污水中非正磷酸盐处理技术研究进展

材料导报

2022, Vol. 36

Issue (Z1): 22050093-5

无机非金属及其复合材料

污水中非正磷酸盐处理技术研究进展

刘利¹, 诸力维¹, 彭喜林¹, 周洋¹, 张楷彬¹, 孙浩荻¹, 李晓林²

1 重庆市三峡鱼复排水有限责任公司,重庆 401133
2 西南大学化学化工学院,重庆 400715

Research Progress on Non-Orthophosphate Treatment Technology in Sewage

LIU Li¹, ZHU Liwei¹, PENG Xilin¹, ZHOU Yang¹, ZHANG Kaibin¹, SUN Haodi¹, LI Xiaolin²

1 Chongqing Three Gorges Yufu Drainage Co., Ltd., Chongqing 401133, China
2 College of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715, China

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摘要磷元素是动物和植物必不可少的元素之一,也是重要的化工原料。随着磷元素的大规模生产和应用,期间产生的污水含有大量的磷元素,磷元素的富集会造成水体富营养化,从而导致大量水体生物死亡。目前,污水中磷元素的主要存在形式有正磷酸盐、非正磷酸盐(亚磷酸盐、次磷酸盐)和有机磷等。随着表面处理工业的发展,非正磷酸盐是磷化表面处理的重要试剂,且应用越来广泛。相比于正磷酸盐,非正磷酸盐无法用生物法和混凝法直接去除,从而造成总磷超标。因此,非正磷酸盐的去除是目前净水过程的重要研究内容。本文通过对有关非正磷酸盐的去除方法进行汇总和提炼,找到针对不同体系的适用的方法。非正磷酸盐的处理方法主要分为物理吸附法和化学氧化法。物理吸附法对低浓度非正磷酸盐污水的吸收效果较好,处理效率高,但对高浓度非正磷酸盐污水的吸收有着较大的限制;化学氧化法是常用的处理非正磷酸盐的方法,化学氧化法又分为传统氧化、芬顿氧化和电化学氧化等。但化学氧化法由于需要外加药剂,产生的污泥含量较高,后续需要较高的处理费用。总的来看,物理法和化学法各有优劣,对于非正磷酸盐的处理,还需要更多深入的研究。

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	刘利
	诸力维
	彭喜林
	周洋
	张楷彬
	孙浩荻
	李晓林

关键词: 污水处理总磷非正磷酸盐物理吸附化学氧化

Abstract: Phosphorus is one of the essential elements of animals and plants, and it is also an important chemical raw material. With the large-scale production and application of phosphorus, the sewage produced during the period contains a large amount of phosphorus, the enrichment of phosphorus element will cause the entrophication of the water, resulting in the death of a large number of animals. At present, the phosphorus elements in sewage mainly include orthophosphate, non-orthophosphate (phosphite, hypophosphite) and organic phosphorus. With the development of the surface treatment industry, non-orthophosphates are used more and more widely as an important component of phosphating surface treatment. Compared with orthophosphate, non-orthophosphate cannot be directly removed by biological methods and coagulation methods, resulting in excessive total phosphorus. Therefore, the removal of non-orthophosphate is an important research content in wastewater treatment. This article summarizes the removal methods of non-orthophosphates, and finds the applicable methods for different systems. The treatment methods of non-orthophosphate are mainly divided into physical adsorption method and chemical oxidation method. The physical adsorption me-thod has better absorbed effect on low non-orthophosphate wastewater and high treatment efficiency, but has a greater limitation on the absorption of high non-orthophosphate wastewater; the chemical oxidation method is a commonly used method for the treatment of non-orthophosphate, and the chemical oxidation method is divided into traditional oxidation, Fenton oxidation and electrochemical oxidation. However, due to the need for additional chemicals, the chemical oxidation method produces a higher sludge content and requires higher treatment costs. In general, physical methods and chemical methods have their own advantages and disadvantages, and more in-depth research is needed on the treatment of non-orthophosphates.

Key words: sewage treatment total phosphorus non-orthophosphate physical adsorption chemical oxidation

出版日期: 2022-06-05 发布日期: 2022-06-08

ZTFLH:

O646.51

通讯作者: 20801461@qq.com;xiaolinli@swu.edu.cn

作者简介: 刘利,环境工程师,现从事污水处理运营管理工作。已发表论文3篇,获得实用新型专利1项,参与授权专利4项。
李晓林,西南大学化学化工学院讲师。分别于2010年、2017年获得重庆大学化学化工学院学士学位和博士学位,博士期间先后赴密苏里大学和耶鲁大学交流学习。主要研究纳米材料的制备及其在电催化氧化中的应用。

引用本文:

刘利, 诸力维, 彭喜林, 周洋, 张楷彬, 孙浩荻, 李晓林. 污水中非正磷酸盐处理技术研究进展[J]. 材料导报, 2022, 36(Z1): 22050093-5.
LIU Li, ZHU Liwei, PENG Xilin, ZHOU Yang, ZHANG Kaibin, SUN Haodi, LI Xiaolin. Research Progress on Non-Orthophosphate Treatment Technology in Sewage. Materials Reports, 2022, 36(Z1): 22050093-5.

链接本文:

http://www.mater-rep.com/CN/ 或 http://www.mater-rep.com/CN/Y2022/V36/IZ1/22050093

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