Abstract: Nanometallic materials have a wide range of application prospects with superior physical and chemical properties compared to traditional bulk metallic materials. Nanomaterials are susceptible to oxidation during service, which can seriously affect the performance of nanodevices and accelerate the aging of devices, resulting in irreversible damage. Figuring out the microscopic process of oxidation of metallic materials and improving the oxidation resistance of materials are major problems in national major projects and the focus of research by scientists and resear-chers. In the past, most of the traditional research on oxidation mechanism was limited to the study of the formation mechanism, formation sequence, formation causes and other factors of multilayer oxidation film at the micron scale, and the study of dynamic oxidation mechanism of metallic materials at the in-situ atomic scale was lacking. Therefore, it is important to study the oxidation process of metal nanomaterials at the nanoscale and to establish a clear atomic-scale oxidation system to improve the antioxidant capacity of materials as well as to design and optimize the design of antioxidant materials. The emergence of advanced in-situ techniques enables researchers to reveal the oxidation mechanism of nano-metals from the atomic scale and resolve the oxidation process from the physical nature, thus solving the fundamental physical problems that have plagued mankind. In this paper, we firstly discuss the reaction mechanism of metal oxidation, then we systematically summarize and analyze the research progress and results obtained in recent years by using in-situ technology for in-situ oxidation experiments, then we systematically summarize and analyze the research progress of in-situ oxidation of different metal nanomaterials, and finally, we make a brief outlook on the future applications of in-situ oxidation technology and the problems that need to be solved.
裴星飞, 王立华, 陈艳辉. 纳米金属材料原位氧化电子显微学研究进展[J]. 材料导报, 2022, 36(Z1): 22010202-10.
PEI Xingfei, WANG Lihua, CHEN Yanhui. Research Progress on In-situ Oxidation by Electron Microscopy of Nanometallic Materials. Materials Reports, 2022, 36(Z1): 22010202-10.
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2022, Vol. 36 
