2014,33(10):2547(in Chinese).
张萌,田清波,徐丽娜,等.发泡水泥的研究现状及展望[J].硅酸盐通报,2014,33(10):2547.
3 Papadopoulos A M. State of the art in thermal insulation materials and aims for future developments[J]. Energy and Buildings,2005,37:78.
4 Gyoung-Seok Choi, Jae-Sik Kang, Young-Sun Jeong, ea al. An experimental study on thermal properties of composite insulation[J]. Thermochimica Acta,2007,455:75.
5 Wang F, Yang L, Guan L, et al. Microstructure and properties of cement foams prepared by magnesium oxychloride cement[J]. Journal of Wuhan University of Technology(Materials Science Edition),2015,30(2):331.
6 Xi X, Shui A, Li Y, et al. Effects of magnesium oxychloride and silicon carbide additives on the foaming property during firing for porcelain ceramics and their microstructure[J]. Journal of the European Ceramic Society,2012,32(12):3035.
7 Sglavo V M, De Genua F, Conci A, et al. Influence of curing temperature on the evolution of magnesium oxychloride cement[J]. Journal of Materials Science,2011,46(20):6726.
8 Chau C K, Chan J, Li Z. Influences of fly ash on magnesium oxychloride mortar[J]. Cement and Concrete Composites,2009,31(4):250.
9 Shuiping W, Rui W, Yingdan Z, et al. Effects of EVA latex on the properties of glass-fiber/magnesium-oxychloride cement composites[J]. Journal of Wuhan University of Technology(Materials Science Edition),2006,21(1):138.
10 Li Y, Li Z J, Pei H F, et al.The influence of FeSO4 and KH2PO4 on the performance of magnesium oxychloride cement[J].Construction and Building Materials,2016,102:233.
11 Chen Xuefei, Wang Luming. Research on water resistance of magnesium oxychloride cement with sodium phosphate and styrene-acrylate emulsion[J]. Concrete,2017(6):76(in Chinese).
陈雪霏,王路明.磷酸钠/苯丙乳液改善氯氧镁水泥耐水性的研究[J].混凝土,2017(6):76.
12 Xu Wen, Liu Xingya, Zhu Qinghua. Experimental research on foam concrete panel prepared with chemical method used in external wall external insulation system[J]. Concrete,2012(3):131(in Chinese).
徐文,刘兴亚,朱清华.外墙外保温用化学发泡泡沫混凝土板的试验研究[J].混凝土,2012(3):131.
13 Kearsley E P, Wainwright P J. The effect of high fly ash content on the compressive strength of foamed concrete[J]. Cement and Concrete Research,2001,31(1):105.
14 Peng Junzhi, Peng Xiaoqin. A review on structure and properties of aerated concrete[J]. Materials Review A: Review Papers,2011,25(1):89(in Chinese).
彭军芝,彭小芹.加气混凝土的结构与性能研究进展[J].材料导报: 综述篇,2011,25(1):89.
15 Guan Hui, Ba Hengjing. A study on the stability of magnesium oxychloride cement[J]. Journal of Harbin Engineering University,2009(11):1213(in Chinese).
关辉,巴恒静.氯氧镁水泥相稳定性的研究[J].哈尔滨工程大学学报,2009(11):1213.
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